Issue

Vol. 29 No. 12 (2017): Vol 29 Issue 12

Copyright (c) 2017 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Effect of Temperature and Concentration on the Viscosity of Perchloric Acid

https://doi.org/10.14233/ajchem.2017.20812
Renu Loshali
Physical Chemistry Laboratory, Department of Chemistry, Kumaun University, S.S.J. Campus, Almora-263 601, India
Narain D. Kandpal
Physical Chemistry Laboratory, Department of Chemistry, Kumaun University, S.S.J. Campus, Almora-263 601, India

Corresponding Author(s) : Renu Loshali

renu.loshali@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 12 (2017): Vol 29 Issue 12

Abstract

In the present study, the effect of concentration and temperature on the viscosities of aqueous solution of perchloric acid is discussed. The experiments were done at 283.65 and 297.65 K. The three concentration regions in perchloric acid-water system have been identified from Jones-Dole viscosity equation and the positive value of B-coefficient indicates strong ion-solvent interaction or water structure making character. The effect of temperature on viscosity B-coefficient confirms that perchloric acid have water structure making character.

Keywords

Perchloric acid Jones-Dole equation B-coefficient
Loshali, R., & Kandpal, N. D. (2017). Effect of Temperature and Concentration on the Viscosity of Perchloric Acid. Asian Journal of Chemistry, 29(12), 2701–2703. https://doi.org/10.14233/ajchem.2017.20812
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. B.K. Joshi and N.D. Kandpal, Phys. Chem. Liq., 45, 463 (2007); https://doi.org/10.1080/00319100600801843.
  2. N.D. Kandpal and B.K. Joshi, Phys. Chem. Indian J., 2, 95 (2007).
  3. K. Kandpal, B.K. Joshi, S.K. Joshi and N.D. Kandpal, E-J. Chem., 4, 574 (2007); https://doi.org/10.1155/2007/850578.
  4. R. Mathpal, B.K. Joshi, S. Joshi and N.D. Kandpal, Monatsh. Chem., 137, 375 (2006); https://doi.org/10.1007/s00706-005-0435-3.
  5. N.D. Kandpal and B.K. Joshi, Phys. Chem. Liq., 47, 250 (2009); https://doi.org/10.1080/00319100701785127.
  6. P. Khanuja, V.R. Chourey and A.A. Ansari, Der Chem. Sin., 3, 948 (2012).
  7. G.R. Bedare, V.D. Bhandakkar and B.M. Suryavanshi, Der Chem. Sin., 4, 132 (2013).
  8. D. Montano, H. Artigas, F.M. Royo and C. Lafuente, Int. J. Thermophys., 34, 34 (2013); https://doi.org/10.1007/s10765-012-1371-1.
  9. K.E. Lee, I. Khan, N. Morad, T.T. Teng and B.T. Poh, J. Solution Chem., 42, 27 (2013); https://doi.org/10.1007/s10953-012-9952-y.
  10. Y. Zheng, K. Dong, Q. Wang, J. Zhang and X. Lu, J. Chem. Eng. Data, 58, 32 (2013); https://doi.org/10.1021/je3004904.
  11. A.I. Karelin, Z.I. Grigorovich and V.Y. Rosolovskii, Spectrochim Acta A Molecul. Spectroscopy, 31, 765 (1975); https://doi.org/10.1016/0584-8539(75)80071-7.
  12. R.W. Duerst, J. Chem. Phys., 48, 2275 (1968); https://doi.org/10.1063/1.1669425.
  13. L.H. Jones and R.A. Penneman, J. Chem. Phys., 21, 542 (1953); https://doi.org/10.1063/1.1698941.
  14. P.S. Knapp, R.O. Waite and E.R. Malinowski, J. Chem. Phys., 49, 5459 (1968); https://doi.org/10.1063/1.1670072.
  15. J.W. Akitt,A.K. Covington, J.G. Freeman and T.H. Lilley, Trans. Faraday Soc., 65, 2701 (1969); https://doi.org/10.1039/tf9696502701.
  16. A.I. Karelin and V.A. Tarasenko, Russ.Chem. Bull. Int. Ed., 52, 1959 (2003); https://doi.org/10.1023/B:RUCB.0000009638.87726.ea.
  17. H.S. Harned and N.N.T. Samaras, J. Am. Chem. Soc., 54, 9 (1932); https://doi.org/10.1021/ja01340a002.
  18. A. D’Aprano, J. Phys. Chem., 75, 3290 (1971); https://doi.org/10.1021/j100690a014.
  19. T. Corridoni, R. Mancinelli, M.A. Ricci and F. Bruni, J. Phys. Chem. B, 115, 14008 (2011); https://doi.org/10.1021/jp202755u.
  20. A.K. Soper, Chem. Phys., 258, 121 (2000); https://doi.org/10.1016/S0301-0104(00)00179-8.
  21. H. Ohtaki and T. Radnai, Chem. Rev., 93, 1157 (1993); https://doi.org/10.1021/cr00019a014.
  22. E.V. Vinogradov, P.R. Smirnov and V.N. Trostin, Russ. Chem. Bull., 52, 1253 (2003); https://doi.org/10.1023/A:1024850421598.
  23. Y. Marcus, Chem. Rev., 109, 1346 (2009); https://doi.org/10.1021/cr8003828.
  24. S. Bouazizi and S. Nasr, J. Mol. Liq., 162, 78 (2011); https://doi.org/10.1016/j.molliq.2011.06.004.
  25. R. Loshali, B. Chandra, N. Sah and N.D. Kandpal, Int. J. Chem. Sci., 12, 1439 (2014).
  26. N.H. El Hammamy, A.I. Kawana, M.N. El Hammamy and H.M. Moharem, Adv. Appl. Sci. Res., 2, 86 (2011).
  27. F.H. Rhodes and C.B. Barbour, Ind. Eng. Chem., 15, 850 (1923); https://doi.org/10.1021/ie50164a033.
  28. R. Loshali and N. Datt Kandpal, J. Chil. Chem. Soc., 62, 3386 (2017); https://doi.org/10.4067/S0717-97072017000100016.
  29. H.J.V. Tyrrell and M. Kennerley, J. Chem. Soc. A: Inorg. Phys. Theor., 408, 2724 (1968); https://doi.org/10.1039/J19680002724.
  30. M. Natarajan, R.K. Wadi and H.C. Gaur, J. Chem. Eng. Data, 35, 87 (1990); https://doi.org/10.1021/je00059a024.
  31. H. Zhao, Biophys. Chem., 122, 157 (2006); https://doi.org/10.1016/j.bpc.2006.03.008.
  32. B.S. Lark, P. Patyar and T.S. Banipal, J. Chem. Thermodyn., 39, 344 (2007); https://doi.org/10.1016/j.jct.2006.08.005.
  33. T.S. Banipal and G. Singh, Thermochim. Acta, 412, 63 (2004); https://doi.org/10.1016/j.tca.2003.08.026.
  34. S. Kant and V. Akashdeep, J. Indian Chem. Soc., 87, 873 (2010).
  35. M.R. Carmen and B. Alejandro, Rev. Colomb. Quim., 41, 123 (2012).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0