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Vol. 29 No. 12 (2017): Vol 29 Issue 12

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Effect of Temperature on Micellization Properties of Binary Mixtures of Sodium Tetradecylsulphate with Sodium Decylsulphate and Sodium Dodecylsulphate in Water

https://doi.org/10.14233/ajchem.2017.20706
O.G. Singh
Department of Chemistry, Moirang College, Manipur-795 133, India

Corresponding Author(s) : O.G. Singh

oinamgobinsingh@yahoo.com

Asian Journal of Chemistry, Vol. 29 No. 12 (2017): Vol 29 Issue 12

Abstract

Critical micelle concentration (CMC) values of binary mixtures of sodium tetradecylsulphate (STS) with sodium decylsulphate (SDeS) and sodium dodecylsulphate (SDS) in water have been determined using conductance measurement method at four different temperatures ranging from 298 to 313 K at 5 K intervals. The variation in CMC and counterion binding constant as a function of temperature have been investigated. Mixed micelle composition, activity coefficient of the components and mutual interaction between the components in the mixed micelle in terms of interaction parameter have been estimated using Rubingh’s model. Variation of these mixed micellization parameters with temperature has been studied. The surfactant mixtures show attractive interaction between the components, which increases with increase in temperature. Thermodynamic parameters of mixed micellization have also been calculated and observed a linear correlation between the entropy change (DS°mic) and enthalpy change (DH°mic).

Keywords

Sodium tetradecylsulphate Sodium decylsulphate Sodium dodecylsulphate Mixed micelle Counterion binding constant
Singh, O. (2017). Effect of Temperature on Micellization Properties of Binary Mixtures of Sodium Tetradecylsulphate with Sodium Decylsulphate and Sodium Dodecylsulphate in Water. Asian Journal of Chemistry, 29(12), 2605–2610. https://doi.org/10.14233/ajchem.2017.20706
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