Analysis of Physical and Thermodynamic Properties of Poly(2-cyclopentyliden-1,3-dioxolan-4-yl-methylmethacrylate-co-styrene) (CPDMMA-ST) Polymer Using Inverse Gas Chromatography

M. Hamdi Karagöz; Adnan Kalkan; Zülfiye Ilter

doi:10.14233/ajchem.2015.19212

Issue

Vol. 27 No. 12 (2015): Vol 27 Issue 12

Issue Published : August 29, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Analysis of Physical and Thermodynamic Properties of Poly(2-cyclopentyliden-1,3-dioxolan-4-yl-methylmethacrylate-co-styrene) (CPDMMA-ST) Polymer Using Inverse Gas Chromatography

https://doi.org/10.14233/ajchem.2015.19212

M. Hamdi Karagöz

Department of Chemistry, Faculty of Science, Yüzüncü Yil Üniversity, Van, Turkey

Adnan Kalkan

Department of Chemistry, Faculty of Science, Yüzüncü Yil Üniversity, Van, Turkey

Zülfiye Ilter

Department of Chemistry, Faculty of Science, Firat Üniversity, Elazig, Turkey

Corresponding Author(s) : M. Hamdi Karagöz

mhkaragoz@yahoo.com.tr

Asian Journal of Chemistry, Vol. 27 No. 12 (2015): Vol 27 Issue 12
Article Published : August 29, 2015

Abstract

In this study, thermodynamic and physical properties of poly(2-cyclopentyliden-1,3-dioxolane-4-yl-methylmethacrylate-co-styrene) (%55CPDMMA-%45ST) were investigated using inverse gas chromatography. Two groups of alcohols and alkanes with different chemical natures and polarities were used to determine certain properties of (CPDMMA-ST)-solute systems. The specific retention volume (V_g⁰), glass transition temperature (T_g), adsorption enthalpy (DH_a), the sorption enthalpy (DH₁^S), sorption free energy (DG₁^S), sorption entropy (DS₁^S), weight fraction activity coefficients of solute probes at infinite dilution (W₁^¥), partial molar enthalpy of solute probes at infinite dilution (DH₁^¥) and Flory-Huggins interaction parameters (c₁₂^¥), between polymer and solvents were determined in the temperature range of 313-473 K. In addition, the solubility parameters of CPDMMA-ST at infinite dilution was determined by plotting the graph of [d₁²-(DG₁^¥/V₁)] versus solubility parameters (d₁), of probes.

Keywords

Polymer Inverse gas chromatography Poly(2-cyclopentyliden-1 3-dioxolan-4-yl-methylmethacrylate-co-styrene)

Hamdi Karagöz, M., Kalkan, A., & Ilter, . Z. (2015). Analysis of Physical and Thermodynamic Properties of Poly(2-cyclopentyliden-1,3-dioxolan-4-yl-methylmethacrylate-co-styrene) (CPDMMA-ST) Polymer Using Inverse Gas Chromatography. Asian Journal of Chemistry, 27(12), 4532–4536. https://doi.org/10.14233/ajchem.2015.19212

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References

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References

J.M. Braun and J.E. Guillet, Macromolecules, 8, 882 (1975); doi:10.1021/ma60048a035.

D.G. Gray and J.E. Guillet, Macromolecules, 7, 244 (1974); doi:10.1021/ma60038a017.

C.T. Chen and Z.Y. Al-Saigh, Macromolecules, 22, 2974 (1989); doi:10.1021/ma00197a017.

M. Öner and S. Dinçer, Polymer, 28, 279 (1987); doi:10.1016/0032-3861(87)90417-4.

C.-T. Chen and Z.Y. Al-Saigh, Polymer, 31, 1170 (1990); doi:10.1016/0032-3861(90)90269-5.

O. Smidsrød and J.E. Guillet, Macromolecules, 2, 272 (1969); doi:10.1021/ma60009a012.

M. Galin, Macromolecules, 10, 1239 (1977); doi:10.1021/ma60060a016.

M.H. Karagöz, H. Erge and Z. İlter, Asian J. Chem., 21, 4032 (2009).

D.D. Deshpande and O.S. Tyagi, Macromolecules, 11, 746 (1978); doi:10.1021/ma60064a026.

G. Dipaola-Baranyi, J.E. Guillet, J.E. Klein and H.E. Jeberien, J. Chromatogr. A, 166, 349 (1978); doi:10.1016/S0021-9673(00)95616-4.

J.M. Braun, M. Cutajar, J.E. Guillet, H.P. Schreiber and D. Patterson, Macromolecules, 10, 864 (1977); doi:10.1021/ma60058a029.

M. Galin and L. Maslinko, Macromolecules, 18, 2192 (1985); doi:10.1021/ma00153a022.

G. Courval and D.G. Gray, Macromolecules, 8, 326 (1975); doi:10.1021/ma60045a016.

J.M. Braun and J.E. Guillet, Macromolecules, 10, 101 (1977); doi:10.1021/ma60055a021.

G. Dipaola-Baranyi and J.E. Guillet, Macromolecules, 11, 228 (1978); doi:10.1021/ma60061a043.

J.E. Guillet, J. Macromol. Sci. Chem., 4, 1669 (1970); doi:10.1080/00222337008069376.

R. Sanetra, B.N. Kolarz and A. Wochowicz, Polymer, 28, 1753 (1987); doi:10.1016/0032-3861(87)90020-6.

A. Etxeberría, J. Alfageme, C. Uriarte and J.J. Iruin, J. Chromatogr. A, 607, 227 (1992); doi:10.1016/0021-9673(92)87080-R.

J. Klein and H.-E. Jeberien, Makromol. Chem., 181, 1237 (1980); doi:10.1002/macp.1980.021810608.

M.H. Karagöz, Ö.S. Zorer and Z. Ilter, Polymer-Plastics Technol. Eng., 45, 785 (2006); doi:10.1080/03602550600611859.

J.E. Guillet, in ed.: J.H. Purnel, Advances in Analytical Chemistry, In: New developments in Gas Chromatography, John Wiley & Sons, New York (1973).

Z. Ilter, I. Kaya and A. Açikses, J. Polym. Eng., 22, 45 (2002); doi:10.1515/POLYENG.2002.22.1.45.

Z. Ilter, E. Özdemir and M. Ahmedzade, Desig. Monomers Polym., 2, 343 (1999); doi:10.1163/156855599X00142.

Z. Ilter, M. Coskun, I. Erol, A. Unal and M. Ahmedzade, Polym. Degrad. Stab., 75, 501 (2002); doi:10.1016/S0141-3910(01)00253-1.

Issue

Vol. 27 No. 12 (2015): Vol 27 Issue 12

Analysis of Physical and Thermodynamic Properties of Poly(2-cyclopentyliden-1,3-dioxolan-4-yl-methylmethacrylate-co-styrene) (CPDMMA-ST) Polymer Using Inverse Gas Chromatography

Corresponding Author(s) : M. Hamdi Karagöz

Abstract

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