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Vol 26 No Supplementary Issue

Copyright (c) 2014 I.J. Shamsudin1, A. Ahmad1, N.H. Hassan1, H. Kaddami3

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Solid Biopolymer Electrolyte Based on k-Carrageenan for Electrochemical Devices Application

https://doi.org/10.14233/ajchem.2014.19019
I.J. Shamsudin1
1School of Chemical Sciences and Food Technology, Faculty of Science and Technology, University Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia 2Department of Chemistry, Centre for Defence Foundation Studies, National Defence University of Malaysia, 57000 Kuala Lumpur, Malaysia 3Department of Chemistry, Faculty of Sciences and Technology of Marrakech, Cadi Ayyad University, Av. A. Elkhattabi, B.P. 549, Marrakech 40000, Morocco *Corresponding author: Fax: +60 3 89212115; Tel: +60 3 89287262; E-mail: azizan@ukm.edu.my
A. Ahmad1
1School of Chemical Sciences and Food Technology, Faculty of Science and Technology, University Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia 2Department of Chemistry, Centre for Defence Foundation Studies, National Defence University of Malaysia, 57000 Kuala Lumpur, Malaysia 3Department of Chemistry, Faculty of Sciences and Technology of Marrakech, Cadi Ayyad University, Av. A. Elkhattabi, B.P. 549, Marrakech 40000, Morocco *Corresponding author: Fax: +60 3 89212115; Tel: +60 3 89287262; E-mail: azizan@ukm.edu.my
N.H. Hassan1
1School of Chemical Sciences and Food Technology, Faculty of Science and Technology, University Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia 2Department of Chemistry, Centre for Defence Foundation Studies, National Defence University of Malaysia, 57000 Kuala Lumpur, Malaysia 3Department of Chemistry, Faculty of Sciences and Technology of Marrakech, Cadi Ayyad University, Av. A. Elkhattabi, B.P. 549, Marrakech 40000, Morocco *Corresponding author: Fax: +60 3 89212115; Tel: +60 3 89287262; E-mail: azizan@ukm.edu.my
H. Kaddami3
1School of Chemical Sciences and Food Technology, Faculty of Science and Technology, University Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia 2Department of Chemistry, Centre for Defence Foundation Studies, National Defence University of Malaysia, 57000 Kuala Lumpur, Malaysia 3Department of Chemistry, Faculty of Sciences and Technology of Marrakech, Cadi Ayyad University, Av. A. Elkhattabi, B.P. 549, Marrakech 40000, Morocco *Corresponding author: Fax: +60 3 89212115; Tel: +60 3 89287262; E-mail: azizan@ukm.edu.my

Corresponding Author(s) : I.J. Shamsudin1

Asian Journal of Chemistry, Vol 26 No Supplementary Issue

Abstract

Solid biopolymer electrolyte based on kappa, k-carrageenan as the polymer host and ionic liquid 1-butyl-3-methylimidazolium chloride, [Bmim]Cl as the charge carrier has been successfully prepared. The ionic conductivity, (s) of the electrolytes significantly increase with the increase of weight percentage, (wt. %) of [Bmim]Cl. The highest s attained is 2.44 × 10-3 S cm-1 at ambient temperature. FTIR spectra confirmed the complexation and interactions of k-carrageenan and [Bmim]Cl. XRD diffractograms revealed that inclusion of [Bmim]Cl has increased the amorphous nature of k-carrageenan. SEM observations showed the smoother surface morphologies of the polymer electrolytes as the wt. % of [Bmim]Cl increases.

Keywords

k-Carrageenan Ionic liquid 1-Butyl-3-methylimidazolium chloride Biopolymer electrolytes Ionic conductivity.
Shamsudin1, I., Ahmad1, A., Hassan1, N., & Kaddami3, H. (2014). Solid Biopolymer Electrolyte Based on k-Carrageenan for Electrochemical Devices Application. Asian Journal of Chemistry, 26(27), 77–80. https://doi.org/10.14233/ajchem.2014.19019
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