Copyright (c) 2014 ian Kannan*, J. Ilavarasi Jeyamalar
This work is licensed under a Creative Commons Attribution 4.0 International License.
Green Synthesis of Energy Rich Petroleum Additive Over Mg-KMSU-11 Solid Acid Catalyst
Corresponding Author(s) : ian Kannan*
Asian Journal of Chemistry,
Vol 26 No Supplementary Issue
Abstract
Glycerol is a major byproduct in the biodiesel industries and disposal of glycerol limiting the biodiesel production. In this article, a new nano porous solid acid catalyst is developed, which converts glycerol into glycerol ether. The synthesized catalyst is characterized by various spectroscopic techniques like XRD, FT-IR, BET surface area, TGA and SEM to confirm its activity and stability. The catalyst pore size is 11 nm, it has high pore size compare to the literature report (2 to 4 nm) and also active at lower temperature (150 °C). This new material is named as Mg-KMSU-11.
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- M. Roze, V. Kampars, K. Teivena, R. Kampare and E. Liepins, Mater. Sci. Appl. Chem., 28, 67 (2013).
- M. Pagliaro, R. Ciriminna, H. Kimura, M. Rossi and C. Della Pina, Eur. J. Lipid Sci. Technol., 111, 788 (2009).
- A.E. Díaz-Álvarez, J. Francos, B. Lastra-Barreira, P. Crochet and V. Cadierno, Chem. Commun., 47, 6208 (2011).
- A. Martin and M. Richter, Eur. J. Lipid Sci. Technol., 113, 100 (2011).
- J.A. Melero, R. van Grieken, G. Morales and M. Paniagua, Energy Fuels, 21, 1782 (2007).
- E. Kaya, N. Oktar, G. Karakas and K. Murtezaoglu, Turk. J. Chem., 34, 935 (2010).
- M. Tanaka, A. Itadani, Y. Kuroda and M. Iwamoto, J. Phys. Chem. C, 116, 5664 (2012).
- O.A. Anunziata, M.L. Martínez and A.R. Beltramone, Materials, 2, 1508 (2009).
- C. Kannan, K. Muthuraja and M.R. Devi, J. Hazard. Mater., 244-245, 10 (2013).
- N.N. Tušar, A. Ristic, G. Mali, M. Mazaj, I. Arcon, D. Arcon, V. Kaucic and N.Z. Logar, Chem. Eur. J., 16, 5783 (2010).
- C. Kannan, K. Sivakami and J. Ilavarasi Jeyamalar, Mater. Lett., 113, 93 (2013).
- X.-D. Li and Q.-Z. Zhai, J. Iran. Chem. Soc., 8(S1), S1 (2011).
- H.B. Hassan, M.A. Abdel Rahim, M.W. Khalil and R.F. Mohammed, Int. J. Electrochem. Sci., 9, 760 (2014).
References
M. Roze, V. Kampars, K. Teivena, R. Kampare and E. Liepins, Mater. Sci. Appl. Chem., 28, 67 (2013).
M. Pagliaro, R. Ciriminna, H. Kimura, M. Rossi and C. Della Pina, Eur. J. Lipid Sci. Technol., 111, 788 (2009).
A.E. Díaz-Álvarez, J. Francos, B. Lastra-Barreira, P. Crochet and V. Cadierno, Chem. Commun., 47, 6208 (2011).
A. Martin and M. Richter, Eur. J. Lipid Sci. Technol., 113, 100 (2011).
J.A. Melero, R. van Grieken, G. Morales and M. Paniagua, Energy Fuels, 21, 1782 (2007).
E. Kaya, N. Oktar, G. Karakas and K. Murtezaoglu, Turk. J. Chem., 34, 935 (2010).
M. Tanaka, A. Itadani, Y. Kuroda and M. Iwamoto, J. Phys. Chem. C, 116, 5664 (2012).
O.A. Anunziata, M.L. Martínez and A.R. Beltramone, Materials, 2, 1508 (2009).
C. Kannan, K. Muthuraja and M.R. Devi, J. Hazard. Mater., 244-245, 10 (2013).
N.N. Tušar, A. Ristic, G. Mali, M. Mazaj, I. Arcon, D. Arcon, V. Kaucic and N.Z. Logar, Chem. Eur. J., 16, 5783 (2010).
C. Kannan, K. Sivakami and J. Ilavarasi Jeyamalar, Mater. Lett., 113, 93 (2013).
X.-D. Li and Q.-Z. Zhai, J. Iran. Chem. Soc., 8(S1), S1 (2011).
H.B. Hassan, M.A. Abdel Rahim, M.W. Khalil and R.F. Mohammed, Int. J. Electrochem. Sci., 9, 760 (2014).