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Vol. 27 No. 10 (2015): Vol 27 Issue 10

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Identification by HPLC-DAD and SEM-EDX Analyses of Lake Pigments from Helichrysum arenarium

https://doi.org/10.14233/ajchem.2015.18935
Yusuf Yildiz
Complete Analysis Laboratories, Inc. Analytical Chemistry Department, 1259 Route 46, Building 4C, Parsippany NJ, 07054, USA
Emine Torgan
Turkish Cultural Foundation, Cultural Heritage Preservation and Natural Dyes Laboratory, Istanbul, Turkey

Corresponding Author(s) : Yusuf Yildiz

yusuf36li@yahoo.com

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10

Abstract

In this study, natural organic lake pigments were producted in various colors and with different mordants from Helichrysum arenarium dye plant. Fe(SO4)2·7H2O, SnCl2·2H2O, KAl(SO4)2·12H2O and Ca(NO3)2·4H2O metal compounds were used. The highest yield was obtained from the lake pigments with alum and used together with alum and calcium mordants. A reversed-phase high-performance liquid chromatography with diode-array detection was utilized for the identification of the lake pigments.The lake pigments were hydrolyzed with a 37 % hydrogen chloride/methanol/water (2:1:1; v/v/v) mixture. Naringenin, apigenin and their derivatives dyestuffs were detected in the analysis result done by HPLC-DAD. Coloring compounds of obtained lake pigments were detected. The microstructure and chemical homogeneity of the natural lake pigments were analyzed by scanning electron microscopy equipped with energy dispersion spectroscopy (SEM-EDX). The elements were identified for each pigment. Color measurements of the lake pigments were taken by CIEL*a*b* spectrophotometer/colorimeter.

Keywords

Helichrysum arenarium HPLC-DAD SEM-EDX Color measurement Lake pigment
Yildiz, Y., & Torgan, E. (2015). Identification by HPLC-DAD and SEM-EDX Analyses of Lake Pigments from Helichrysum arenarium. Asian Journal of Chemistry, 27(10), 3716–3720. https://doi.org/10.14233/ajchem.2015.18935
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