Synthesis and Characterization of Linear Polycarboxylate Dispersant of Glacial Acrylic Acid−Maleic Acid−Sodium Methallylsulfonate for Ceramics

Kiran Kumar Kommanapalli; Pierre Lyot; Jhansi Rani Sunkara; Pierrick Checule; A.V.L.N.S.H. Hari Haran

doi:10.14233/ajchem.2018.21076

Issue

Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

Issue Published : March 29, 2018

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Linear Polycarboxylate Dispersant of Glacial Acrylic Acid−Maleic Acid−Sodium Methallylsulfonate for Ceramics

https://doi.org/10.14233/ajchem.2018.21076

Kiran Kumar Kommanapalli

SNF SAS Dispersant Research Labs Division, Ceramic R&D Laboratory, SNF Floerger, ZAC de Milieux 42163 andrezieux Cedex, France

Pierre Lyot

SNF SAS Dispersant Research Labs Division, Ceramic R&D Laboratory, SNF Floerger, ZAC de Milieux 42163 andrezieux Cedex, France

Jhansi Rani Sunkara

Department of Chemistry, Andhra University, Visakhapatnam-530 003, India

Pierrick Checule

SNF SAS Dispersant Research Labs Division, Ceramic R&D Laboratory, SNF Floerger, ZAC de Milieux 42163 andrezieux Cedex, France

A.V.L.N.S.H. Hari Haran

Central Research Laboratories, GITAM Institute of Technology, GITAM University, Visakhapatnam-530 045, India

Corresponding Author(s) : Kiran Kumar Kommanapalli

kommanapalli.k@snf-india.com; kkirann72@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018
Article Published : March 29, 2018

Abstract

In this research, linear polycarboxylate of glacial acrylic acid (GAA), maleic acid (MA) and sodium methallylsulfonate (SMAS) dispersant polymer as a water reducer was synthesized for ceramic applications by using redox free radical initiation system consisting sodium persulfate (Na₂S₂O₈) and sodium hypophosphite (Na₂H₂PO₂) through aqueous solution free radical polymerization. The structural characterizations were done using FT-IR and ¹H NMR. The molecular weight of polymer was analyzed using GPC and residual monomer levels in final product were measured with HPLC. Measured the ceramic flow times, viscosities at dispersant dosage rate 0.30 % (dry slurry based) and the results indicated that linear polycarboxylate showed a good performance at the mol ratios of GAA:MA:SMAS = 60:20:20, ratios of initiator (Na₂S₂O₈) and chain transfer agents (Na₂H₂PO₂) 2:6 % at, 85 ºC polymerization temperature and 2 h reaction time.

Keywords

Dispersant Polycarboxylate Acrylic acid Maleic anhydride Sodium methallylsulfonate Redox initiator Viscosity

Kommanapalli, K. K., Lyot, P., Sunkara, J. R., Checule, P., & Hari Haran, A. (2018). Synthesis and Characterization of Linear Polycarboxylate Dispersant of Glacial Acrylic Acid−Maleic Acid−Sodium Methallylsulfonate for Ceramics. Asian Journal of Chemistry, 30(5), 983–987. https://doi.org/10.14233/ajchem.2018.21076

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References

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References

H. Fei and X. Wei, Shandong Ceram., 22, 594 (2012).

S.-H. Zhang, M. Zhang and J.-T. Jia, Bull. Chinese Ceram. Soc., 32, 677 (2013).

S.-F. Guo, Y.-X. Pang and Y.H. Deng, Fine Chem., 28, 594 (2011).

M. Eygi and G. Atesok, Ceram. Int., 34, 1903 (2008); https://doi.org/10.1016/j.ceramint.2007.07.012.

A.A. Zaman, R. Tsuchiya and B.M. Moudgil, J. Colloid Interface Sci., 256, 73 (2002); https://doi.org/10.1006/jcis.2001.7941.

C.Q. Yang and X. Gu, J. Appl. Polym. Sci., 81, 223 (2001); https://doi.org/10.1002/app.1432.

K.A. Hughes and G. Swift, Low Molecular Weight Water Soluble Phosphinate and Phosphonate Containing Polymers, US Patent 5077361 (1991).

B. Urtel, R. Wirschem, E. Heintz and D. Faul Phosphorus-Containing Low Molecular Weight Polyacrylic Acid as a Dispersant and its Use, Chinese Patent CN103403044B (2016).

F. Gauthier, Y. Duccini, D. Witiak, B. Weinstein and R. Porter, Detergent Formulations Comprising at Least One Water Soluble Polymer, or Salt Thereof, Bearing a Phosphonate Group, US Patent 6489287 B1 (2002).

T.F. McCallum III and B. Weinstein, Process for Preparing PhosphonateTerminated Polymers, US Patent 5866664 (1999).

J. Detering, B. Urtel, S. Nied and E. Heintz, Low Molecular Weight Phosphorus-Containing Polyacrylic Acids and Use Thereof as Scale Inhibitors in Water-Carrying Systems, US Patent 2012/0199783 (2012).

S. Yamaguchi, Poly(meth)acrylic Acid-Based Polymer Composition, US Patent 9469936 (2016).

L.G. Dammann, Process for Preparing Low Molecular Weight WaterSoluble Polymers by Copolymerizing with Water-Soluble Monomers a Calculated Quantity of Methallylsulfonate Monomer, US Patent 4451628 (1984).

S.-R.T. Chen and C.W. Vaughan, Method for Controlling Scale Deposition in Aqueous Systems using Allyl Sulfonate/Maleic Anhydride Polymers, US Patent 5000856 (1991).

Y.-S. Ye, H.-L. Huang and K.-C. Hsu, J. Appl. Polym. Sci., 100, 2490 (2006); https://doi.org/10.1002/app.23606.

B.-A. Chen, Bull. Chinese Ceramic Soc., 31, 9 (2014).

B. Weinstein, W.C. Vinci and K.B. Laughlin, Method of Preparing a Polymer, Chinese Patent CN101445569 A (2008).

M. Creamer, R. Krasnansky, J. Manna and D.C. Santos, Process for Grinding Minerals in Aqueous Dispersion Using a Dispersing Agent Comprising Homopolymers and/or Copolymers of (Meth)acrylic Acid, EP 20090306266 (2009).

S. Tamaki, K. Kamei, K. Osaki, K. Naitou, K. Kano, T. Yoshimura, N. Tanaka and S. Hiramatsu, Process for Production of Carboxylic Acid Polymers, EP Patent 20020785953 (2004).

Y. Duccini and A. Dufour, Dispersion of Granular Solid, Japanes Patent JP 2001070778A (2001).

L. Behal and D. Schelker, ed.: J.B. Wachtman, Effects of Polyacrylate and Sodium Silicate Dispersant on Plaster Mold Characteristics, In: A Collection of Papers Presented at the 97th Annual Meeting and the 1995 Fall Meetings of the Materials & Equipment/Whitewares: Ceramic Engineering and Science Proceedings, John Wiley & Sons, Inc., Hoboken, NJ, USA, vol. 17, Issue 1 (1996); https://doi.org/10.1002/9780470314807.ch4.

B.Y. Jiang, H.-G. Ji, B. Liao, H.-L. Liu and H. Pang, Fine Chem., 28, 1004 (2011).

K. Cui, X.-L. Zou and Y.-J. Lan, Fine Chem., 24, 179 (2010).

Q.-Q. Huang, B. Liao, B.-Y. Jiang, B. Wang, H.-G. Ji, J.-H. Huang and H. Pang, Fine Chem., 27, 338 (2013).

L. Liu, G.-H. Zhang, X.L. Fu, R. Xiang, Z.Q. He and Y.-B. Li, Fine Chem., 28, 505 (2014).

M. Kramer, R. Krasnanski, J. Manner and D.C. Santos, Methods of Using Dispersants to Grind Minerals in Aqueous Dispersions, Chinese Patent CN101550291B (2012).

Y. Zhang, L. Meng and L. Meng, Chinese Ceram., 46, 65 (2010).

E. Sakai, K. Yamada and A. Ohta, J. Adv. Concr. Technol., 1, 16 (2003); https://doi.org/10.3151/jact.1.16.

J.H. Yang, X.Q. He, H. Wang and M.F. Chen, Foshan Ceram., 9, 4 (2005).

D.J. Gale, Copolymers of Maleic Acid and Acrylic Acid, US Patent 3635915 (1972).

Issue

Vol. 30 No. 5 (2018): Vol 30 Issue 5, 2018

Synthesis and Characterization of Linear Polycarboxylate Dispersant of Glacial Acrylic Acid−Maleic Acid−Sodium Methallylsulfonate for Ceramics

Corresponding Author(s) : Kiran Kumar Kommanapalli

Abstract

Keywords

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