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Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

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Contribution to Modelling the Effect of Temperature on Removal of Nickel Ions by Adsorption on Nano-Bentonite

https://doi.org/10.14233/ajchem.2018.21252
F. Alakhras
Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, Dammam 31441, Saudi Arabia
E. Al-Abbad
Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, Dammam 31441, Saudi Arabia
N.O. Alzamel
Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, Dammam 31441, Saudi Arabia
F.M. Abouzeid
Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, Dammam 31441, Saudi Arabia; Chemistry Department, Faculty of Science, Alexandria University, PO Box 2, Moharram Beck, Alexandria 21568, Egypt
N. Ouerfelli
Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, Dammam 31441, Saudi Arabia

Corresponding Author(s) : F. Alakhras

falakhras@iau.edu.sa

Asian Journal of Chemistry, Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

Abstract

Nano-bentonite was investigated as a prospect sorbent for the elimination of nickel ions from aqueous solutions. At optimum conditions; pH 6, Ni(II) primary concentration 100 mg/L and adsorbent dosage 0.5 g, the achieved highest adsorption capability was 39.06 mg/g. The isothermal data were modeled with Langmuir and Freundlich isotherm models. Thermodynamic data revealed the spontaneity of target species adsorption onto used adsorbent, raise in entropy change at the solid-liquid boundary and endothermic process. The purpose of this study was to extend primary and secondary prototypes to express the effect of temperature (from 20 to 50 °C) on the sorption of nickel ions onto bentonite surface. Proposed models could be integrated to suggest some practical equations for different experimental conditions and can be exploited for further prediction and interesting additional interpretations.

Keywords

Nano bentonite Nickel Adsorption Temperature effect Thermodynamic
Alakhras, F., Al-Abbad, E., Alzamel, N., Abouzeid, F., & Ouerfelli, N. (2018). Contribution to Modelling the Effect of Temperature on Removal of Nickel Ions by Adsorption on Nano-Bentonite. Asian Journal of Chemistry, 30(5), 1147–1156. https://doi.org/10.14233/ajchem.2018.21252
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