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Vol. 29 No. 12 (2017): Vol 29 Issue 12

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Gallium(III) Iodide Mediated Mild and Efficient Method for Synthesis of 4-Iodotetrahydropyrans by Cross-Cyclization of Epoxides and Homoallylic Alcohols

https://doi.org/10.14233/ajchem.2017.20814
K. Kamesu
Ragas Pharmaceuticals Private Limited (OPC), IDA Cherlapally, Hyderabad-500 051, India; Department of Chemistry, K L University, Vaddeswaram, Guntur-522 502, India
G.V. Krishnamohan
Department of Chemistry, K L University, Vaddeswaram, Guntur-522 502, India
K. Rajasekhar
Ragas Pharmaceuticals Private Limited (OPC), IDA Cherlapally, Hyderabad-500 051, India

Corresponding Author(s) : K. Rajasekhar

koorella.rajasekhar@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 12 (2017): Vol 29 Issue 12

Abstract

The synthesis of 4-iodotetrahydropyran derivatives has been achieved via gallium(III) iodide mediated cyclization of epoxides and homo-allylic alcohols. This is a single step diastereoselective method for the preparation of 4-iodotetrahydropyrans.

Keywords

Epoxides Homoallylic alcohols Tetrahydropyrans Gallium(III) iodide
Kamesu, K., Krishnamohan, G., & Rajasekhar, K. (2017). Gallium(III) Iodide Mediated Mild and Efficient Method for Synthesis of 4-Iodotetrahydropyrans by Cross-Cyclization of Epoxides and Homoallylic Alcohols. Asian Journal of Chemistry, 29(12), 2704–2706. https://doi.org/10.14233/ajchem.2017.20814
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