Issue

Vol. 30 No. 12 (2018): Vol 30 Issue 12

Copyright (c) 2018 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Influence of Temperature and Concentration of Capping Molecule and bis(N-Cyclohexyl-2-hydroxy-1-naphthaldehydato)manganese(II) as Single Source Precursor for Synthesis of TOPO Capped Mn3O4 Nanoparticles

https://doi.org/10.14233/ajchem.2018.21505%20
T. Xaba
Department of Chemistry, Vaal University of Technology, P/Bag X021, Vanderbijlpark, South Africa

Corresponding Author(s) : T. Xaba

thokozanix@vut.ac.za

Asian Journal of Chemistry, Vol. 30 No. 12 (2018): Vol 30 Issue 12

Abstract

In this study, the effect of temperature, amount of the precursor and the concentration of the stabilizer on the synthesis of manganese oxide nanoparticles using bis(N-cyclohexyl-2-hydroxy-1-naphthaldehydato)manganese(II) complex has been investigated. The precursor was prepared from the chemical reaction of 2-hydroxy-1-naphthaldehyde, amine and manganese salt. The resulting precursor was thermally decomposed into tri-n-octylphosphine oxide (TOPO) to synthesize TOPO capped manganese oxide nanoparticles at the temperature ranging from 120 to 200 ºC. Various instruments were used to characterize the prepared complex and manganese nanoparticles. The optical band gaps energies of the nanoparticles were decreasing from 1.48 to 1.35 eV when the decomposition temperature was increased.

Keywords

Manganese complex Tri-n-octylphosphine oxide Manganese oxide Nanoparticles Semiconductors
Xaba, T. (2018). Influence of Temperature and Concentration of Capping Molecule and bis(N-Cyclohexyl-2-hydroxy-1-naphthaldehydato)manganese(II) as Single Source Precursor for Synthesis of TOPO Capped Mn3O4 Nanoparticles. Asian Journal of Chemistry, 30(12), 2652–2658. https://doi.org/10.14233/ajchem.2018.21505
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. V. Arun, N. Sridevi, P.P. Robinson, S. Manju and K.K.M. Yusuff, J. Mol. Catal. Chem., 304, 191 (2009); https://doi.org/10.1016/j.molcata.2009.02.011.
  2. K.C. Gupta and A.K. Sutar, Coord. Chem. Rev., 252, 1420 (2008); https://doi.org/10.1016/j.ccr.2007.09.005.
  3. Y.-B. Dong, H.-Q. Zhang, J.-P. Ma, R.-Q. Huang and C.-Y. Su, Cryst. Growth Des., 5, 1857 (2005); https://doi.org/10.1021/cg0501534.
  4. A.K. Ghosh, D. Ghoshal, J. Ribas, G. Mostafa and N.R. Chaudhuri, Cryst. Growth Des., 6, 36 (2006); https://doi.org/10.1021/cg050423i.
  5. P. Phuengphai, S. Youngme, P. Kongsaeree, C. Pakawatchai, N. Chaichit, S.J. Teat, P. Gamez and J. Reedijk, CrystEngComm, 11, 1723 (2009); https://doi.org/10.1039/b901607d.
  6. P.A. Vigato and S. Tamburini, Coord. Chem. Rev., 248, 1717 (2004); https://doi.org/10.1016/j.cct.2003.09.003.
  7. D. Pucci, A. Bellusci, A. Crispini, M. Ghedini and M. La Deda, Inorg. Chim. Acta, 357, 495 (2004); https://doi.org/10.1016/j.ica.2003.08.015.
  8. C. Biswas, M.G.B. Drew, A. Figuerola, S. Gómez-Coca, E. Ruiz, V. Tangoulis and A. Ghosh, Inorg. Chim. Acta, 363, 846 (2010); https://doi.org/10.1016/j.ica.2009.12.048.
  9. K. Fan, C. Cao, Y. Pan, D. Lu, D. Yang, J. Feng, L. Song, M. Liang and X. Yan, Nat. Nanotechnol., 7, 459 (2012); https://doi.org/10.1038/nnano.2012.90.
  10. C.R. Olsen, T.J. Smith, J.S. Embley, J.H. Maxfield, K.R. Hansen, J.R. Peterson, A.M. Henrichsen, S.D. Erickson, D.C. Buck, J.S. Colton and R.K. Watt, Nanotechnology, 28, 195601 (2017); https://doi.org/10.1088/1361-6528/aa68ae.
  11. H.-Y. Su, Y. Gorlin, I.C. Man, F. Calle-Vallejo, J.K. Nørskov, T.F. Jaramillo and J. Rossmeisl, J. Phys. Chem. Chem. Phys., 14, 14010 (2012); https://doi.org/10.1039/c2cp40841d.
  12. A. Ramírez, D. Friedrich, M. Kunst and S. Fiechter, Chem. Phys. Lett., 568-569, 157 (2013); https://doi.org/10.1016/j.cplett.2013.03.054.
  13. M.M. Najafpour, F. Rahimi, M. Amini, S. Nayeri and M. Bagherzadeh, Dalton Trans., 41, 11026 (2012); https://doi.org/10.1039/c2dt30553d.
  14. S.L. Brock, N. Duan, Z.R. Tian, O. Giraldo, H. Zhou and S.L. Suib, Chem. Mater., 10, 2619 (1998); https://doi.org/10.1021/cm980227h.
  15. S.L. Suib, J. Mater. Chem., 18, 1623 (2008); https://doi.org/10.1039/b714966m.
  16. X. Fang, X. Lu, X. Guo, Y. Mao, Y.S. Hu, J. Wang, Z. Wang, F. Wu, H. Liu and L. Chen, Electrochem. Commun., 12, 1520 (2010); https://doi.org/10.1016/j.elecom.2010.08.023.
  17. W.S. Seo, H.H. Jo, K. Lee, B. Kim, S.J. Oh and J.T. Park, Angew. Chem. Int. Ed., 43, 1115 (2004); https://doi.org/10.1002/anie.200352400.
  18. S.T. Myung, S. Komaba and N. Kumagai, Electrochim. Acta, 47, 3287 (2002); https://doi.org/10.1016/S0013-4686(02)00248-7.
  19. Y. Lvov, B. Munge, O. Giraldo, I. Ichinose, S.L. Suib and J.F. Rusling, Langmuir, 16, 8850 (2000); https://doi.org/10.1021/la000110j.
  20. X.-L. Luo, J.-J. Xu, W. Zhao and H.-Y. Chen, Biosens. Bioelectron., 19, 1295 (2004); https://doi.org/10.1016/j.bios.2003.11.019.
  21. X. Liu, C. Chen, Y. Zhao and B. Jia, J. Nanomater., Article ID 736375 (2013); https://doi.org/10.1155/2013/736375.
  22. R. Ramprasath, G. Kalpana and T. Pandiselvi, Impl. J. Interdiscipl. Res., 2, 1409 (2016).
  23. M.M. Najafpour, F. Rahimi, E.-M. Aro, C.-H. Lee and S.I. Allakhverdiev, J. R. Soc. Interface, 9, 2383 (2012); https://doi.org/10.1098/rsif.2012.0412.
  24. Y.Q. Chang, X.Y. Xu, X.H. Luo, C.P. Chen and D.P. Yu, J. Cryst. Growth, 264, 232 (2004); https://doi.org/10.1016/j.jcrysgro.2003.11.117.
  25. S.K. Park, A. Jin, S.H. Yu, J. Ha, B. Jang, S. Bong, S. Woo, Y.E. Sung and Y. Piao, Electrochim. Acta, 120, 452 (2014); https://doi.org/10.1016/j.electacta.2013.12.018.
  26. H. Chang, Y. Guo, L. Yang, Q. Liu, W. Feng, J. Liang and G. Rao, J. Solid State Chem., 177, 4341 (2004); https://doi.org/10.1016/j.jssc.2004.07.040.
  27. E. Finocchio and G. Busca, Catal. Today, 70, 213 (2001); https://doi.org/10.1016/S0920-5861(01)00419-9.
  28. S.K. Apte, S.D. Naik, R.S. Sonawane, B.B. Kale, N. Pavaskar, A.B. Mandale and B.K. Das, Mater. Res. Bull., 41, 647 (2006); https://doi.org/10.1016/j.materresbull.2005.08.028.
  29. Z.W. Chen, J.K.L. Lai and C.H. Shek, Scr. Mater., 55, 735 (2006); https://doi.org/10.1016/j.scriptamat.2006.05.041.
  30. M. Salavati-Niasari, F. Davar and M. Mazaheri, Poly., 27, 3467 (2008); https://doi.org/10.1016/j.poly.2008.04.015.
  31. X. Tai, X. Yin, Q. Chen and M. Tan, Molecules, 8, 439 (2003); https://doi.org/10.3390/80500439.
  32. T. Ozkaya, A. Baykal, H. Kavas, Y. Ko¨seog¢lu and M.S. Toprak, Physica B, 403, 3760 (2008); https://doi.org/10.1016/j.physb.2008.07.002.
  33. L. He, G. Zhang, Y. Dong, Z. Zhang, S. Xue and X. Jiang, Nano-Micro Lett., 6, 38 (2014); https://doi.org/10.1007/BF03353767.
  34. M. Wang, G.-H. Lee, Y. Wang, T.-Y. Dong and H.-H. Wei, J. Chin. Chem. Soc., 49, 825 (2002); https://doi.org/10.1002/jccs.200200118.
  35. R. Vafazadeh, V. Hayeri and A.C. Willis, Polyhedron, 29, 1810 (2010); https://doi.org/10.1016/j.poly.2010.02.030.
  36. T. Akitsu and Y. Einaga, Polyhedron, 25, 1089 (2006); https://doi.org/10.1016/j.poly.2005.07.048.
  37. M. Sebastian, V. Arun, P.P. Robinson, A.A. Varghese, R. Abraham, E. Suresh and K.K.M. Yusuff, Polyhedron, 29, 3014 (2010); https://doi.org/10.1016/j.poly.2010.08.016.
  38. W. Xiao, J.S. Chen and X.W.D. Lou, CrystEngComm, 13, 5685 (2011); https://doi.org/10.1039/c1ce05711a.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 2 Download : 0