Physical and Thermodynamic Properties of Poly(2-p-bromophenyl-1,3-dioxolane-4-yl-methylacrylate) and Poly(2-p-chlorophenyl-1,3-dioxolane-4-yl-methylacrylate) Using Inverse Gas Chromatography

M. Hamdi Karagöz; Murat Kafli

doi:10.14233/ajchem.2015.19120

Issue

Vol. 27 No. 12 (2015): Vol 27 Issue 12

Issue Published : August 29, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Physical and Thermodynamic Properties of Poly(2-p-bromophenyl-1,3-dioxolane-4-yl-methylacrylate) and Poly(2-p-chlorophenyl-1,3-dioxolane-4-yl-methylacrylate) Using Inverse Gas Chromatography

https://doi.org/10.14233/ajchem.2015.19120

M. Hamdi Karagöz

Department of Chemistry, Faculty of Science, Yüzüncü Yil University, Van, Turkey

Murat Kafli

Department of Chemistry, Faculty of Science, Yüzüncü Yil University, Van, Turkey

Corresponding Author(s) : M. Hamdi Karagöz

mhkaragoz@yahoo.com.tr

Asian Journal of Chemistry, Vol. 27 No. 12 (2015): Vol 27 Issue 12
Article Published : August 29, 2015

Abstract

In this study, the thermodynamic and physical properties of poly(2-p-bromophenyl-1,3-dioxolane-4-yl-methylacrylate) (PPBPDMA) and poly(2-p-chlorophenyl-1,3-dioxolane-4-yl-methylacrylate) (PPCPDMA) were investigated using inverse gas chromatography. Two groups of alcohols and alkanes with different chemical natures and polarities were used to determine certain properties of [(PPBPDMA) and (PPCPDMA)]-solute systems. The specific retention volume (V_g⁰), glass transition temperature (T_g), adsorption enthalpy (DH_a), sorption enthalpy (DH₁^S), sorption free energy (DG₁^S), sorption entropy (DS₁^S), weight fraction activity coefficients of the solute probes at infinite dilution (W₁^¥), partial molar enthalpy of the solute probes at infinite dilution (DH₁^¥) and Flory-Huggins interaction parameters (c₁₂^¥), between the polymer and solvents were determined at 303-423 K. In addition, the solubility parameters of PPBPDMA and PPCPDMA at infinite dilution were determined by plotting the graph of [d₁² – (DG₁^¥/V₁)] versus the solubility parameters (d₁) of the probes.

Keywords

Polymer Inverse gas chromatography Thermodynamic and Physical properties

Hamdi Karagöz, M., & Kafli, M. (2015). Physical and Thermodynamic Properties of Poly(2-p-bromophenyl-1,3-dioxolane-4-yl-methylacrylate) and Poly(2-p-chlorophenyl-1,3-dioxolane-4-yl-methylacrylate) Using Inverse Gas Chromatography. Asian Journal of Chemistry, 27(12), 4344–4350. https://doi.org/10.14233/ajchem.2015.19120

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References

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References

J.M. Braun and J.E. Guillet, Macromolecules, 8, 882 (1975); doi:10.1021/ma60048a035.

D.G. Gray and J.E. Guillet, Macromolecules, 7, 244 (1974); doi:10.1021/ma60038a017.

C.T. Chen and Z.Y. Al-Saigh, Macromolecules, 22, 2974 (1989); doi:10.1021/ma00197a017.

M. Öner and S. Dinçer, Polymer, 28, 279 (1987); doi:10.1016/0032-3861(87)90417-4.

C.-T. Chen and Z.Y. Al-Saigh, Polymer, 31, 1170 (1990); doi:10.1016/0032-3861(90)90269-5.

O. Smidsrød and J.E. Guillet, Macromolecules, 2, 272 (1969); doi:10.1021/ma60009a012.

M. Galin, Macromolecules, 10, 1239 (1977); doi:10.1021/ma60060a016.

I. Kaya and K. Ceylan, Doga-Tr. J. Chem., 17, 1 (1993).

D.D. Deshpande and O.S. Tyagi, Macromolecules, 11, 746 (1978); doi:10.1021/ma60064a026.

G. Dipaola-Baranyi, J.E. Guillet, J.E. Klein and H.E. Jeberien, J. Chromatogr. A, 166, 349 (1978); doi:10.1016/S0021-9673(00)95616-4.

J.M. Braun, M. Cutajar, J.E. Guillet, H.P. Schreiber and D. Patterson, Macromolecules, 10, 864 (1977); doi:10.1021/ma60058a029.

M. Galin and L. Maslinko, Macromolecules, 18, 2192 (1985); doi:10.1021/ma00153a022.

G. Courval and D.G. Gray, Macromolecules, 8, 326 (1975); doi:10.1021/ma60045a016.

J.M. Braun and J.E. Guillet, Macromolecules, 10, 101 (1977); doi:10.1021/ma60055a021.

G. Dipaola-Baranyi and J.E. Guillet, Macromolecules, 11, 228 (1978); doi:10.1021/ma60061a043.

R. Sanetra, B.N. Kolarz and A.Wochowicz, Polymer, 28, 1753 (1987); doi:10.1016/0032-3861(87)90020-6.

A. Etxeberría, J. Alfageme, C. Uriarte and J.J. Iruin, J. Chromatogr. A, 607, 227 (1992); doi:10.1016/0021-9673(92)87080-R.

J.E. Guillet, J. Macromol. Sci. Chem., 4, 1669 (1970); doi:10.1080/00222337008069376.

Z. Ilter, F. Alhanli, F. Dogan and I. Kaya, Chin. J. Polym. Sci., 30, 642 (2012); doi:10.1007/s10118-012-1155-x.

F. Alhanli, Ph.D. Thesis, Synthesis and Characterization of Polymers Containing Chloro and Bromo-1,3-dioxalane Group as Side Chain, Firat University, Elazig, Turkey (2004).

M.H. Karagöz, Ö.S. Zorer and Z. Ilter, Polym. Plast. Technol. Eng, 45, 785 (2006); doi:10.1080/03602550600611859.

M.H. Karagöz, H. Erge and Z. Ilter, Asian J. Chem., 21, 4032 (2009).

J.E. Guillet and J.H. Purnel, Advances in Analytical Chemistry and Instrumentation Gas Chromatography, John Wiley & Sons, New York (1973).

J. Klein and H.-E. Jeberien, Makromol. Chem., 181, 1237 (1980); doi:10.1002/macp.1980.021810608.

Z. Ilter, I. Kaya and A. Açikses, J. Polym. Eng., 22, 45 (2002); doi:10.1515/POLYENG.2002.22.1.45.

Z. Ilter, E. Özdemir and M. Ahmedzade, Des. Monomers Polym., 2, 343 (1999); doi:10.1163/156855599X00142.

Issue

Vol. 27 No. 12 (2015): Vol 27 Issue 12

Physical and Thermodynamic Properties of Poly(2-p-bromophenyl-1,3-dioxolane-4-yl-methylacrylate) and Poly(2-p-chlorophenyl-1,3-dioxolane-4-yl-methylacrylate) Using Inverse Gas Chromatography

Corresponding Author(s) : M. Hamdi Karagöz

Abstract

Keywords

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