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Vol. 29 No. 2 (2017): Vol 29 Issue 2

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Regioselective Ring-Opening of Epoxides with Thiophenols in Presence of b-Cyclodextrin in Water

https://doi.org/10.14233/ajchem.2017.20172
Siping Tang
Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, Hunan Province, P.R. China; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang 421008, Hunan Province, P.R. China
Yuancheng Tang
Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, Hunan Province, P.R. China
Zhifeng Xu
Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, Hunan Province, P.R. China; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang 421008, Hunan Province, P.R. China
Yonglan Feng
Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, Hunan Province, P.R. China; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang 421008, Hunan Province, P.R. China
Junhua Li
Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, Hunan Province, P.R. China; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang 421008, Hunan Province, P.R. China
Peihong Deng
Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, Hunan Province, P.R. China; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang 421008, Hunan Province, P.R. China

Corresponding Author(s) : Siping Tang

tsp00@163.com

Asian Journal of Chemistry, Vol. 29 No. 2 (2017): Vol 29 Issue 2

Abstract

This paper reports a simple, mild and convenient method to synthesize b-hydroxysulfides. These b-hydroxysulfides were achieved with excellent yields (> 80 %) and high regioselectivity by ring-opening reaction of oxiranes with thiophenols in presence of the b-cyclodextrin at 30 °C in water. b-Cyclodextrin as catalyst greatly accelerated the reactions and can be recovered.

Keywords

b-Hydroxysulfides Oxiranes b-Cyclodextrin Thiophenol Regioselectivity
Tang, S., Tang, Y., Xu, Z., Feng, Y., Li, J., & Deng, P. (2016). Regioselective Ring-Opening of Epoxides with Thiophenols in Presence of b-Cyclodextrin in Water. Asian Journal of Chemistry, 29(2), 305–308. https://doi.org/10.14233/ajchem.2017.20172
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