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Vol. 29 No. 9 (2017): Vol 29 Issue 9

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A Novel 4-(1H-Benzimidazol-2-yl)-2-methoxy-phenol Derived Fluorescent Sensor for Determination of CN– Ion

https://doi.org/10.14233/ajchem.2017.20662
R. Rahmawati
Study Program of Chemistry, Department of Education of Mathematics and Natural Sciences, Universitas Mataram, Jalan Majapahit 62, Mataram, Indonesia; Department of Chemistry, Universitas Gadjah Mada, Jalan Kaliurang Sekip Utara, Bulaksumur 21, Yogyakarta, Indonesia
B. Purwono
Department of Chemistry, Universitas Gadjah Mada, Jalan Kaliurang Sekip Utara, Bulaksumur 21, Yogyakarta, Indonesia
S. Matsjeh
Department of Chemistry, Universitas Gadjah Mada, Jalan Kaliurang Sekip Utara, Bulaksumur 21, Yogyakarta, Indonesia

Corresponding Author(s) : R. Rahmawati

mymine76@ymail.com

Asian Journal of Chemistry, Vol. 29 No. 9 (2017): Vol 29 Issue 9

Abstract

A novel fluorescent sensor 4-(1H-benzimidazol-2-yl)-2-methoxy-phenol derivative was synthesized. Solution of 4-(1H-benzimidazol-2-yl)-2-methoxy-phenol (1 × 10–7 M) in DMSO displays highly sensitives and rapid respons to CN– ion [values of LOD = 1.8 × 10–6 M and Ka = 2.5 (± 0.26) × 106 M–1]. Sensor 4-(1H-benzimidazol-2-yl)-2-methoxy-phenol coordinated with CN– ion form with a 1:1 binding stoichiometry.

Keywords

Fluorescent sensor Cyanide ion Benzimidazole
Rahmawati, R., Purwono, B., & Matsjeh, S. (2017). A Novel 4-(1H-Benzimidazol-2-yl)-2-methoxy-phenol Derived Fluorescent Sensor for Determination of CN– Ion. Asian Journal of Chemistry, 29(9), 1959–1962. https://doi.org/10.14233/ajchem.2017.20662
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