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Extraction of Essential Oils of Lemon Grass Using Ionic Liquid
Corresponding Author(s) : Toyonobu Usuki
Asian Journal of Chemistry,
Vol. 29 No. 2 (2017): Vol 29 Issue 2
Abstract
Geranial [(E)-3,7-dimethyl-2,6-octadienal], neral [(Z)-3,7-dimethyl-2,6-octadienal] and geraniol [(E)-3,7-dimethyl-2,6-octadien-1-ol] are found in lemon grass and are attractive essential oils with potential medicinal applications. In this study, a new method for extracting these natural flavour substances from lemon grass using co-solvent systems consisting of methanol or ethyl acetate and the ionic liquids 1-butyl-3-methylimidazolium chloride ([C4mim]Cl) or 1-ethyl-3-methylimidazolium methylphosphonate ([C2mim][(MeO)(H)PO2]) is described.
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- A.A. Kasali, A.O. Oyedeji and A.O. Ashilokun, Flav. Fragr. J., 16, 377 (2001).
- H. Wen, N. Aoki and R. Ohsugi, Trop. Agr. Develop., 56, 14 (2012).
- K.N. Agbafor and E.I. Akubugwo, Afr. J. Biotechnol., 6, 596 (2007).
- P. Kotzekidou, P. Giannakidis and A. Boulamatsis, Lebensm. Wiss. Technol., 41, 119 (2008).
- J.J. Mahanta, M. Chutia, M. Bordoloi, M.G. Pathak, R.K. Adhikary and T.C. Sarma, Flav. Fragr. J., 22, 525 (2007).
- H. Ohno and Y. Fukaya, Chem. Lett., 38, 2 (2009).
- N. Sun, H. Rodríguez, M. Rahman and R.D. Rogers, Chem. Commun., 47, 1405 (2011).
- Y. Dai, J. van Spronsen, G.-J. Witkamp, R. Verpoorte and Y.H. Choi, J. Nat. Prod., 76, 2162 (2013).
- R.P. Swatloski, S.K. Spear, J.D. Holbrey and R.D. Rogers, J. Am. Chem. Soc., 124, 4974 (2002).
- Y. Fukaya, K. Hayashi, M. Wada and H. Ohno, Green Chem., 10, 44 (2008).
- T. Usuki, N. Yasuda, M. Yoshizawa-Fujita and M. Rikukawa, Chem. Commun., 47, 10560 (2011).
- S. Onda, T. Usuki, M. Yoshizawa-Fujita and M. Rikukawa, Chem. Lett., 44, 1461 (2015).
- K. Bica, P. Gaertner and R.D. Rogers, Green Chem., 13, 1997 (2011).
- T. Liu, X. Sui, R. Zhang, L. Yang, Y. Zu, L. Zhang, Y. Zhang and Z. Zhang, J. Chromatogr. A, 1218, 8480 (2011).
- M.A. Desai and J. Parikh, ACS Sustain. Chem. Eng., 3, 421 (2015).
- B.T. Schaneberg and I.A. Khan, J. Agric. Food Chem., 50, 1345 (2002).
- C. Rolz, R. De Leon, M.C. De Arriola and S. De Cabrera, Appl. Environ. Microbiol., 52, 607 (1986).
- Y. Pu, N. Jiang and A.J. Ragauskas, J. Wood Chem. Technol., 27, 23 (2007).
- Y. Fukaya, A. Sugimoto and H. Ohno, Biomacromolecules, 7, 3295 (2006).
References
A.A. Kasali, A.O. Oyedeji and A.O. Ashilokun, Flav. Fragr. J., 16, 377 (2001).
H. Wen, N. Aoki and R. Ohsugi, Trop. Agr. Develop., 56, 14 (2012).
K.N. Agbafor and E.I. Akubugwo, Afr. J. Biotechnol., 6, 596 (2007).
P. Kotzekidou, P. Giannakidis and A. Boulamatsis, Lebensm. Wiss. Technol., 41, 119 (2008).
J.J. Mahanta, M. Chutia, M. Bordoloi, M.G. Pathak, R.K. Adhikary and T.C. Sarma, Flav. Fragr. J., 22, 525 (2007).
H. Ohno and Y. Fukaya, Chem. Lett., 38, 2 (2009).
N. Sun, H. Rodríguez, M. Rahman and R.D. Rogers, Chem. Commun., 47, 1405 (2011).
Y. Dai, J. van Spronsen, G.-J. Witkamp, R. Verpoorte and Y.H. Choi, J. Nat. Prod., 76, 2162 (2013).
R.P. Swatloski, S.K. Spear, J.D. Holbrey and R.D. Rogers, J. Am. Chem. Soc., 124, 4974 (2002).
Y. Fukaya, K. Hayashi, M. Wada and H. Ohno, Green Chem., 10, 44 (2008).
T. Usuki, N. Yasuda, M. Yoshizawa-Fujita and M. Rikukawa, Chem. Commun., 47, 10560 (2011).
S. Onda, T. Usuki, M. Yoshizawa-Fujita and M. Rikukawa, Chem. Lett., 44, 1461 (2015).
K. Bica, P. Gaertner and R.D. Rogers, Green Chem., 13, 1997 (2011).
T. Liu, X. Sui, R. Zhang, L. Yang, Y. Zu, L. Zhang, Y. Zhang and Z. Zhang, J. Chromatogr. A, 1218, 8480 (2011).
M.A. Desai and J. Parikh, ACS Sustain. Chem. Eng., 3, 421 (2015).
B.T. Schaneberg and I.A. Khan, J. Agric. Food Chem., 50, 1345 (2002).
C. Rolz, R. De Leon, M.C. De Arriola and S. De Cabrera, Appl. Environ. Microbiol., 52, 607 (1986).
Y. Pu, N. Jiang and A.J. Ragauskas, J. Wood Chem. Technol., 27, 23 (2007).
Y. Fukaya, A. Sugimoto and H. Ohno, Biomacromolecules, 7, 3295 (2006).