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Removal of Hexavalent Chromium from Water and Organic Solvent Mixed Media by Adsorption Using Weak Base Anion Exchanger Tulsion A-2X (MP)
Corresponding Author(s) : Sanjaykumar V. Divekar
Asian Journal of Chemistry,
Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018
Abstract
The removal of a most common toxic, environmental pollutant and carcinogen chromium(VI) was studied by batch technique for the adsorption and ion exchange method from water and organic solvent mixed media under various conditions like interaction time, pH, effect of organic solvents and temperature. Maximum adsorption of chromium(VI) on Tulsion A-2X (MP) was in the optimum pH range of 5.0-5.5. Increase in temperature decreased the adsorption of chromium(VI). Interaction time indicated that about 70 % removal of chromium(VI) was within 15 min. Chromium(IV) adsorption was discussed based on first order kinetics and adsorption isotherms.
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References
Y. Gu and X. Zhu, Mikrochim. Acta, 173, 433 (2011); https://doi.org/10.1007/s00604-011-0578-3.
R.M. Sedman, J. Beaumont, T.A. McDonald, S. Reynolds, G. Krowech and R. Howd, J. Environ. Sci. Health, 24, 155 (2006); https://doi.org/10.1080/10590500600614337.
U.S. Environmental Protection Agency, Guidance for Data Useability in Risk Assessment, Part A (1992).
S. Edebali and E. Pehlivan, Chem. Eng. J., 161, 161 (2010); https://doi.org/10.1016/j.cej.2010.04.059.
P.S. Koujalagi, S.V. Divekar, R.M. Kulkarni and R.K. Nagarale, Desalination Water Treat., 51, 3273 (2013); https://doi.org/10.1080/19443994.2012.749049.
S. Gupta and B.V. Babu, Chem. Eng. J., 150, 352 (2009); https://doi.org/10.1016/j.cej.2009.01.013.
B. Galan, D. Castaneda and I. Ortiz, Water Res., 39, 4317 (2005); https://doi.org/10.1016/j.watres.2005.08.015.
G. Kabir and S.E. Ogbeide, Int. J. Environ. Res., 2, 377 (2008).
P.S. Koujalagi, S.V. Divekar, R.M. Kulkarni and E.M. Cuerda-Correa, Desalination Water Treat., 57, 23965 (2016); https://doi.org/10.1080/19443994.2016.1138329.
A.D. Eaton, L.S. Clesceri and A.E. Greenberg, American Public Health Association (APHA), AWWA, WPCE: Washington D.C., vol. 4 (1995).
APHA, AWWA, WEF, “Standard Methods for Examination of Water and Waste Water, Washington-DC, NewYork, edn 20 (1998).
S.S. Baral, S.N. Das and P. Rath, Biochem. Eng. J., 31, 216 (2006); https://doi.org/10.1016/j.bej.2006.08.003.
P.K. Pandey, S.K. Sharma and S.S. Sambi, Int. J. Environ. Sci. Technol., 7, 395 (2010); https://doi.org/10.1007/BF03326149.
E. Pehlivan and S. Cetin, J. Hazard. Mater., 163, 448 (2009); https://doi.org/10.1016/j.jhazmat.2008.06.115.
S.I. Sandler, Chemical and Engineering Thermodynamics, John Wiley & Sons, New York, USA, edn 3 (1999).
I.-H. Lee, Y.-C. Kuan and J.-M. Chern, J. Chinese Inst. Chem. Eng., 38, 71 (2007); https://doi.org/10.1016/j.jcice.2006.11.001.
Y.H. Li, Z. Di, J. Ding, D. Wu, Z. Luan and Y. Zhu, Water Res., 39, 605 (2005); https://doi.org/10.1016/j.watres.2004.11.004.
F. Gode and E. Pehlivan, J. Hazard. Mater., 100, 231 (2003); https://doi.org/10.1016/S0304-3894(03)00110-9.
J. Pradhan, S.N. Das and R.S. Thakur, J. Colloid Interface Sci., 217, 137 (1999); https://doi.org/10.1006/jcis.1999.6288.
G. McKay, H.S. Blair and J.R. Gardner, J. Appl. Polym. Sci., 27, 3043 (1982); https://doi.org/10.1002/app.1982.070270827.
S.V. Mohan, N.C. Rao and J. Karthikeyan, J. Hazard. Mater., 90, 189 (2002); https://doi.org/10.1016/S0304-3894(01)00348-X.
T.W. Weber and R.K. Chakravorti, J. Am. Inst. Chem. Eng., 20, 228 (1974); https://doi.org/10.1002/aic.690200204.
A. Sari, M. Tuzen, D. Citak and M. Soylak, J. Hazard. Mater., 149, 283 (2007); https://doi.org/10.1016/j.jhazmat.2007.03.078.