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Synthesis and Properties of Two Dimensional Wavelike Sheet Coordination Polymer
Corresponding Author(s) : L.L. Liang
Asian Journal of Chemistry,
Vol. 27 No. 12 (2015): Vol 27 Issue 12
Abstract
A new coordination polymer [Zn(C14H18SO6)(C28H22N4)]n, has been synthesized under solvothermal conditions and characterized by single crystal X-ray structure analyses, thermogravimetric analyses, powder X-ray diffraction and solid-state photoluminescent measurements. The Zn2+ ion has a square pyramidal coordination and two neighbouring Zn2+ ions are bridged together by four carboxylate groups of 4,4'-dicarboxyldiphenyl sulfone to generate a paddle wheel dinuclear zinc structure. The dizinc paddle wheel is linked by two V-shaped linker 4,4'-dicarboxyldiphenyl sulfone via carboxylate groups to form an infinite 1-D chain which is further connected by 4,4'-bis(benzimidazole-1-ylmethyl)biphenyl through sharing the dizinc paddlewheel into an infinite 2D sheet framework. The framework is further strengthened by p-p interaction between benzimidazol rings of 4,4'-bis(benzimidazole-1-ylmethyl)biphenyl ligand and the benzene ring of 4,4'-dicarboxyldiphenyl sulfone ligand. The TG analysis shows that the framework of the complex is stable up to 370 °C. Moreover, the complex exhibits strong photoluminescence in the solid state at room temperature.
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- J.R. Li, J. Sculley and H.C. Zhou, Chem. Rev., 112, 869 (2012); doi:10.1021/cr200190s.
- H. Wu, Q. Gong, D.H. Olson and J. Li, Chem. Rev., 112, 836 (2012); doi:10.1021/cr200216x.
- M. Zhang, G. Feng, Z. Song, Y.P. Zhou, H.Y. Chao, D. Yuan, T.T. Tan, Z. Guo, Z. Hu, B.Z. Tang, B. Liu and D. Zhao, J. Am. Chem. Soc., 136, 7241 (2014); doi:10.1021/ja502643p.
- E. Barea, C. Montoro and J.A. Navarro, Chem. Soc. Rev., 43, 5419 (2014); doi:10.1039/C3CS60475F.
- Y. He, W. Zhou, G. Qian and B. Chen, Chem. Soc. Rev., 43, 5657 (2014); doi:10.1039/C4CS00032C.
- Z. Hu, B.J. Deibert and J. Li, Chem. Soc. Rev., 43, 5815 (2014); doi:10.1039/C4CS00010B.
- L.L. Liang, S.B. Ren, J. Zhang, Y.Z. Li, H.B. Du and X.Z. You, Cryst. Growth Des., 10, 1307 (2010); doi:10.1021/cg901353e.
- Z.Q. Shi, Y.Z. Li, Z.J. Guo and H.G. Zheng, CrystEngComm, 16, 900 (2014); doi:10.1039/C3CE41966E.
- L. Luo, K. Chen, Q. Liu, Y. Lu, T. Okamura, G.C. Lv, Y. Zhao and W.Y. Sun, Cryst. Growth Des., 13, 2312 (2013); doi:10.1021/cg301815w.
- Z.L. Tao, L. Qin and H.G. Zheng, Wuji Huaxue Xuebao, 28, 2109 (2012).
- Z.L. Tao, J.H. Cui, L. Qin and H.G. Zheng, Wuji Huaxue Xuebao, 28, 2633 (2012).
- Z.L. Tao, T.T. Shi, L.L. Liang and H.B. Xue, J. Synth. Cryst., 42, 371 (2013).
- L. Dobrzànska, G.O. Lloyd, T. Jacobs, I. Rootman, C.L. Oliver, M.W. Bredenkamp and L.J. Barbour, J. Mol. Struct., 796, 107 (2006); doi:10.1016/j.molstruc.2006.02.059.
- C. Janiak, J. Chem. Soc., Dalton Trans., 3885 (2000); doi:10.1039/b003010o.
- M.D. Allendorf, C.A. Bauer, R.K. Bhakta and R.J.T. Houk, Chem. Soc. Rev., 38, 1330 (2009); doi:10.1039/b802352m.
References
J.R. Li, J. Sculley and H.C. Zhou, Chem. Rev., 112, 869 (2012); doi:10.1021/cr200190s.
H. Wu, Q. Gong, D.H. Olson and J. Li, Chem. Rev., 112, 836 (2012); doi:10.1021/cr200216x.
M. Zhang, G. Feng, Z. Song, Y.P. Zhou, H.Y. Chao, D. Yuan, T.T. Tan, Z. Guo, Z. Hu, B.Z. Tang, B. Liu and D. Zhao, J. Am. Chem. Soc., 136, 7241 (2014); doi:10.1021/ja502643p.
E. Barea, C. Montoro and J.A. Navarro, Chem. Soc. Rev., 43, 5419 (2014); doi:10.1039/C3CS60475F.
Y. He, W. Zhou, G. Qian and B. Chen, Chem. Soc. Rev., 43, 5657 (2014); doi:10.1039/C4CS00032C.
Z. Hu, B.J. Deibert and J. Li, Chem. Soc. Rev., 43, 5815 (2014); doi:10.1039/C4CS00010B.
L.L. Liang, S.B. Ren, J. Zhang, Y.Z. Li, H.B. Du and X.Z. You, Cryst. Growth Des., 10, 1307 (2010); doi:10.1021/cg901353e.
Z.Q. Shi, Y.Z. Li, Z.J. Guo and H.G. Zheng, CrystEngComm, 16, 900 (2014); doi:10.1039/C3CE41966E.
L. Luo, K. Chen, Q. Liu, Y. Lu, T. Okamura, G.C. Lv, Y. Zhao and W.Y. Sun, Cryst. Growth Des., 13, 2312 (2013); doi:10.1021/cg301815w.
Z.L. Tao, L. Qin and H.G. Zheng, Wuji Huaxue Xuebao, 28, 2109 (2012).
Z.L. Tao, J.H. Cui, L. Qin and H.G. Zheng, Wuji Huaxue Xuebao, 28, 2633 (2012).
Z.L. Tao, T.T. Shi, L.L. Liang and H.B. Xue, J. Synth. Cryst., 42, 371 (2013).
L. Dobrzànska, G.O. Lloyd, T. Jacobs, I. Rootman, C.L. Oliver, M.W. Bredenkamp and L.J. Barbour, J. Mol. Struct., 796, 107 (2006); doi:10.1016/j.molstruc.2006.02.059.
C. Janiak, J. Chem. Soc., Dalton Trans., 3885 (2000); doi:10.1039/b003010o.
M.D. Allendorf, C.A. Bauer, R.K. Bhakta and R.J.T. Houk, Chem. Soc. Rev., 38, 1330 (2009); doi:10.1039/b802352m.