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Vol. 30 No. 10 (2018): Vol 30 Issue 10, 2018

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Synthesis and Photophysical Investigations of Novel Transition Metal Complexes of Pyridine Tetrazole Ligands

https://doi.org/10.14233/ajchem.2018.21056
Rayees Ahmad Malik
Department of Chemistry, Faculty of Technology and Sciences, Lovely Professional University, Phagwara-144 411, India
Nawaz Gulzar Bhat
Department of Chemistry, Faculty of Technology and Sciences, Lovely Professional University, Phagwara-144 411, India
Renu Yadav
Department of Chemistry, Faculty of Technology and Sciences, Lovely Professional University, Phagwara-144 411, India
Navjot Singh
Department of Chemistry, Faculty of Technology and Sciences, Lovely Professional University, Phagwara-144 411, India
Gulshan Kumar
Department of Chemistry, Faculty of Technology and Sciences, Lovely Professional University, Phagwara-144 411, India
Suraj Mal
Department of Chemistry, Faculty of Technology and Sciences, Lovely Professional University, Phagwara-144 411, India

Corresponding Author(s) : Rayees Ahmad Malik

malikraqeeb111@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 10 (2018): Vol 30 Issue 10, 2018

Abstract

Two bidentate pyridine-tetrazole ligands viz. pyridine tetrazole (Hpytz) and pyridine tetrazole-N-oxide (Hpytzo), which are integrated in vitro from pyridine carbonitrile by thermal cycloaddition reaction with sodium azide for complexation with transition metals (Fe3+, Co2+, Ni2+, Zn2+ and Ru3+) to improve sophisticated photonic appliances in them as perceived in Ln (III) complexes. The configuration investigation of bis and tris-complexes was studied in solution by UV, FTIR and 1H NMR techniques. The hetero-nuclear pyridine tetrazole metal complexes display a close performance concerning the photo-physical properties as displayed by lanthanide(III) complexes and conventional carboxylate analogous.

Keywords

Transition metal complexes Pyridine tetrazole ligands Spectroscopy
Malik, R. A., Bhat, N. G., Yadav, R., Singh, N., Kumar, G., & Mal, S. (2018). Synthesis and Photophysical Investigations of Novel Transition Metal Complexes of Pyridine Tetrazole Ligands. Asian Journal of Chemistry, 30(10), 2159–2163. https://doi.org/10.14233/ajchem.2018.21056
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