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Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Copyright (c) 2023 VENKATESHWARLU KANDUKURI, KALPANA MANDA, HARI PADMASRI AYTAM, CHANDRASEKHAR VASAM

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Generation of Pure H2 through CH4 Cracking Over Ni Supported on ZrO2 Modified Al2O3 Catalyst

https://doi.org/10.14233/ajchem.2023.28283
VENKATESHWARLU KANDUKURI
Department of Pharmaceutical Chemistry, Telangana University, Nizamabad-503322, India
https://orcid.org/0009-0008-1993-5523
KALPANA MANDA
Catalysis and Fine Chemicals Department, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
https://orcid.org/0009-0001-4734-4922
HARI PADMASRI AYTAM
3Department of Chemistry, University College of Science, Osmania University, Tarnaka, Hyderabad-500007, India
https://orcid.org/0000-0002-1615-0033
CHANDRASEKHAR VASAM
Department of Pharmaceutical Chemistry, Telangana University, Nizamabad-503322, India
https://orcid.org/0000-0002-5403-7891

Corresponding Author(s) : CHANDRASEKHAR VASAM

vasamcs@yahoo.co.in

Asian Journal of Chemistry, Vol. 35 No. 10 (2023): Vol 35 Issue 10, 2023

Abstract

Clean hydrogen formation via CH4 cracking on a zirconia-modified alumina support at 550 ºC and atmospheric pressure with constant Ni loading. The increased H2 yields on 20Ni/3 wt.% ZrO2-Al2O3 are explained by the large Ni surface area. TEM and XRD confirmed the deactivated catalyst’s graphitic origin, while Raman spectroscopy helped distinguish between ordered and disordered carbon. As determined by H2 pulse chemisorption, the high H2 yields produced by 20wt%Ni/3 wt.%ZrO2-Al2O3 catalyst is typified by well- ispersed Ni particles and large Ni metal area. 

Keywords

Hydrogen production CH4 decomposition Ni Catalyst
KANDUKURI, V., MANDA, K., AYTAM, H. P., & VASAM, C. (2023). Generation of Pure H2 through CH4 Cracking Over Ni Supported on ZrO2 Modified Al2O3 Catalyst. Asian Journal of Chemistry, 35(10), 2481–2486. https://doi.org/10.14233/ajchem.2023.28283
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