Issue

Vol 26 No Supplementary Issue

Copyright (c) 2014 S. Jodeh1, O. Hamed1, M. Mohamed1, T. Ben Hadda2, B. Hammouti3, R. Salghi4, S. Radi3, A. Abu Obaid1, I. Warad1

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Removal of Phenol from Olive Industry Liquid Waste Using Polyitaconic Acid

https://doi.org/10.14233/ajchem.2014.19004
S. Jodeh1
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
O. Hamed1
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
M. Mohamed1
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
T. Ben Hadda2
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
B. Hammouti3
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
R. Salghi4
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
S. Radi3
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
A. Abu Obaid1
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu
I. Warad1
1Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, State of Palestine 2Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, Oujda-60000, Morocco 3LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, BP 4808, Oujda, Morocco 4Laboratory of Environmental Engineering and Biotechnology, ENSA, University Ibn Zohr, P.O. Box 1136, 80000 Agadir, Morocco *Corresponding author: Fax: +97 92345982; Tel: +97 599590498; E-mail: sjodeh@najah.edu

Corresponding Author(s) : S. Jodeh1

Asian Journal of Chemistry, Vol 26 No Supplementary Issue

Abstract

This study focuses on a new approach for removal of phenol from an aqueous solution. In this approach cross-linked polyitaconic acid was used as phenol adsorpent. Cross-linked polyitaconic acid was prepared from itaonic acid and the cross-linking agent 1,4-butane diglcidyl ether using chain growth polymerization technique. The adsorption property of cross-linked polyitaconic acid was investigated in terms of adsorbent dosage, pH, temperature, contact time and contaminant concentration. The adsorption capacity of cross-linked polyitaconic acid was studied using Freundlich and Langmuir models at equilibrium to determine mechanism of adsorption process whether it is a chemical or physical process. It appears that analysis of the adsorption mechanism suggested that hydrogen bonding was the primary driving force for phenol adsorbed on the polymeric adsorbents in cyclohexane and multiple hydrogen bonding was involved for poly(N-methyl-N-p-vinylbenzylurea (PMVBU) with phenol. The results also showed that the adsorption properties of cross-linked polyitaconic acid model followed Langmuir model with B value of 0.031 which support our results in that the adsorption is favorable. The pseudo-second-order model was the best for describing the kinetic adsorption of phenol with correlation coefficient valued (R2) is being 0.9975 and, K2 and qe of 0.0118, 11.933, respectively. This validated that the adsorption process was a chemical adsorption.

Keywords

Polyitaconic acid Phenol Adsorption Wastewater Isotherm Olive waste.
Jodeh1, S., Hamed1, O., Mohamed1, M., Ben Hadda2, T., Hammouti3, B., Salghi4, R., … Warad1, I. (2014). Removal of Phenol from Olive Industry Liquid Waste Using Polyitaconic Acid. Asian Journal of Chemistry, 26(27), 15–22. https://doi.org/10.14233/ajchem.2014.19004
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