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Adsorption of Acid Orange 33 Dye by Bentonite and Surfactant Modified Bentonite
Corresponding Author(s) : Mark Jeeva
Asian Journal of Chemistry,
Vol. 30 No. 11 (2018): Vol 30 Issue 11
Abstract
The batch adsorption of acid orange 33 from water onto Na-bentonite and CTAB-modified bentonite (CTAB-Ben) was studied. The effects of varying factors, such as initial dye concentration, adsorbent dosage, pH, contact time and temperature, which influence the adsorption capacities of Na-bentonite and CTAB-modified bentonite were investigated and discussed. The results revealed that the adsorption capacities of CTAB-modified bentonite toward acid orange 33 were higher than those of Na-bentonite. The maximum adsorption efficiency of CTAB-modified bentonite was 50 mg/g when acid orange 33 concentration, adsorbent dosage, reaction time and equilibrium pH were 50 mg/L, 80 mg, 90 min and 2, respectively. The isotherm study results for CTAB-Ben satisfactorily fit the Langmuir (R2 > 0.959) and Freundlich (R2 > 0.957) models. The calculated values of the thermodynamic parameters ΔG, ΔH and ΔS showed that the adsorption was a spontaneous and endothermic reaction.
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- M.S. Chiou, P.Y. Ho and H.Y. Li, Dyes Pigments, 60, 69 (2004); https://doi.org/10.1016/S0143-7208(03)00140-2.
- K.C. Chen, J.Y. Wu, C.C. Huang, Y.M. Liang and S.C. Hwang, J. Biotechnol., 101, 241 (2003); https://doi.org/10.1016/S0168-1656(02)00362-0.
- O.J. Hao, H. Kim and P.-C. Chiang, Crit. Rev. Environ. Sci. Technol., 30, 449 (2000); https://doi.org/10.1080/10643380091184237.
- S. Kara, C. Aydiner, E. Demirbas, M. Kobya and N. Dizge, Desalination, 212, 282 (2007); https://doi.org/10.1016/j.desal.2006.09.022.
- S. Wang and E. Ariyanto, J. Colloid Interface Sci., 314, 25 (2007); https://doi.org/10.1016/j.jcis.2007.05.032.
- C. Namasivayam and D.J.S.E. Arasi, Chemosphere, 34, 401 (1997); https://doi.org/10.1016/S0045-6535(96)00385-2.
- A.S. Ozcan, B. Erdem and A. Ozcan, J. Colloid Interface Sci., 280, 44 (2004); https://doi.org/10.1016/j.jcis.2004.07.035.
- B. Zohra, K. Aicha, S. Fatima, B. Nourredine and D. Zoubir, Chem. Eng. J., 136, 295 (2008); https://doi.org/10.1016/j.cej.2007.03.086.
- S.S. Tahir and N. Rauf, Chemosphere, 63, 1842 (2006); https://doi.org/10.1016/j.chemosphere.2005.10.033.
- N. Jovic-Jovicic, A. Milutinovic-Nikolic, I. Grzetic and D. Jovanovic, Chem. Eng. Technol., 31, 567 (2008); https://doi.org/10.1002/ceat.200700421.
- W.T. Akl, A. Youssef and M. Al-Awadhi, J. Anal. Bioanal. Technol., 4, 172 (2013) https://doi.org/10.4172/2155-9872.1000e116.
- K.G. Bhattacharyya and S.S. Gupta, Sep. Purif. Technol., 50, 388 (2006); https://doi.org/10.1016/j.seppur.2005.12.014.
- S.H. Siregar, K. Wijaya, E.S. Kunarti, A. Syoufian and Suyanta, Asian J. Chem., 30, 25 (2018); https://doi.org/10.14233/ajchem.2018.20782.
- A. Czimerova, J. Bujdak and R. Dohrmann, Appl. Clay Sci., 34, 2 (2006); https://doi.org/10.1016/j.clay.2006.02.008.
- J. Pan and B. Guan, J. Hazard. Mater., 183, 341 (2010); https://doi.org/10.1016/j.jhazmat.2010.07.030.
- K.G. Bhattacharyya and A. Sarma, Dyes Pigments, 57, 211 (2003); https://doi.org/10.1016/S0143-7208(03)00009-3.
- W.T. Tsai, C.W. Lai and T.Y. Su, J. Hazard. Mater.,134, 169 (2006); https://doi.org/10.1016/j.jhazmat.2005.10.055.
- X. Jin, M. Jiang, J. Du and Z. Chen, J. Ind. Eng. Chem., 20, 3025 (2014); https://doi.org/10.1016/j.jiec.2013.11.038.
- W.T. Tsai, C.W. Lai and K.J. Hsien, Colloids Surf. A Physicochem. Eng. Asp., 297, 749 (2005); https://doi.org/10.1016/j.jcis.2005.10.058.
- O. Gok, A.S. Ozcan and A. Ozcan, Appl. Surf. Sci., 256, 5439 (2010); https://doi.org/10.1016/j.apsusc.2009.12.134.
- J. Guo, S. Chen, L. Liu, B. Li, P. Yang, L. Zhang and Y. Feng, J. Colloid Interface Sci., 382, 61 (2012); https://doi.org/10.1016/j.jcis.2012.05.044.
- M. Kiransan, R.D.C. Soltani, A. Hassani, S. Karaca and A. Khataee, J. Taiwan Instit. Chem. Eng., 45, 2565 (2014); https://doi.org/10.1016/j.jtice.2014.06.007.
References
M.S. Chiou, P.Y. Ho and H.Y. Li, Dyes Pigments, 60, 69 (2004); https://doi.org/10.1016/S0143-7208(03)00140-2.
K.C. Chen, J.Y. Wu, C.C. Huang, Y.M. Liang and S.C. Hwang, J. Biotechnol., 101, 241 (2003); https://doi.org/10.1016/S0168-1656(02)00362-0.
O.J. Hao, H. Kim and P.-C. Chiang, Crit. Rev. Environ. Sci. Technol., 30, 449 (2000); https://doi.org/10.1080/10643380091184237.
S. Kara, C. Aydiner, E. Demirbas, M. Kobya and N. Dizge, Desalination, 212, 282 (2007); https://doi.org/10.1016/j.desal.2006.09.022.
S. Wang and E. Ariyanto, J. Colloid Interface Sci., 314, 25 (2007); https://doi.org/10.1016/j.jcis.2007.05.032.
C. Namasivayam and D.J.S.E. Arasi, Chemosphere, 34, 401 (1997); https://doi.org/10.1016/S0045-6535(96)00385-2.
A.S. Ozcan, B. Erdem and A. Ozcan, J. Colloid Interface Sci., 280, 44 (2004); https://doi.org/10.1016/j.jcis.2004.07.035.
B. Zohra, K. Aicha, S. Fatima, B. Nourredine and D. Zoubir, Chem. Eng. J., 136, 295 (2008); https://doi.org/10.1016/j.cej.2007.03.086.
S.S. Tahir and N. Rauf, Chemosphere, 63, 1842 (2006); https://doi.org/10.1016/j.chemosphere.2005.10.033.
N. Jovic-Jovicic, A. Milutinovic-Nikolic, I. Grzetic and D. Jovanovic, Chem. Eng. Technol., 31, 567 (2008); https://doi.org/10.1002/ceat.200700421.
W.T. Akl, A. Youssef and M. Al-Awadhi, J. Anal. Bioanal. Technol., 4, 172 (2013) https://doi.org/10.4172/2155-9872.1000e116.
K.G. Bhattacharyya and S.S. Gupta, Sep. Purif. Technol., 50, 388 (2006); https://doi.org/10.1016/j.seppur.2005.12.014.
S.H. Siregar, K. Wijaya, E.S. Kunarti, A. Syoufian and Suyanta, Asian J. Chem., 30, 25 (2018); https://doi.org/10.14233/ajchem.2018.20782.
A. Czimerova, J. Bujdak and R. Dohrmann, Appl. Clay Sci., 34, 2 (2006); https://doi.org/10.1016/j.clay.2006.02.008.
J. Pan and B. Guan, J. Hazard. Mater., 183, 341 (2010); https://doi.org/10.1016/j.jhazmat.2010.07.030.
K.G. Bhattacharyya and A. Sarma, Dyes Pigments, 57, 211 (2003); https://doi.org/10.1016/S0143-7208(03)00009-3.
W.T. Tsai, C.W. Lai and T.Y. Su, J. Hazard. Mater.,134, 169 (2006); https://doi.org/10.1016/j.jhazmat.2005.10.055.
X. Jin, M. Jiang, J. Du and Z. Chen, J. Ind. Eng. Chem., 20, 3025 (2014); https://doi.org/10.1016/j.jiec.2013.11.038.
W.T. Tsai, C.W. Lai and K.J. Hsien, Colloids Surf. A Physicochem. Eng. Asp., 297, 749 (2005); https://doi.org/10.1016/j.jcis.2005.10.058.
O. Gok, A.S. Ozcan and A. Ozcan, Appl. Surf. Sci., 256, 5439 (2010); https://doi.org/10.1016/j.apsusc.2009.12.134.
J. Guo, S. Chen, L. Liu, B. Li, P. Yang, L. Zhang and Y. Feng, J. Colloid Interface Sci., 382, 61 (2012); https://doi.org/10.1016/j.jcis.2012.05.044.
M. Kiransan, R.D.C. Soltani, A. Hassani, S. Karaca and A. Khataee, J. Taiwan Instit. Chem. Eng., 45, 2565 (2014); https://doi.org/10.1016/j.jtice.2014.06.007.