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Removal of Dye Bismarck Brown G by Photocatalytic Reaction over Prepared Co-Oxide Cr2O3-NiO: A Kinetic Study
Corresponding Author(s) : Abbas J. Atiyah
Asian Journal of Chemistry,
Vol. 30 No. 11 (2018): Vol 30 Issue 11
Abstract
The co-oxides Cr2O3-NiO was prepared by using a co-precipitation method. The co-oxides were prepared by calcination temperatures at 500 ºC. The prepared materials were investigated using powder X-rays diffraction and Fourier transform infrared spectroscopy. The photocatalytic activity of prepared co-oxides was examined by removing Bismarck brown G dye from simulated industrial wastewaters. From the obtained results, the best efficiency for Bismarck brown G dye removal was found to be around 97. 5 %. This was achieved at optimal reaction conditions which were pH = 4, weight of catalyst 0.15 g, T = 303 K and time of reaction was 1 h. Both of Frundlich and Langmuir adsorption isotherms were studied.
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N. Popovici, M.L. Paramês, R.C. Da Silva, O. Monnereau, P.M. Sousa, A.J. Silvestre and O. Conde, Appl. Phys., A Mater. Sci. Process., 79, 1409 (2004); https://doi.org/10.1007/s00339-004-2795-7.
V.M. Bermudez and W.J. DeSisto, J. Vac. Sci. Technol. A, 19, 576 (2001); https://doi.org/10.1116/1.1339008.
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Y. Ogino and S. Nakajima, J. Catal., 9, 251 (1967); https://doi.org/10.1016/0021-9517(67)90250-3.
T. Robinson, G. McMullan, R. Marchant and P. Nigam, Bioresour. Technol., 77, 247 (2001); https://doi.org/10.1016/S0960-8524(00)00080-8.
D. Georgiou, P. Melidis, A. Aivasidis and K. Gimouhopoulos, Dyes Pigments, 52, 69 (2002); https://doi.org/10.1016/S0143-7208(01)00078-X.
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N. Serpone, J. Adv. Oxid. Technol., 2, 203 (1997); https://doi.org/10.1515/jaots-1997-0104.
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J.E. LennardJones, Trans. Faraday Soc., 28, 333 (1932); https://doi.org/10.1039/tf9322800333.
A.F. Halbus, A.J. Lafta, Z.H. Athab and F.H. Hussein, Asian J. Chem., 26S, 167 (2014); https://doi.org/10.14233/ajchem.2014.19038.
J.C. Maxwell, Nature, 11, 357 (1975); https://doi.org/10.1038/011357a0.
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I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); https://doi.org/10.1021/ja02242a004.
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E.T. Soares, M.A. Lansarin and C.C. Moro, Braz. J. Chem. Eng., 24, 29 (2007).
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S. Suslick, Science, 247, 1439 (1990); https://doi.org/10.1126/science.247.4949.1439.
T. Narendra, A. Oza and S. Ingale, J. Environ. Res. Technol., 4, 165 (2014).
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S.K. Kansal, N. Kaur and S. Singh, Nano. Res. Let., 4, 709 (2009); https://doi.org/10.1007/s11671-009-9300-3.
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