Copyright (c) 2023 D.A. Raghupathy, G. Ramgopal, V.G. Dileep Kumar, T. Naveen Kumar, C.R. Ravikumar
This work is licensed under a Creative Commons Attribution 4.0 International License.
Study of Bi-functional Applications of ZnO Nanoparticles Synthesized via Sonochemical Route
Corresponding Author(s) : G. Ramgopal
Asian Journal of Chemistry,
Vol. 35 No. 12 (2023): Vol 35 Issue 12, 2023
Abstract
The sonochemical synthesis involved the dispersion of zinc oxide (ZnO) precursor in a suitable solvent, followed by ultrasonic irradiation to induce chemical reactions and nucleation of ZnO nanoparticles. The resulting nanomaterials exhibited a uniform particle size distribution, which is crucial for their photocatalytic efficiency. ZnO nanoparticles with a uniform particle size of 25 nm were successfully synthesized using a sonochemical route and were employed for the degradation of direct green and fast orange dyes under UV light irradiation. The band gap of the ZnO nanoparticles was determined to be 3.35 eV, indicating its potential as a photocatalyst for dye degradation. The degradation efficiency of the dyes was evaluated by monitoring the change in their concentration over time. The ZnO nanoparticles demonstrated excellent photocatalytic activity, efficiently degrading both dyes within a relatively short duration. The electrochemical studies further confirmed the potential applicability of the synthesized ZnO nanoparticles in various electrochemical systems. The ZnO electrode that was produced could detect lead in an acidic solution. The ZnO electrode is a promising electrode material for making sensor applications because of its higher electrochemical behaviour. Overall, this research contributes to the development of efficient and environmentally friendly approaches for wastewater treatment and lead sensor.
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- S. Sabir, M. Arshad and S.K. Chaudhari, Scient. World J., 2014, 925494 (2014); https://doi.org/10.1155/2014/925494
- M. Arakha, S. Pal, D. Samantarrai, T.K. Panigrahi, B.C. Mallick, K. Pramanik, B. Mallick and S. Jha, Sci. Rep., 5, 14813 (2015); https://doi.org/10.1038/srep14813
- X. Bai, L. Li, H. Liu, L. Tan, T. Liu and X. Meng, ACS Appl. Mater. Interfaces, 7, 1308 (2015); https://doi.org/10.1021/am507532p
- U. Ozgür, Y.I. Alivov, C. Liu, A. Teke, M.A. Reshchikov, S. Doðan, V. Avrutin, S.-J. Cho and H. Morkoç, J. Appl. Phys., 98, 041301 (2005); https://doi.org/10.1063/1.1992666
- M. Moritz and M. Geszke-Moritz, Chem. Eng. J., 228, 596 (2013); https://doi.org/10.1016/j.cej.2013.05.046
- A.A. Reinert, C. Payne, L. Wang, J. Ciston, Y. Zhu and P.G. Khalifah, Inorg. Chem., 52, 8389 (2013); https://doi.org/10.1021/ic400011n.
- B. Ludi and M. Niederberger, Dalton Trans., 42, 12554 (2013); https://doi.org/10.1039/c3dt50610j
- B. Kumar, K. Smita, L. Cumbal and A. Debut, Bioinorg. Chem. Appl., 2014, 784268 (2014); https://doi.org/10.1155/2014/784268
- G.R. Navyashree, H. Nagabhushana, D.V. Sunitha and S. Yeshodamma, Int. J. Eng. Res., l, 790 (2016).
- S.Y. Pung, C.S. Ong, K.M. Isha and M.H. Othman, Sains Malays., 43, 273 (2014).
- R. Suntako, Bull. Mater. Sci., 38, 1033 (2015); https://doi.org/10.1007/s12034-015-0921-0
- A.P. Zhang and J.Z. Zhang, J. Alloys Compd., 491, 631 (2010); https://doi.org/10.1016/j.jallcom.2009.11.027
- T. Takizawa, T. Watanabe and K. Honda, J. Phys. Chem., 82, 1391 (1978); https://doi.org/10.1021/j100501a014
- P. Nithyadharseni, K.P. Abhilash, S. Petnikota, M.R. Anilkumar, R. Jose, K.I. Ozoemena, R. Vijayaraghavan, P. Kulkarni, G. Balakrishna, B.V.R. Chowdari, S. Adams and M.V. Reddy, Electrochim. Acta, 247, 358 (2017); https://doi.org/10.1016/j.electacta.2017.06.170
- V.N. Kalpana and V.D. Rajeswari, Bioinorg. Chem. Appl., 2018, 3569758 (2018); https://doi.org/10.1155/2018/3569758
- J. Yang, X. Zhao, X. Shan, H. Fan, L. Yang, Y. Zhang and X. Li, J. Alloys Compd., 556, 1 (2013); https://doi.org/10.1016/j.jallcom.2012.12.098
- J.J. Xu, Y.H. Ao, D.G. Fu and C.W. Yuan, J. Hazard. Mater., 164, 762 (2009); https://doi.org/10.1016/j.jhazmat.2008.08.108
- J.A. Anta, E. Guillén and R. Tena-Zaera, J. Phys. Chem. C, 116, 11413 (2012); https://doi.org/10.1021/jp3010025
- C.R. Ravikumar, M.S. Santosh, H.P. Nagaswarupa, S.C. Prashantha, S. Yallappa and M.R. Anil Kumar, Mater. Res. Express, 4, 065503 (2017); https://doi.org/10.1088/2053-1591/aa73a5
- C.R. Ravi kumar, P. Kotteeswaran, V.B. Raju, A. Murugan, M.S. Santosh, H.P. Nagaswarupa, S.C. Prashantha, M.R.A. Kumar and M.S. Shivakumar, J. Energy Storage, 9, 12 (2017); https://doi.org/10.1016/j.est.2016.11.001
- K.M. Girish, S.C. Prashantha, H. Nagabhushana, C.R. Ravikumar, H.P. Nagaswarupa, R. Naik, H.B. Premakumar and B. Umesh, J. Sci. Adv. Mater. Devices, 3, 151 (2018); https://doi.org/10.1016/j.jsamd.2018.02.001
- C.R. Ravikumar, M.R.A. Kumar, H.P. Nagaswarupa, S.C. Prashantha, A.S. Bhatt, M.S. Santosh and D. Kuznetsov, J. Alloys Compd., 736, 332 (2018); https://doi.org/10.1016/j.jallcom.2017.11.111
- D. Darbar, M.R. Anilkumar, V. Rajagopalan and I. Bhattacharya, Ceramic Int., 44, 4630 (2017); https://doi.org/10.1016/j.ceramint.2017.12.010
References
S. Sabir, M. Arshad and S.K. Chaudhari, Scient. World J., 2014, 925494 (2014); https://doi.org/10.1155/2014/925494
M. Arakha, S. Pal, D. Samantarrai, T.K. Panigrahi, B.C. Mallick, K. Pramanik, B. Mallick and S. Jha, Sci. Rep., 5, 14813 (2015); https://doi.org/10.1038/srep14813
X. Bai, L. Li, H. Liu, L. Tan, T. Liu and X. Meng, ACS Appl. Mater. Interfaces, 7, 1308 (2015); https://doi.org/10.1021/am507532p
U. Ozgür, Y.I. Alivov, C. Liu, A. Teke, M.A. Reshchikov, S. Doðan, V. Avrutin, S.-J. Cho and H. Morkoç, J. Appl. Phys., 98, 041301 (2005); https://doi.org/10.1063/1.1992666
M. Moritz and M. Geszke-Moritz, Chem. Eng. J., 228, 596 (2013); https://doi.org/10.1016/j.cej.2013.05.046
A.A. Reinert, C. Payne, L. Wang, J. Ciston, Y. Zhu and P.G. Khalifah, Inorg. Chem., 52, 8389 (2013); https://doi.org/10.1021/ic400011n.
B. Ludi and M. Niederberger, Dalton Trans., 42, 12554 (2013); https://doi.org/10.1039/c3dt50610j
B. Kumar, K. Smita, L. Cumbal and A. Debut, Bioinorg. Chem. Appl., 2014, 784268 (2014); https://doi.org/10.1155/2014/784268
G.R. Navyashree, H. Nagabhushana, D.V. Sunitha and S. Yeshodamma, Int. J. Eng. Res., l, 790 (2016).
S.Y. Pung, C.S. Ong, K.M. Isha and M.H. Othman, Sains Malays., 43, 273 (2014).
R. Suntako, Bull. Mater. Sci., 38, 1033 (2015); https://doi.org/10.1007/s12034-015-0921-0
A.P. Zhang and J.Z. Zhang, J. Alloys Compd., 491, 631 (2010); https://doi.org/10.1016/j.jallcom.2009.11.027
T. Takizawa, T. Watanabe and K. Honda, J. Phys. Chem., 82, 1391 (1978); https://doi.org/10.1021/j100501a014
P. Nithyadharseni, K.P. Abhilash, S. Petnikota, M.R. Anilkumar, R. Jose, K.I. Ozoemena, R. Vijayaraghavan, P. Kulkarni, G. Balakrishna, B.V.R. Chowdari, S. Adams and M.V. Reddy, Electrochim. Acta, 247, 358 (2017); https://doi.org/10.1016/j.electacta.2017.06.170
V.N. Kalpana and V.D. Rajeswari, Bioinorg. Chem. Appl., 2018, 3569758 (2018); https://doi.org/10.1155/2018/3569758
J. Yang, X. Zhao, X. Shan, H. Fan, L. Yang, Y. Zhang and X. Li, J. Alloys Compd., 556, 1 (2013); https://doi.org/10.1016/j.jallcom.2012.12.098
J.J. Xu, Y.H. Ao, D.G. Fu and C.W. Yuan, J. Hazard. Mater., 164, 762 (2009); https://doi.org/10.1016/j.jhazmat.2008.08.108
J.A. Anta, E. Guillén and R. Tena-Zaera, J. Phys. Chem. C, 116, 11413 (2012); https://doi.org/10.1021/jp3010025
C.R. Ravikumar, M.S. Santosh, H.P. Nagaswarupa, S.C. Prashantha, S. Yallappa and M.R. Anil Kumar, Mater. Res. Express, 4, 065503 (2017); https://doi.org/10.1088/2053-1591/aa73a5
C.R. Ravi kumar, P. Kotteeswaran, V.B. Raju, A. Murugan, M.S. Santosh, H.P. Nagaswarupa, S.C. Prashantha, M.R.A. Kumar and M.S. Shivakumar, J. Energy Storage, 9, 12 (2017); https://doi.org/10.1016/j.est.2016.11.001
K.M. Girish, S.C. Prashantha, H. Nagabhushana, C.R. Ravikumar, H.P. Nagaswarupa, R. Naik, H.B. Premakumar and B. Umesh, J. Sci. Adv. Mater. Devices, 3, 151 (2018); https://doi.org/10.1016/j.jsamd.2018.02.001
C.R. Ravikumar, M.R.A. Kumar, H.P. Nagaswarupa, S.C. Prashantha, A.S. Bhatt, M.S. Santosh and D. Kuznetsov, J. Alloys Compd., 736, 332 (2018); https://doi.org/10.1016/j.jallcom.2017.11.111
D. Darbar, M.R. Anilkumar, V. Rajagopalan and I. Bhattacharya, Ceramic Int., 44, 4630 (2017); https://doi.org/10.1016/j.ceramint.2017.12.010