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Vol. 29 No. 9 (2017): Vol 29 Issue 9

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Synthesis, Characterization and Analytical Applications of Novel Electroactive Sensor based on Titanium(IV) Tungstovanadate for Determination of Cadmium

https://doi.org/10.14233/ajchem.2017.20752
Harish Kumar Sharma
Department of Chemistry, Maharishi Markandeshwar University, Sadopur, Ambala-134 007, India
Anju Parmar
Department of Chemistry, Maharishi Markandeshwar University, Mullana, Ambala-133 207, India
Pernita Dogra
Department of Chemistry, Maharishi Markandeshwar University, Sadopur, Ambala-134 007, India

Corresponding Author(s) : Pernita Dogra

microsil98@yahoo.co.in

Asian Journal of Chemistry, Vol. 29 No. 9 (2017): Vol 29 Issue 9

Abstract

The novel exchanger titanium(IV) tungstovanadate has been prepared by sol-gel method. The characterization of sensor has been done with FTIR, SEM, EDS and X-ray diffraction studies. Membranes containing different composition of electroactive material and epoxy resin as binder were prepared. The membrane with 60 % electroactive material and 40 % epoxy binder gives the best response. Potentiometric result shows that the sensor can be used in the concentration range of 10-7 to 10-1 M Cd(II) ions with a near Nernstian slope of 21 mV/decade. The electrode shows a fast response time of < 10 sec. The working pH range of the electrode is 2.62 to 8.66 and it behaves well in the partially non aqueous medium upto 30 % concentration of ethanol, methanol and acetone. Fixed interference method was used for determining the selectivity coefficient with respect to different metal ions like Pb2+, Cr3+, La2+, Co2+, Hg2+, As3+, Cu2+, Ni2+, Mn2+, Sm3+ etc. and effect of internal solution was also studied. The developed sensor can be used as an indicator electrode in the potentiometric titration of Cd(II) against EDTA and oxalic acid.

Keywords

Titanium(IV) tungstovanadate Electroactive sensor Cadmium Selectivity coefficient
Sharma, H. K., Parmar, A., & Dogra, P. (2017). Synthesis, Characterization and Analytical Applications of Novel Electroactive Sensor based on Titanium(IV) Tungstovanadate for Determination of Cadmium. Asian Journal of Chemistry, 29(9), 2051–2056. https://doi.org/10.14233/ajchem.2017.20752
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