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Synthesis and Spectroscopic Investigations of Schiff Bases Transition Metal Complexes of Copper(II), Cobalt(II) and Nickel(II)
Corresponding Author(s) : B.K. Rai
Asian Journal of Chemistry,
Vol. 29 No. 12 (2017): Vol 29 Issue 12
Abstract
This work presents an experimental and theoretical study on complexes of copper(II), cobalt(II) and nickel(II) with Schiff base ligand 3-propyl-(N-o-toluidine)quinazoline semicarbazone (PTQS). The spectroscopic properties of the complexes have been investigated by IR and electronic spectra. The molecular geometry of the complexes have been proposed on the basis of elemental analyses, molar mass and magnetic susceptibility. It is suggested that the ligand PTQS acts in a bidentate manner and coordination proposes with azomethine N and carbonyl oxygen atom of semicarbazone moiety. The remaining coordination sites are occupied by negative ions such as Cl−, Br−, I−, NO3− and ClO4−. The geometry of complexes was assigned to be octahedral.
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- B.K. Rai, J. Indian Chem. Soc., 90, 105 (2013).
- R. Rai, R.R. Kumar, M. Kumar and B.K. Rai, Orient. J. Chem., 30, 303 (2014); https://doi.org/10.13005/ojc/300139.
- R. Kumari and B.K. Rai, Asian J. Chem., 26(Suppl.), S280 (2014); https://doi.org/10.14233/ajchem.2014.19065.
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References
R. Bastida, S. Gonzalez, T. Rodriguez,A. Sousa and D.E. Fenton, J. Chem. Soc., Dalton Trans., 3643 (1990); https://doi.org/10.1039/DT9900003643.
M.R. Malachowski, M. Adams, N. Elia, A.L. Rheingold and R.S. Kelly, J. Chem. Soc., Dalton Trans., 2177 (1999); https://doi.org/10.1039/A900223E.
L. Casella, M. Gullotti and R. Viganò,Inorg. Chim. Acta, 124, 121 (1986); https://doi.org/10.1016/S0020-1693(00)85860-0.
J.C. Liu, S.X. Wang, L.F. Wang, F.Y. He and X.Y. Huang, Polyhedron, 15, 3659 (1996); https://doi.org/10.1016/0277-5387(95)00523-4
M.E. Hossain, M.N. Alam, M.A. Ali, M. Nazimuddin, F.E. Smith and R.C. Hynes, Polyhedron, 15, 973 (1996); https://doi.org/10.1016/0277-5387(95)00310-X.
A.A.R. Despaigne, L.F. Vieira, I.C. Mendes, F.B. Costa, N.L. Speziali and H. Beraldo, J. Braz. Chem. Soc., 21, 1247 (2010); https://doi.org/10.1590/S0103-50532010000700012.
N. Nawar and N.M. Hosny, Chem. Pharm. Bull. (Tokyo), 47, 944 (1999); https://doi.org/10.1248/cpb.47.944.
M. Alagesan, N.S.P. Bhuvanesh and N. Dharmaraj, Dalton Trans., 42, 7210 (2013); https://doi.org/10.1039/c3dt50371b.
P.V. Bernhardt, G.J. Wilson, P.C. Sharpe, D.S. Kalinowski and D.R. Richardson, J. Biol. Inorg. Chem., 13, 107 (2008); https://doi.org/10.1007/s00775-007-0300-4.
J. Easmon, G. Purstinger, K.S. Thies, G. Heinisch and J. Hofmann, J. Med. Chem., 49, 6343 (2006); https://doi.org/10.1021/jm060232u.
A. Rescifina, M.G. Varrica, C. Carnovale, G. Romeo and U. Chiacchio, Eur. J. Med. Chem., 51, 163 (2012); https://doi.org/10.1016/j.ejmech.2012.02.038.
A. Narani, R.K. Marella, P. Ramudu, K.S.R. Rao and D.R. Burri, RSC Adv., 4, 3774 (2014); https://doi.org/10.1039/C3RA44213F.
J.P. Collman, M. Zhong, C. Zhang and S. Costanzo, J. Org. Chem., 66, 7892 (2001); https://doi.org/10.1021/jo010615u.
S.Y. Ebrahimipour, I. Sheikhshoaie, M. Mohamadi, S. Suarez, R. Baggio, M. Khaleghi, M. Torkzadeh-Mahani and A. Mostafavi, Spectrochim. Acta A, 142, 410 (2015); https://doi.org/10.1016/j.saa.2015.01.088.
M.M. Alam, G. Verma, M. Shaquiquzzaman, A. Marella, M. Akhtar and M.R. Ali, J. Pharm. Bioallied Sci., 6, 69 (2014); https://doi.org/10.4103/0975-7406.129170.
D. Dey, S. Pal, P.P. Bag, S. Saha and S. Chandraleka, J. Indian Chem. Soc., 92, 191 (2017).
N. Gayathri and M.S. Suresh, Asian J. Chem., 29, 541 (2017); https://doi.org/10.14233/ajchem.2017.20227.
J. Devi and M. Yadav, Asian J. Chem., 29, 551 (2017); https://doi.org/10.14233/ajchem.2017.20236.
A. Ahlawat, S. Asija and N. Singh, Asian J. Chem., 29, 669 (2017); https://doi.org/10.14233/ajchem.2017.20303.
N.T. Dhokale, B.K. Karale and A.V. Nagawade, Asian J. Chem., 29, 843 (2017); https://doi.org/10.14233/ajchem.2017.20329.
B.K. Rai and A. Kumar, Asian J. Chem., 25, 1169 (2013); https://doi.org/10.14233/ajchem.2013.13199A.
B.K. Rai, J. Indian Chem. Soc., 90, 105 (2013).
R. Rai, R.R. Kumar, M. Kumar and B.K. Rai, Orient. J. Chem., 30, 303 (2014); https://doi.org/10.13005/ojc/300139.
R. Kumari and B.K. Rai, Asian J. Chem., 26(Suppl.), S280 (2014); https://doi.org/10.14233/ajchem.2014.19065.
R. Rai,A. Baluni, P. Kumari and B.K. Rai, Asian J. Chem., 27, 2237 (2015); https://doi.org/10.14233/ajchem.2015.18640.
A.I. Vogel, A Textbook of Quantitative Chemical Analysis, Revised by J. Bessett, R.C. Denny, J.H. Jeffery and J. Mendham, ELBS, London, edn 5 (1997).
S. Silverstein and X.W. Francis, Spectrometric Identification of Organic Compounds, John Wiley & Sons, end 6 (2008).
W. Kemp, Organic Spectroscopy, Palgrove, New York, edn 3 (2008).
K. B. Gudasi, S. A. Patil, J. Serb. Chem. Soc., 17, 520 (2006).
P.P. Singh and V.P. Shukla, Inorg. Chim. Acta, 7, 493 (1973); https://doi.org/10.1016/S0020-1693(00)94870-9.
J.R. Ferraro, Low Frequency Vibration of Inorganic and Coordination Compound, Plenum Press, New York (1971).
D.M. Boghaei and N. Lashanizadegan, Synth React. Inorg. Metal-Org. Chem., 30, 1393 (2000); https://doi.org/10.1080/00945710009351841.
C.C. Addition, N. Logan, S.C. Wallwork and D.C. Garner, Quart. Rev., 25, 289 (1971).
H.L. Harikumaran Nair and C.P. Prathakaran, Indian J. Chem., 39A, 989 (2000).
B.N. Figgis, Introduction to Ligand Field, Wiley Eastern Ltd., New Delhi, p. 279 (1976).
R.N. Carlin and A.J. Van bryneveledt, Magnetic Properties of Transition Metal Complexes, Springer Verlag, New York (1997).