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Vol 26 No Supplementary Issue

Copyright (c) 2014 Manop Sriuttha1, Rungroj Chanajaree2, Wimonrat Tongpoothorn3, Kitiyaporn Wittayanarakul1

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A Combined Experimental/Computational Study on Adsorption of Fe2+ by Cigarette Filter Added with Chitosan

https://doi.org/10.14233/ajchem.2014.19043
Manop Sriuttha1
1Department of Natural Resource and Environmental Management, Faculty of Applied Science and Engineering, KhonKaen University, Nongkhai Campus, Nongkhai 43000, Thailand 2Metallurgy and Materials Science Research Institute (MMRI), Chulalongkorn University 10330, Bangkok, Thailand 3Department of Chemistry, Faculty of Engineering, Rajamangala University of Technology Isan, Khon Kaen Campus, Khon Kaen 40000, Thailand *Corresponding author: E-mail: kitiwi@kku.ac.th
Rungroj Chanajaree2
1Department of Natural Resource and Environmental Management, Faculty of Applied Science and Engineering, KhonKaen University, Nongkhai Campus, Nongkhai 43000, Thailand 2Metallurgy and Materials Science Research Institute (MMRI), Chulalongkorn University 10330, Bangkok, Thailand 3Department of Chemistry, Faculty of Engineering, Rajamangala University of Technology Isan, Khon Kaen Campus, Khon Kaen 40000, Thailand *Corresponding author: E-mail: kitiwi@kku.ac.th
Wimonrat Tongpoothorn3
1Department of Natural Resource and Environmental Management, Faculty of Applied Science and Engineering, KhonKaen University, Nongkhai Campus, Nongkhai 43000, Thailand 2Metallurgy and Materials Science Research Institute (MMRI), Chulalongkorn University 10330, Bangkok, Thailand 3Department of Chemistry, Faculty of Engineering, Rajamangala University of Technology Isan, Khon Kaen Campus, Khon Kaen 40000, Thailand *Corresponding author: E-mail: kitiwi@kku.ac.th
Kitiyaporn Wittayanarakul1
1Department of Natural Resource and Environmental Management, Faculty of Applied Science and Engineering, KhonKaen University, Nongkhai Campus, Nongkhai 43000, Thailand 2Metallurgy and Materials Science Research Institute (MMRI), Chulalongkorn University 10330, Bangkok, Thailand 3Department of Chemistry, Faculty of Engineering, Rajamangala University of Technology Isan, Khon Kaen Campus, Khon Kaen 40000, Thailand *Corresponding author: E-mail: kitiwi@kku.ac.th

Corresponding Author(s) : Manop Sriuttha1

Asian Journal of Chemistry, Vol 26 No Supplementary Issue

Abstract

The ability of cigarette filter added with chitosan (CFAC) for the Fe2+ removal from aqueous solution has been investigated by adsorption method. It is found that the Freundlich isotherm can well describe the Fe2+ adsorption capacity in CFAC. The experimental data suggests the pseudo-second-order equation represented as the adsorption model. The Fe2+ ions adsorb spontaneously on the CFAC and the possible process is more favorable at higher temperatures. The obtained DH° and DS° values indicate that the adsorption reaction is the endothermic and some structural changes appear at the adsorbent and randomly occur at the solid/liquid interface, respectively. In addition, the computational approach has been performed to show the binding interaction between the Fe2+ and the chitosan. The result suggests that nitrogen atoms of chitosan are the preferential adsorption site for Fe2+. This work is worth to see the ability of the new adsorbent for further development of metal removal from the aqueous solution that is the application for waste water treatment.

Keywords

Chitosan gel Adsorption Kinetics adsorption Thermodynamics Molecular dynamic Simulation.
Sriuttha1, M., Chanajaree2, R., Tongpoothorn3, W., & Wittayanarakul1, K. (2014). A Combined Experimental/Computational Study on Adsorption of Fe2+ by Cigarette Filter Added with Chitosan. Asian Journal of Chemistry, 26(27), 189–194. https://doi.org/10.14233/ajchem.2014.19043
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