Issue

Vol. 27 No. 12 (2015): Vol 27 Issue 12

Copyright (c) 2015 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Physico-Chemical Aspects of Solubility of Reactive Gases in Water

https://doi.org/10.14233/ajchem.2015.19162
B.R. Deshwal
Department of Chemistry, All India Jat Heroes' Memorial College, Rohtak-124 001, India
N. Kundu
Department of Chemistry, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131 039, India

Corresponding Author(s) : B.R. Deshwal

deshwalbr@yahoo.com

Asian Journal of Chemistry, Vol. 27 No. 12 (2015): Vol 27 Issue 12

Abstract

The solubility versus partial pressure data for various reactive gases in water has been described. The contribution of chemical reaction in solubility of SO2, NH3, Cl2 and ClO2 in water has been highlighted. Chlorine dioxide showed only Henry type solubility and existed in the gaseous form even in the aqueous phase. On the contrary, NH3, Cl2 and SO2 showed appreciable contribution of solubility due to chemical reaction and existed in the ionized form in the aqueous phase. An empirical relation having three adjustable parameters (a, b, and h) have been derived to discuss the physical and chemical terms of the total solubility in water. The Henry’s coefficient (H) of SO2, NH3, Cl2 and ClO2 has been evaluated at various temperatures and the temperature dependence of Henry’s coefficient has been discussed using a four parameter equation. The enthalpy of dissolution (DH) for various gases is evaluated and compared with the literature values.

Keywords

Solubility Gas Henry’s coefficient Empirical relation Enthalpy of dissolution
Deshwal, B., & Kundu, N. (2015). Physico-Chemical Aspects of Solubility of Reactive Gases in Water. Asian Journal of Chemistry, 27(12), 4429–4435. https://doi.org/10.14233/ajchem.2015.19162
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. H. Hikita, S. Asai and H. Nose, Am. Inst. Chem. Eng. J., 24, 147 (1978); doi:10.1002/aic.690240117.
  2. D.A. Pearson, and L.A. Lundberg, Chem. Eng. Prog., 47, 257 (1951).
  3. W.L. Beuschlein and L.O. Simenson, J. Am. Chem. Soc., 62, 610 (1940); doi:10.1021/ja01860a053.
  4. A. Douabul and J. Riley, J. Chem. Eng. Data, 24, 274 (1979); doi:10.1021/je60083a014.
  5. J.R. Sevilla, M. Alvarez, M.C. Diaz and M.C. Marrero, J. Chem. Eng. Data, 49, 1710 (2004); doi:10.1021/je049833l.
  6. H.F. Johnstone and P.W. Leppla, J. Am. Chem. Soc., 56, 2233 (1934); doi:10.1021/ja01326a009.
  7. B. Rumpf and G. Maurer, Fluid Phase Equilib., 81, 241 (1992); doi:10.1016/0378-3812(92)85155-2.
  8. M. Teramoto, K. Kido and H. Teranishi, J. Chem. Eng. of Jpn, 13, 458 (1980); doi:10.1252/jcej.13.458.
  9. C.S. Chang and G.T. Rochelle, Am. Inst. Chem. Eng. J., 27, 292 (1981); doi:10.1002/aic.690270217.
  10. M. Schultes, Chem. Eng. Technol., 21, 201 (1998); doi:10.1002/(SICI)1521-4125(199802)21:2<201::AID-CEAT201>3.0.CO;2-W.
  11. Q. Zhang, H. Wang, I.G. Dalla Lana and K.T. Chuang, Ind. Eng. Chem. Res., 37, 1167 (1998); doi:10.1021/ie9706119.
  12. V.M.H. Govindarao and K.V. Gopalakrishna, Ind. Eng. Chem. Res., 32, 2111 (1993); doi:10.1021/ie00021a037.
  13. J.M. Hales, and D.R. Drewes, Atmos. Environ., 13, 1133 (1979); doi:10.1016/0004-6981(79)90037-4.
  14. P.G. Dasgupta and S. Dong, Atmos. Environ., 20, 565 (1986); doi:10.1016/0004-6981(86)90099-5.
  15. T.K. Sherwood, Ind. Eng. Chem., 17, 745 (1925); doi:10.1021/ie50187a043.
  16. B. Rumpf and G. Maurer, J. Solution Chem., 23, 37 (1994); doi:10.1007/BF00972606.
  17. D.S. Jin, B.R. Deshwal, Y.S. Park and H.K. Lee, J. Hazard. Mater., 135, 412 (2006); doi:10.1016/j.jhazmat.2005.12.001.
  18. B.R. Deshwal and H.K. Lee, J. Environ. Sci., 21, 155 (2009); doi:10.1016/S1001-0742(08)62244-5.
  19. B.R. Deshwal, D.S. Jin, S.H. Lee, S.H. Moon, J.H. Jung and H.K. Lee, J. Hazard. Mater., 150, 649 (2008); doi:10.1016/j.jhazmat.2007.05.016.
  20. D.G. Leaist, J. Solution Chem., 15, 827 (1986); doi:10.1007/BF00646090.
  21. E.M. Aieta and P.V. Roberts, J. Chem. Eng. Data, 31, 51 (1986); doi:10.1021/je00043a017.
  22. Y. Awakura, S. Yoshitake and H. Majima, Jpn Inst. Met., 31, 697 (1990).
  23. M. Alkan, M. Oktay, M.M. Kocakerim and M. Copur, J. Hazard. Mater., 119, 13 (2005); doi:10.1016/j.jhazmat.2004.11.001.
  24. G.D. Yadav and M.M. Sharma, Chem. Eng. Sci., 36, 599 (1981); doi:10.1016/0009-2509(81)80149-2.
  25. R.H. Perry and D. Green, Perry’s Chemical Engineers’ Handbook, McGraw-Hill, Selangor, Malaysia, edn 7 (1984).
  26. G.M. Barrow, Physical Chemistry, McGraw Hill, Singapore (1988).
  27. R.C. Reid, J.M. Prausnitz and B.E. Poling, The Properties of Gases & Liquids, McGraw Hill, Singapore (1988).
  28. M.K. Mondal, Fluid Phase Equilib., 253, 98 (2007); doi:10.1016/j.fluid.2007.01.015.
  29. V. Bieling, B. Rumpf, F. Strepp and G. Maurer, Fluid Phase Equilib., 53, 251 (1989); doi:10.1016/0378-3812(89)80093-7.
  30. P.V. Danckwerts, Gas-Liquid Reactions, McGraw Hill, New York (1970).
  31. E. Wilhelm, R. Battino and R.J. Wilcock, Chem. Rev., 77, 219 (1977); doi:10.1021/cr60306a003.
  32. M.C. Kawanangh and R.R. Trussell, J. Am. Water Works Assoc., 72, 684 (1980).
  33. D.R. Lide, CRC Hand Book of Chemistry and Physics, Internet Version, CRC Press Inc., Boca Raton FL (2005).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0