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This work is licensed under a Creative Commons Attribution 4.0 International License.
UV Protection and Antibacterial Treatment of Wool using Green Silver Nanoparticles
Corresponding Author(s) : Sakil Mahmud
Asian Journal of Chemistry,
Vol. 30 No. 1 (2018): Vol 30 Issue 1
Abstract
Herein, we attempted a new green based silver nanoparticles employing sodium alginate (Na-Alg) as reducing agent to functionalize wool fabric surface. This research aims to enhance the antimicrobial activity and UV resistance of wool fabrics treated with synthesized silver nanoparticles. The resulting products were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy spectra (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA) and UV-visible absorbance. The results specified that silver nanoparticles (AgNPs) were successfully assembled on wool surface when liquor pH and temperature of application medium were adjusted to 4 and 40 ºC, respectively for 2 h. Thermogravimetric analysis indicated that the combined finishing of wool fabric with AgNPs could improve its thermal property. It was observed that the presence of green based AgNPs significantly enhanced the UV resistance and antibacterial activity of fabrics particularly for samples coated with 70 ppm AgNPs. These promising results support that the present approach is useful for the fabrication of antimicrobial and UV protector fabrics.
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S.-S. Sun and R.-C. Tang, Ind. Eng. Chem. Res., 50, 4217 (2011); https://doi.org/10.1021/ie101505q.
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R. Dastjerdi and M. Montazer, Colloids Surf. B Biointerfaces, 79, 5 (2010); https://doi.org/10.1016/j.colsurfb.2010.03.029.
L. Hadad, N. Perkas, Y. Gofer, J. CalderonMoreno, A. Ghule and A. Gedanken, J. Appl. Polym. Sci., 104, 1732 (2007); https://doi.org/10.1002/app.25813.
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N. Choi, D. Seo and J. Lee, Mater. Sci. Forum, 29, 394 (2005).
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J.A. Maclaren and B. Milligan, Wool Science: The Chemical Reactivity of the Wool Fibre, Science Press: Marrickville, Australia, vol. 122. (1981).
M. Pollini, F. Paladini,A. Licciulli,A. Maffezzoli, L. Nicolais and A. Sannino, J. Appl. Polym. Sci., 125, 2239 (2012); https://doi.org/10.1002/app.36444.
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H.Y. Ki, J.H. Kim, S.C. Kwon and S.H. Jeong, J. Mater. Sci., 42, 8020 (2007); https://doi.org/10.1007/s10853-007-1572-3.
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K.G. Stamplecoskie and J.C. Scaiano, J. Am. Chem. Soc., 132, 1825 (2010); https://doi.org/10.1021/ja910010b.
E. Abdel-Halim and S.S. Al-Deyab, Carbohydr. Polym., 86, 1615 (2011); https://doi.org/10.1016/j.carbpol.2011.06.072.
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A. Mandal, S. Sekar, N. Chandrasekaran,A. Mukherjee and T.P. Sastry, RSC Adv., 5, 15763 (2015); https://doi.org/10.1039/C4RA09694K.
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M. El-Rafie, M. El-Naggar, M. Ramadan, M.M. Fouda, S.S. Al-Deyab and A. Hebeish, Carbohydr. Polym., 86, 630 (2011); https://doi.org/10.1016/j.carbpol.2011.04.088.
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T. Briggs and A. Bull, J. Phys. Chem., 26, 845 (1921); https://doi.org/10.1021/j150225a005.
B. Tang, J. Wang, S. Xu, T. Afrin, W. Xu, L. Sun and X. Wang, J. Colloid Interface Sci., 356, 513 (2011); https://doi.org/10.1016/j.jcis.2011.01.054.
D.G. King and A.P. Pierlot, Color. Technol., 125, 111 (2009); https://doi.org/10.1111/j.1478-4408.2009.00182.x.
S.H. Hsieh, Z. Huang, Z. Huang and Z. Tseng, J. Appl. Polym. Sci., 94, 1999 (2004); https://doi.org/10.1002/app.21104.
P.P. Bose, M.G. Drew and A. Banerjee, Org. Lett., 9, 2489 (2007); https://doi.org/10.1021/ol0708471.
P.J. Davies,A.R. Horrocks and M. Miraftab, Polym. Int., 49, 1125 (2000); https://doi.org/10.1002/1097-0126(200010)49:10<1125::AIDPI489>3.0.CO;2-B.
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H.E. Emam and T. Bechtold, Appl. Surf. Sci., 357, 1878 (2015); https://doi.org/10.1016/j.apsusc.2015.09.095.
M. Gorenšek and P. Recelj, Text. Res. J., 77, 138 (2007); https://doi.org/10.1177/0040517507076329.
C.-H. Xue, J. Chen, W. Yin, S.-T. Jia and J.-Z. Ma, Appl. Surf. Sci., 258, 2468 (2012); https://doi.org/10.1016/j.apsusc.2011.10.074.
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M. Saito, J. Coated Fabrics, 23, 150 (1993); https://doi.org/10.1177/152808379302300205.