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Luminescence and Electrochemical Properties of Organostannoxane Coordination Polymer Based on Ferrocenyl-2-Cyano Carboxylate Ligand
Corresponding Author(s) : Nallasamy Palanisami
Asian Journal of Chemistry,
Vol. 29 No. 12 (2017): Vol 29 Issue 12
Abstract
Organostannoxane-based multiredox assemblies containing ferrocenyl peripheries have been readily synthesized by a simple one-pot synthesis, with quantitative yields. The reaction of triorganotin oxides, (nBuSn)2O with 2-cyano-3-ferrocenyl acrylic acid leads to the formation of [(nBu3SnOC(O)CNCHFc)n] polymeric structure. FT-IR, NMR, UV-Vis and emission spectroscopic techniques were performed for the characterization of [(nBu3SnOC(O)CNCHFc)n](Fc = h5C5H4-Fe-h5C5H4) polymeric structure. Electrochemical studies on these hybrid organotin/ferrocene systems reveal that most of them exhibit a single quasi-reversible oxidation peak.
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- F. Frehill, K.H.G. Schulte, C.P. Martin, L. Wang, S. Patel, J.A. Purton, J.G. Vos and P. Moriarty, Langmuir, 20, 6421 (2004); https://doi.org/10.1021/la036414y.
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- J. Beckmann and J. Bolsinger, Organometallics, 26, 3601 (2007); https://doi.org/10.1021/om070084l.
- L. Cuffe, R.D.A. Hudson, J.F. Gallagher, S. Jennings, C.J. McAdam, R.B.T. Connelly, A.R. Manning, B.H. Robinson and J. Simpson, Organometallics, 24, 2051 (2005); https://doi.org/10.1021/om0492653.
- K. Senthilkumar, M. Gopalakrishnan and N. Palanisami, Spectrochim. Acta Part A, 148, 156 (2015); https://doi.org/10.1016/j.saa.2015.03.133.
- A. Béziau, S.A. Baudron and M.W. Hosseini, Dalton Trans., 41, 7227 (2012); https://doi.org/10.1039/c2dt30549f.
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References
F. Frehill, K.H.G. Schulte, C.P. Martin, L. Wang, S. Patel, J.A. Purton, J.G. Vos and P. Moriarty, Langmuir, 20, 6421 (2004); https://doi.org/10.1021/la036414y.
N. Das,A.M. Arif, P.J. Stang, M. Sieger, B. Sarkar, W. Kaim and J. Fiedler, J. Inorg. Chem., 44, 5798 (2005); https://doi.org/10.1021/ic0481834.
V. Chandrasekhar and R. Thirumoorthi, Organometallics, 26, 5415 (2007); https://doi.org/10.1021/om700622r.
D. Braga, L. Maini, M. Polito, E. Tagliavini and F. Grepioni, Coord. Chem. Rev., 246, 53 (2003); https://doi.org/10.1016/S0010-8545(03)00108-5.
V. Chandrasekhar, J. Goura, K. Gopal, J. Liu and P. Goddard, Polyhedron, 72, 35 (2014); https://doi.org/10.1016/j.poly.2014.01.017.
K.A. Williams, A.J. Boydston and C.W. Bielawski, Chem. Soc. Rev., 36, 729 (2007); https://doi.org/10.1039/B601574N.
V. Chandrasekhar, S. Nagendran, S. Bansal, M.A. Kozee and D.R. Powell, Angew. Chem. Int. Ed., 39, 1833 (2000); https://doi.org/10.1002/(SICI)1521-3773(20000515)39:10<1833::AID-ANIE1833>3.0.CO;2-3.
J.-L. Fillaut, J. Linares and D. Astruc, New J. Chem., 16, 305 (1992).
M. Watanabe, Y.J. Chang, P.-T. Chou, A. Staykov, M. Shibahara, K. Sako, T. Ishihara and T.J. Chow, Tetrahedron Lett., 56, 1548 (2015); https://doi.org/10.1016/j.tetlet.2015.02.012.
M. Kondo, R. Shinagawa, M. Miyazawa, M.K. Kabir, Y. Irie, T. Horiba, T. Naito, K. Maeda, S. Utsuno and F. Uchida, Dalton Trans., 515 (2003); https://doi.org/10.1039/B210475J.
P.A. Chase, R.J.M.K. Gebbink and G. van Koten, J. Organomet. Chem., 689, 4016 (2004); https://doi.org/10.1016/j.jorganchem.2004.07.032.
H. Puff, W. Schuh, R. Sievers, W. Wald and R. Zimmer, J. Organomet. Chem., 260, 271 (1984); https://doi.org/10.1016/S0022-328X(00)99476-2.
V. Chandrasekhar, K. Gopal, S. Nagendran, P. Singh,A. Steiner, S. Zacchini and J.F. Bickley, Chem. Eur. J., 11, 5437 (2005); https://doi.org/10.1002/chem.200500316.
V. Chandrasekhar and R. Thirumoorthi, Dalton Trans., 39, 2684 (2010); https://doi.org/10.1039/b922044e.
J. Beckmann and J. Bolsinger, Organometallics, 26, 3601 (2007); https://doi.org/10.1021/om070084l.
L. Cuffe, R.D.A. Hudson, J.F. Gallagher, S. Jennings, C.J. McAdam, R.B.T. Connelly, A.R. Manning, B.H. Robinson and J. Simpson, Organometallics, 24, 2051 (2005); https://doi.org/10.1021/om0492653.
K. Senthilkumar, M. Gopalakrishnan and N. Palanisami, Spectrochim. Acta Part A, 148, 156 (2015); https://doi.org/10.1016/j.saa.2015.03.133.
A. Béziau, S.A. Baudron and M.W. Hosseini, Dalton Trans., 41, 7227 (2012); https://doi.org/10.1039/c2dt30549f.
W.-C. Yen, H.-C. Lin, J.-S. Huang, Y.-J. Huang and Y.-L. Chueh, Sci. Adv. Mater., 6, 1 (2014); https://doi.org/10.1166/sam.2014.1674.
V. Chandrasekhar, S. Nagendran, S. Bansal, M.A. Kozee and D.R. Powell, Angew. Chem., 112, 1903 (2000); https://doi.org/10.1002/(SICI)1521-3757(20000515)112:10<1903::AID-ANGE1903>3.0.CO;2-5.