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Vol. 29 No. 9 (2017): Vol 29 Issue 9

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A Novel Approach of Partial Derivatives to Estimate the Normal Boiling Temperature via Viscosity Arrhenius Behaviour in N,N-Dimethylformamide + Ethanol Fluid Systems

https://doi.org/10.14233/ajchem.2017.20764
Mohamed Dallel
Université de Tunis El Manar, Laboratoire de Biophysique et Technologies Médicales, LR13ES07, Institut Supérieur des Technologies Médicales de Tunis, 9 Avenue Dr. Zouhaier Essafi 1006 Tunis, Tunisia
Ahlam A. Al-Arfaj
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
Nuhad A. Al-Omair
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
Mishael A. Alkhaldi
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
Noura O. Alzamel
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
Asala A. Al-Zahrani
University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
Noureddine Ouerfelli
Université de Tunis El Manar, Laboratoire de Biophysique et Technologies Médicales, LR13ES07, Institut Supérieur des Technologies Médicales de Tunis, 9 Avenue Dr. Zouhaier Essafi 1006 Tunis, Tunisia; University of Dammam, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia

Corresponding Author(s) : Ahlam A. Al-Arfaj

ahalarfaj@uod.edu.sa

Asian Journal of Chemistry, Vol. 29 No. 9 (2017): Vol 29 Issue 9

Abstract

The experimental values of absolute viscosity in N,N-dimethylformamide + ethanol binary fluid mixtures (from 303.15 to 323.15 K) can induce us to investigate different correlation expressions as well as their derivative quantities. Investigation of the molar enthalpy of viscous flow (DH*) and the viscosity activation energy (Ea) reveals close values and similar variation against composition, here we can justify the notion of partial activation energies Ea1 and Ea2 for pure components along with their separately individual contributions. Correlation between the two Arrhenius parameters in the whole range of compositions shows the existence of different interaction behaviours, delimited by peculiar compositions. It is also noticed that the ratio between the two parameters leads to the Arrhenius temperature which is in causal correlation with the temperature of vapourization in the liquid-vapour isobaric diagram and the limiting partial properties can permit us to predict values of the boiling temperatures of the pure fluid components.

Keywords

Binary fluid mixture Viscosity Activation energy Arrhenius temperature Boiling point
Dallel, M., Al-Arfaj, A. A., Al-Omair, N. A., Alkhaldi, M. A., Alzamel, N. O., Al-Zahrani, A. A., & Ouerfelli, N. (2017). A Novel Approach of Partial Derivatives to Estimate the Normal Boiling Temperature via Viscosity Arrhenius Behaviour in N,N-Dimethylformamide + Ethanol Fluid Systems. Asian Journal of Chemistry, 29(9), 2038–2050. https://doi.org/10.14233/ajchem.2017.20764
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