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Vol. 29 No. 9 (2017): Vol 29 Issue 9

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Synthesis of Spinel ZnFe2O4 Modified with SDS via Low Temperature Combustion Method and Adsorption Behaviour of Crystal Violet Dye

https://doi.org/10.14233/ajchem.2017.20827
Mukesh Kumar
Department of Chemistry, School of Physical Sciences, Lovely Professional University, Phagwara-144 411, India
Harmanjit Singh Dosanjh
Department of Chemistry, School of Physical Sciences, Lovely Professional University, Phagwara-144 411, India
Harminder Singh
Department of Chemistry, School of Physical Sciences, Lovely Professional University, Phagwara-144 411, India

Corresponding Author(s) : Harminder Singh

harminder.singh@lpu.co.in; harminder_env@yahoo.com

Asian Journal of Chemistry, Vol. 29 No. 9 (2017): Vol 29 Issue 9

Abstract

Nano materials such as nano ferrites and their composites have been intensively investigated for water treatment. In present study nano zinc ferrites were successfully synthesized using low temperature combustion method and the surface of nano zinc ferrite was modified with surfactant sodium dodecyl sulphate (SDS). The characterization and morphology of zinc ferrite have been studied by FTIR, SEM and XRD techniques. Sodium dodecyl sulphate modified zinc ferrite showed excellent adsorption behaviour toward crystal violet dye. The adsorption behaviour has been studied at various parameters such as pH, adsorbent dose, temperature, concentration and time. The experimental data obtained from adsorption studies have been analyzed by Langmuir, Freundlich, Temkin and D-R adsorption isotherm models at different temperatures. The data was well fitted in Langmuir isotherm model. The maximum adsorption capacity (Qo) at different temperatures as 298, 303 and 308 K were 135.5, 170.6 and 188.3 mg/g. The adsorption kinetics was studied by using pseudo first order, pseudo second order and intra particle diffusion model. The adsorption kinetics was found to follow the pseudo second order kinetic model. Adsorption thermodynamic parameters DG°, DH°and DS° have been calculated from experimental data and indicated that the adsorption process was spontaneous in nature. The results showed that SDS-Zn ferrites as a magnetic adsorbent might be a suitable alternative to remove dyes from waste water.

Keywords

Spinel Zn ferrite Low temperature combustion method Surface modification Adsorption Kinetics Adsorption isotherm
Kumar, M., Dosanjh, H. S., & Singh, H. (2017). Synthesis of Spinel ZnFe2O4 Modified with SDS via Low Temperature Combustion Method and Adsorption Behaviour of Crystal Violet Dye. Asian Journal of Chemistry, 29(9), 2057–2064. https://doi.org/10.14233/ajchem.2017.20827
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