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Vol. 29 No. 12 (2017): Vol 29 Issue 12

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A Novel Three-Fold Interpenetrating Three-Dimensional Co(II) Coordination Polymer Based on Flexible Bistriazole Ligand: Synthesis, Structure and Magnetic Properties

https://doi.org/10.14233/ajchem.2017.20740
J.L. Lu
School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng 224051, P.R. China
Y.S. Xue
School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng 224051, P.R. China
J. Wei
School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng 224051, P.R. China
T. Zhou
School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng 224051, P.R. China

Corresponding Author(s) : Y.S. Xue

xueys1988@163.com; yunshanxue1988@163.com

Asian Journal of Chemistry, Vol. 29 No. 12 (2017): Vol 29 Issue 12

Abstract

A three-fold interpenetrating three-dimensional Co(II) coordination polymer, [Co(BTB)3(BF4)2]n (1) [BTB = 1,4-bis(1,2,4-triazol-1-yl)-butane] has been prepared and characterized through IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis revealed that complex 1 is 3-fold interpenetrating a-polonium cubic network. In addition, complex 1 exhibits very weak antiferromagnetic coupling between Co(II) ions in low temperature.

Keywords

Coordination polymer 1,4-Bis(1,2,4-triazol-1-yl)butane Copper complex Antiferromagnetic
Lu, J., Xue, Y., Wei, J., & Zhou, T. (2017). A Novel Three-Fold Interpenetrating Three-Dimensional Co(II) Coordination Polymer Based on Flexible Bistriazole Ligand: Synthesis, Structure and Magnetic Properties. Asian Journal of Chemistry, 29(12), 2643–2646. https://doi.org/10.14233/ajchem.2017.20740
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