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Vol. 36 No. 4 (2024): Vol 36 Issue 4, 2024

Copyright (c) 2024 Ruhul Amin Bepari

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Theoretical Validation of Reversible Acidochromism of a Cinnamaldehyde based Scaffold with Experimental Investigations

https://doi.org/10.14233/ajchem.2024.30911
Rupam Patgiri
Department of Chemistry, Bhattadev University, Bajali, Pathsala-781325, India
Bapan Saha
Department of Chemistry, Handique Girls’ College, Guwahati-781001, India
Nilpawan Sarma
Department of Chemistry, Gauhati University, Guwahati-781014, India
Ziaur Rahman
Department of Chemistry, University of North Bengal, Raja Rammohunpur, Darjeeling-734013, India
Ruhul Amin Bepari
Department of Chemistry, Bhattadev University, Bajali, Pathsala-781325, India
https://orcid.org/0000-0002-4848-5532

Corresponding Author(s) : Ruhul Amin Bepari

ruhulbepari@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 4 (2024): Vol 36 Issue 4, 2024

Abstract

Present study explores the reversible acidochromism displayed by cinnamaldehyde derivative-based scaffold (P1), which is highly sensitive to variations in acidity and basicity. Upon exposing to an acidic environment, the solution containing P1 undergoes a vivid colour shift from yellow to a vibrant pink-fuchsia colour due to the conversion of imine within P1 into its quinonoid form. The color change can be completely reversed by adding a basic material, demonstrating the reversible acidochromic behavior of the P1 system. Moreover, the practical application of this acidochromic property is demonstrated through the development of a test kit utilizing paper strips. This kit effectively harnesses the acidochromic nature of P1 to detect even minute quantities of acidic or basic substances in solutions. The underlying mechanisms of the acid-base detection and corresponding colorimetric shifts in response to the acid-base interactions have meticulously been explored using density functional theoretical investigations.

Keywords

Acidochromism Colorimetry paper Strips
Patgiri, R., Saha, B., Sarma, N., Rahman, Z., & Bepari, R. A. (2024). Theoretical Validation of Reversible Acidochromism of a Cinnamaldehyde based Scaffold with Experimental Investigations. Asian Journal of Chemistry, 36(4), 837–843. https://doi.org/10.14233/ajchem.2024.30911
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