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Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

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Oxidation Kinetics of L-Arabinose with Quinolinium Chlorochromate

https://doi.org/10.14233/ajchem.2018.21134
J.V. Singh
Department of Chemistry, Nehru College, Chhibramau-209 721, India
Ashish Tomar
Department of Chemistry, Meerut College, Meerut-250 001, India

Corresponding Author(s) : Ashish Tomar

ashishtomar1983@yahoo.co.in

Asian Journal of Chemistry, Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

Abstract

Oxidation kinetics of L-arabinose with quinolinium chlorochromate (QCC) have been investigated spectrophotometrically. Under pseudo-first order condition, the oxidation is first order with respect to both [QCC] and [L-arabinose]. The oxidation rate was promoted by [acid] and remains unaffected by [NaClO4]. A 1:1 stoichiometry is observed. Activation energy and concerned thermodynamic parameters worked out from reaction rate at different temperatures. Mechanism consistent with the observed data has been proposed.

Keywords

Oxidation Kinetic Mechanism L-Arabinose Quinolinium chlorochromate Spectrophotometrically
Singh, J., & Tomar, A. (2018). Oxidation Kinetics of L-Arabinose with Quinolinium Chlorochromate. Asian Journal of Chemistry, 30(5), 1027–1030. https://doi.org/10.14233/ajchem.2018.21134
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