Novel Dithiocarbamates for Electrochemical Detection of Nickel(II) in Environmental Samples

T. Niranjan; Suvardhan Kanchi; Krishna Bisetty; N. Venkatasubba Naidu

doi:10.14233/ajchem.2015.18883

Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Issue Published : June 22, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Novel Dithiocarbamates for Electrochemical Detection of Nickel(II) in Environmental Samples

https://doi.org/10.14233/ajchem.2015.18883

T. Niranjan

Department of Chemistry, Sri Venkateswara University, Tirupati-517 502, India

Suvardhan Kanchi

Department of Chemistry, Durban University of Technology, Durban 4000, South Africa

Krishna Bisetty

Department of Chemistry, Durban University of Technology, Durban 4000, South Africa

N. Venkatasubba Naidu

Department of Chemistry, Sri Venkateswara University, Tirupati-517 502, India

Corresponding Author(s) : N. Venkatasubba Naidu

nvsn69@gmail.com

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10
Article Published : June 22, 2015

Abstract

Ammonium 4-phenylpiperazine-1-dithiocarbamate (Amm 4-PP-DTC) and ammonium 4-benzylpiperidine-1-dithiocarbamate (Amm 4-BP-DTC) were synthesized for the determination of nickel(II) using catalytic hydrogen currents (CHC’s) technique with DC Polarography. The method was based on the chelation of nickel(II) with Amm 4-PP-DTC/ Amm 4-BP-DTC in presence of NH₄OH at pH 6.8 to produce catalytic hydrogen current at -1.50V and -1.41 V vs. SCE respectively. Optimized polarographic conditions were established by studying effect of pH, supporting electrolyte (NH₄Cl), ligands and metal ion concentration and effect of adverse ions on peak height to improve the sensitivity, selectivity and detection limits of the present method. This technique is successfully applied for the analysis of nickel(II) in different matrices with recoveries ranging from 96.0-99.0 % and the results obtained were comparable with the atomic absorption spectroscopy.

Keywords

DC polarography Catalytic hydrogen current technique Nickel(II) Ammonium 4-arylpiperazine-1-dithiocarbamate

Niranjan, T., Kanchi, S., Bisetty, K., & Venkatasubba Naidu, N. (2015). Novel Dithiocarbamates for Electrochemical Detection of Nickel(II) in Environmental Samples. Asian Journal of Chemistry, 27(10), 3598–3604. https://doi.org/10.14233/ajchem.2015.18883

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References

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References

ATS DR (Agency for toxic Substanus and Disease Registry); Toxicological Profile for Nickel, ATSDR/U. S. Public Health Service, ATSDR/TP-88/19 (1988).

T. Daldrup, K. Haarhoff and S.C. Szathnary, Berichte Zur Gerichtlichen Medizin, 41, 141 (1988).

F.W. Sunderman Jr., A. Aito, L.G. Morgan and T. Noresth, in eds.: E. Nieboer and J.O. Nriagu In: Nickel and Human Health, John Wiley & Sons Inc., New York, pp. 49-68 (1981).

R. Croyer, in eds.: M.O. Amdur, J.D. Doull and C.D. Klaassen, Toxic Effect of Metals, In: Casrett and Doull’s Toxicology, Pergamon Press, New York, edn 4, pp. 623-680 (1991).

D. Templeton, Biological Monitoring of Chemical Exposure in the Workplace, World Health Organization, Geneva (1990).

E. Merian, M. Anke and M. Stoppler, Elements and Their Compounds in the Environment, Wiley, VCH, Weinheim, vol. 2, (2004).

J.G. Sen Gupta, Anal. Chim. Acta, 58, 23 (1972); doi:10.1016/S0003-2670(00)86850-6.

S. Scaccia, Talanta, 49, 467 (1999); doi:10.1016/S0039-9140(98)00374-9.

A. Economou and P.R. Fielden, Talanta, 46, 1137 (1998); doi:10.1016/S0039-9140(97)00381-0.

M. Frolin, E. Contiero and I. Calliari, Ann. Chim., 39, 81 (1991).

Y. Fu, W.G. Wang, K.J. Xie and Q.R. Zhao, Fenxi Huaxue., 26, 431 (1998).

Y.L. Ren, X.B. Zhang, Y.G. Ren, M.C. Wang and G.A. Xu, Fenxi Huaxue, 25, 301 (1997).

W. Galas and J. Trzcionka, Chemica Analityczna (Warsaw), 42, 697 (1997).

S.N. Muddukrishna, J. Holzbecher and D.E. Ryan, J. Radioanal. Nucl. Chem., 148, 27 (1991); doi:10.1007/BF02060543.

G. Suresh, P. Dhanakakshmi and N.V.S. Naidu, Int. J. Curr. Sci., 23, 83 (2003).

K. Saraswathi, N.V.S. Naidu, K. Meena Kumari and K. Padmaja, Chem. Environ. Res., 8, 271 (1999).

K. Saraswathi, K. Yamuna, A. Hemasundaram and N.V.S. Naidu, J. Electrochem. Soc. India., 51, 155 (2002).

K. Saraswathi, G. Suresh, P. Prameela and N.V.S. Naidu, Trans. SAEST, 38, 151, (2003).

K. Saraswathi, N.V.S. Naidu, G. Suresh and K. Dhanalakshmi, Bull. Electrochem., 22, 1 (2006).

S. Kanchi, P. Krishnamurthy, K. Saraswathi and N. Venkatasubba Naidu, Chem. Technol. An Indian J., 6, 6 (2011).

S. Kanchi, T. Niranjan, K. Saraswathi and N. Venkatasubba Naidu, Anal. Chem. An Indian J., 10, 231 (2011).

S. Kanchi, M. Sulochana, K.B. Naidu, K. Saraswathi and N.V. Naidu, Food Anal. Methods, 4, 453 (2011); doi:10.1007/s12161-010-9191-z.

S. Kanchi, P. Singh, M.I. Sabela, K. Bisetty and N. Venkatasubba Naidu, Int. J. Electrochem. Soc., 8, 4260 (2013).

S. Kanchi, P. Anuradha, B.N. Kumar, K. Gopalakrishnan and P. Ravi, Arabian J. Chem., doi:10.1013/i.arabjc.2012.08.01.

S. Kanchi, P. Singh and K. Bisetty, Arabian J. Chem., 7, 11 (2014); doi:10.1016/i.arabjc.2013.04.026.

S. Kanchi, P. Mi Sabela, P. Singh and K. Bisetty, Arabian J. Chem., doi:10.1016/i.arabjc.2013.07.061.

Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Novel Dithiocarbamates for Electrochemical Detection of Nickel(II) in Environmental Samples

Corresponding Author(s) : N. Venkatasubba Naidu

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