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Vol. 30 No. 10 (2018): Vol 30 Issue 10, 2018

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Template Synthesis of Sn(II), Sn(IV) and Co(II) complexes via 3-Aminopropyltriethoxysilane and Salicylaldehyde and Evaluate their Antibacterial Sensitivity

https://doi.org/10.14233/ajchem.2018.21439
Hayder Hamied Mihsen
Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq
Suhad kreem Abass
Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq
Ali Kreem Abass
Department of Chemistry, College of Applied Medical Sciences, University of Kerbala, Kerbala, Iraq
Khalid A. Hussain
Department of Biology, College of Science, University of Kerbala, Kerbala, Iraq
Zainab Fadhil Abbas
Department of Biology, College of Science, University of Kerbala, Kerbala, Iraq

Corresponding Author(s) : Hayder Hamied Mihsen

hayder_alhmedawi@hotmail.com

Asian Journal of Chemistry, Vol. 30 No. 10 (2018): Vol 30 Issue 10, 2018

Abstract

Template method reaction of SnCl2·2H2O or SnCl4·5H2O or CoCl2·6H2O with 3-aminopropyltriethoxysilane and salicyaldehyde have been carried out to prepare three metal complexes; C32H53N2O8ClSnSi2 (A), C32H53N2O8Cl3SnSi2 (B) and C32H52N2O8CoSi2 (C). The prepared metal complexes were characterized by analytical techniques viz., FT-IR, 1H NMR, UV-visible, CHNS elemental and molar conductivity. The analytical data shows that the metal ion to ligand (Schiff base ) ratio in the prepared complexes was in 1:2. Octahedral structures were proposed for A and B complexes while C complex has a tetrahedral structure. The antibacterial activity of metal complexes were investigated against Streptococcus pneumoniae (Gram-negative) and Proteus (Gram-positive). The results showed that all the prepared complexes diminished the bacterial growth.

Keywords

Template method 3-Aminopropyltriethoxysilane Tin Cobalt Complexes Octahedral structure Antibacterial sensitivity
Mihsen, H. H., Abass, S. kreem, Abass, A. K., Hussain, K. . A., & Abbas, Z. F. (2018). Template Synthesis of Sn(II), Sn(IV) and Co(II) complexes via 3-Aminopropyltriethoxysilane and Salicylaldehyde and Evaluate their Antibacterial Sensitivity. Asian Journal of Chemistry, 30(10), 2277–2280. https://doi.org/10.14233/ajchem.2018.21439
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