Synthesis and Characterization of New Azo 4,5-dimethyl-2-((3-((E)-1-(2-phenylhydrazono)ethyl)phenyl)diazenyl)-1H-imidazole and its Metal(II) Complexes

Waleed A. Mahmoud; Amir Musa; Nadia H. Obaid

doi:10.14233/ajchem.2018.20982

Issue

Vol. 30 No. 3 (2018): Vol 30 Issue 3

Issue Published : January 31, 2018

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of New Azo 4,5-dimethyl-2-((3-((E)-1-(2-phenylhydrazono)ethyl)phenyl)diazenyl)-1H-imidazole and its Metal(II) Complexes

https://doi.org/10.14233/ajchem.2018.20982

Waleed A. Mahmoud

Department of Chemistry, College of Science for Women, Baghdad University, Baghdad, Iraq

Amir Musa

Department of Chemistry, College of Science, Kufa University, Kufa, Iraq

Nadia H. Obaid

Department of Chemistry, College of Education for Girl, Kufa University, Kufa, Iraq

Corresponding Author(s) : Waleed A. Mahmoud

waleed56ali@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 3 (2018): Vol 30 Issue 3
Article Published : January 31, 2018

Abstract

In this paper, a new azo ligand, 4,5-dimethyl-2-((3-((E)-1-(2-phenylhydrazono)ethyl)phenyl)diazenyl)-1H-imidazole (DPDPIH) and its metal complexes were synthesized. The ligand (DPDPIH) and its metal complexes were characterized by elemental, IR, ¹H NMR electronic and mass spectra. The values of elemental microanalysis and metal contents were in good agreement with the calculated values. The molar conductivity indicated that all these metal complexes were non-electrolyte in nature. The magnetic susceptibility values indicated that all the metal complexes were paramagnetic except cadmium and zinc complexes.

Keywords

Imidazole derivative Metal complexes

Mahmoud, W. A., Musa, A., & Obaid, N. H. (2018). Synthesis and Characterization of New Azo 4,5-dimethyl-2-((3-((E)-1-(2-phenylhydrazono)ethyl)phenyl)diazenyl)-1H-imidazole and its Metal(II) Complexes. Asian Journal of Chemistry, 30(3), 551–555. https://doi.org/10.14233/ajchem.2018.20982

Download Citation

References

D. Setamdideh, B. Khezri and M. Rahmatollahzadeh, J. Serb. Chem. Soc., 78, 1 (2013); https://doi.org/10.2298/JSC120111044S.
S. Senapati, S.K. Jasimuddin and C. Sinha, Indian J. Chem., 45A, 1153 (2006).
U.S. Ray, D. Banerjee and C. Sinha, Proc. Indian Acad. Sci. Chem., 115, 169 (2003); https://doi.org/10.1007/BF02704256.
H. Debus, Annalen. Pharm., 107, 199 (1858); https://doi.org/10.1002/jlac.18581070209.
A. Albert and E.P. Serjeant, Ionization Constants of Acids and Bases, John Wiley & Sons, New York (1962).
M.H. Jebur, R.T. Mahdi and A.M. Ali, Asian J. Res. Chem., 6, 1156 (2013).
H.P. Patel and J.M. Tedder, J. Chem. Soc., 4589 (1963); https://doi.org/10.1039/jr9630004589.
K. Hoffman, Imidazole and its Derivatives, Interscience, New York, 143-145 (1953).
W.A. Mahmoud, M.A. Habiban and T.A. Kareem, Baghdad Sci. J., 12, 503 (2015).
M.A. Habiban, W.A. Mahmoud and T.A. Kareem, Baghdad Sci. J., 12, 96 (2015).
R.J.M. Klein Gebbink, R.T. Jonas, C.R. Goldsmith and T.D.P. Stack, Inorg. Chem., 41, 4633 (2002); https://doi.org/10.1021/ic025617r
A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier Publishing Co. Ltd., New York (1984).
E. Erdem, E.Y. Sari, R. Kilincarslan and N. Kabay, Transition Met. Chem., 34, 167 (2009); https://doi.org/10.1007/s11243-008-9173-9.
H. Golchoubian, W.L. Waltz and J.W. Quail, Can. J. Chem., 77, 37 (1999); https://doi.org/10.1139/v98-208.
R.A. Ammar and A.N. Alghaz, Int. J. Electrochem. Sci., 8, 8686 (2013).
A.T. Numan, K.M. Sultan and A.S. Abdullah, J. Ibn Al-Haitham Pure Appl. Sci., 33, 1 (2009).
B.A. Jassim, M.Sc. Thesis, College of Science for Women, University of Baghdad, Baghdad, Iraq (2014).
A.S. Shaker and F. Yong, Amer. J. Sci. Res., 5, 20 (2009).
A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier Publishing Co. Ltd., New York (1988).
M.S. Suresh and V. Prakash, J. Physiol. Sci., 5, 2203 (2010).
N.K.G. Aziz, Ph.D. Thesis, College of Science for Women, University of Baghdad, Baghdad, Iraq (2016).
I. Ferracane, Materials in Density: Principles and Applications, Lippincott Williams and Willikins (2001).
G. Hughes and N.R. McLean, Emerg. Med. J., 5, 223 (1988); https://doi.org/10.1136/emj.5.4.223.
C. Guillard, C. Puzenat, E.H. Lachheb, A. Houas and J. Herrmann, Int. J. Photoenergy, 7, 1 (2005); https://doi.org/10.1155/S1110662X05000012.
W.A. Mahmoud, A.S. Al-Hamdani and B.A. Jasim, Res. J. Pharm. Biol. Chem. Sci., 8, 305 (2017).
M.B. Halli, K. Mallikarjun and S. Surykant, J. Chem. Pharm. Res., 7, 1797 (2015).
K.J. Al-Adilee, A.K. Abass and A.M. Taher, J. Mol. Struct., 1108, 378 (2016); https://doi.org/10.1016/j.molstruc.2015.11.038.

References

D. Setamdideh, B. Khezri and M. Rahmatollahzadeh, J. Serb. Chem. Soc., 78, 1 (2013); https://doi.org/10.2298/JSC120111044S.

S. Senapati, S.K. Jasimuddin and C. Sinha, Indian J. Chem., 45A, 1153 (2006).

U.S. Ray, D. Banerjee and C. Sinha, Proc. Indian Acad. Sci. Chem., 115, 169 (2003); https://doi.org/10.1007/BF02704256.

H. Debus, Annalen. Pharm., 107, 199 (1858); https://doi.org/10.1002/jlac.18581070209.

A. Albert and E.P. Serjeant, Ionization Constants of Acids and Bases, John Wiley & Sons, New York (1962).

M.H. Jebur, R.T. Mahdi and A.M. Ali, Asian J. Res. Chem., 6, 1156 (2013).

H.P. Patel and J.M. Tedder, J. Chem. Soc., 4589 (1963); https://doi.org/10.1039/jr9630004589.

K. Hoffman, Imidazole and its Derivatives, Interscience, New York, 143-145 (1953).

W.A. Mahmoud, M.A. Habiban and T.A. Kareem, Baghdad Sci. J., 12, 503 (2015).

M.A. Habiban, W.A. Mahmoud and T.A. Kareem, Baghdad Sci. J., 12, 96 (2015).

R.J.M. Klein Gebbink, R.T. Jonas, C.R. Goldsmith and T.D.P. Stack, Inorg. Chem., 41, 4633 (2002); https://doi.org/10.1021/ic025617r

A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier Publishing Co. Ltd., New York (1984).

E. Erdem, E.Y. Sari, R. Kilincarslan and N. Kabay, Transition Met. Chem., 34, 167 (2009); https://doi.org/10.1007/s11243-008-9173-9.

H. Golchoubian, W.L. Waltz and J.W. Quail, Can. J. Chem., 77, 37 (1999); https://doi.org/10.1139/v98-208.

R.A. Ammar and A.N. Alghaz, Int. J. Electrochem. Sci., 8, 8686 (2013).

A.T. Numan, K.M. Sultan and A.S. Abdullah, J. Ibn Al-Haitham Pure Appl. Sci., 33, 1 (2009).

B.A. Jassim, M.Sc. Thesis, College of Science for Women, University of Baghdad, Baghdad, Iraq (2014).

A.S. Shaker and F. Yong, Amer. J. Sci. Res., 5, 20 (2009).

A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier Publishing Co. Ltd., New York (1988).

M.S. Suresh and V. Prakash, J. Physiol. Sci., 5, 2203 (2010).

N.K.G. Aziz, Ph.D. Thesis, College of Science for Women, University of Baghdad, Baghdad, Iraq (2016).

I. Ferracane, Materials in Density: Principles and Applications, Lippincott Williams and Willikins (2001).

G. Hughes and N.R. McLean, Emerg. Med. J., 5, 223 (1988); https://doi.org/10.1136/emj.5.4.223.

C. Guillard, C. Puzenat, E.H. Lachheb, A. Houas and J. Herrmann, Int. J. Photoenergy, 7, 1 (2005); https://doi.org/10.1155/S1110662X05000012.

W.A. Mahmoud, A.S. Al-Hamdani and B.A. Jasim, Res. J. Pharm. Biol. Chem. Sci., 8, 305 (2017).

M.B. Halli, K. Mallikarjun and S. Surykant, J. Chem. Pharm. Res., 7, 1797 (2015).

K.J. Al-Adilee, A.K. Abass and A.M. Taher, J. Mol. Struct., 1108, 378 (2016); https://doi.org/10.1016/j.molstruc.2015.11.038.

Issue

Vol. 30 No. 3 (2018): Vol 30 Issue 3

Synthesis and Characterization of New Azo 4,5-dimethyl-2-((3-((E)-1-(2-phenylhydrazono)ethyl)phenyl)diazenyl)-1H-imidazole and its Metal(II) Complexes

Corresponding Author(s) : Waleed A. Mahmoud

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents