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Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

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ZrO2 Nanoparticles-Supported Cu2(II)-β-Cyclodextrin Mediated Synthesis of N-2 Substituted Tetrazoles by [2+3] Cycloaddition and Post Tetrazole Alkylation

https://doi.org/10.14233/ajchem.2018.21192
Yarabhally R. Girish
Deparment of Organic Chemistry, Indian Institute of Science, Bengaluru-560 012, India
Kothanahally S. Sharath Kumar
Deparment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru-570 006, India
Kereyagalahally H. Narasimhamurthy
Deparment of Studies in Organic Chemistry, University of Mysore, Manasagangotri, Mysuru-570 006, India
Kanchugarakoppal S. Rangappa
Deparment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru-570 006, India
Sheena Shashikanth
Deparment of Studies in Organic Chemistry, University of Mysore, Manasagangotri, Mysuru-570 006, India

Corresponding Author(s) : Sheena Shashikanth

shashis1956@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

Abstract

An efficient one-pot ZrO2 nanoparticles-supported Cu2(II)-β-cyclodextrin promoted [2+3] cycloaddition of benzonitriles and sodium azide followed by post tetrazole alkylation using aralkyl esters for the synthesis of N-2-substituted tetrazoles has been presented. One-pot operation, atom-economical, regioselectivity and good yields are the main advantages of this protocol. From the atom economy, it is clear that, catalyst can be reused up to four times without any appreciable changes in catalytic activity

Keywords

ZrO2 Nanoparticles [2 3] Cycloaddition Alkylation Tetrazoles Benzonitriles
Girish, Y. R., Sharath Kumar, K. S., Narasimhamurthy, K. H., Rangappa, K. S., & Shashikanth, S. (2018). ZrO2 Nanoparticles-Supported Cu2(II)-β-Cyclodextrin Mediated Synthesis of N-2 Substituted Tetrazoles by [2+3] Cycloaddition and Post Tetrazole Alkylation. Asian Journal of Chemistry, 30(5), 1093–1098. https://doi.org/10.14233/ajchem.2018.21192
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