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Vol. 26 No. 24 (2014)

Copyright (c) 2014 C.X. Zhao1, Y.J. Ding2, T.T. Yuan1, D.Y. Wanyan1, Y.J. Guo1, Z.Z. Hu1, X. Li1

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Syntheses and Crystal Structure of Ce(IV) Complex Containing 4-Heterocyclic Acylpyrazolone

https://doi.org/10.14233/ajchem.2014.18477
C.X. Zhao1
1College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China 2Institute of Medicinal Chemistry, College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China *Corresponding author: Tel/Fax: +86 394 8178253; E-mail: yongjieding@163.com
Y.J. Ding2
1College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China 2Institute of Medicinal Chemistry, College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China *Corresponding author: Tel/Fax: +86 394 8178253; E-mail: yongjieding@163.com
T.T. Yuan1
1College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China 2Institute of Medicinal Chemistry, College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China *Corresponding author: Tel/Fax: +86 394 8178253; E-mail: yongjieding@163.com
D.Y. Wanyan1
1College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China 2Institute of Medicinal Chemistry, College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China *Corresponding author: Tel/Fax: +86 394 8178253; E-mail: yongjieding@163.com
Y.J. Guo1
1College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China 2Institute of Medicinal Chemistry, College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China *Corresponding author: Tel/Fax: +86 394 8178253; E-mail: yongjieding@163.com
Z.Z. Hu1
1College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China 2Institute of Medicinal Chemistry, College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China *Corresponding author: Tel/Fax: +86 394 8178253; E-mail: yongjieding@163.com
X. Li1
1College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China 2Institute of Medicinal Chemistry, College of Chemistry and Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P.R. China *Corresponding author: Tel/Fax: +86 394 8178253; E-mail: yongjieding@163.com

Corresponding Author(s) : C.X. Zhao1

Asian Journal of Chemistry, Vol. 26 No. 24 (2014)

Abstract

A novel Ce complex of 4-acylpyrazolones of formula [Ce(CPTP)4] (C6H5CH3)3 (HCPTP = 1-(4-chlorophenyl)-3-phenyl-4-thenoyl-1H-pyrazol-5-ol) has been synthesized and characterized. It crystallizes in the triclinic space group P-1 with a = 12.9770(12) Å, b = 16.7877(15) Å, c = 21.8362(19) Å; a = 105.5250(10)º, b = 93.389(2)º, g = 99.209(2)º, V = 4498.4(7) Å3, C101H72N8O8S4CeCl4, Mr = 1935.87, Z = 2, Dc = 1.429 g/cm3, m = 0.781 mm-1, F(000) = 1976, R = 0.0312 and wR = 0.0696 for 16643 observed reflections with I > 2s(I). The complex is mononuclear. In air and solution stable compounds containing an eight-coordinated Ce(IV) center in a distorted dodecahedral configuration, the average Ce-O bond length is 2.3351(14) Å.

Keywords

Acylpyrazolone complex Cerium Crystal structure.
Zhao1, C., Ding2, Y., Yuan1, T., Wanyan1, D., Guo1, Y., Hu1, Z., & Li1, X. (2014). Syntheses and Crystal Structure of Ce(IV) Complex Containing 4-Heterocyclic Acylpyrazolone. Asian Journal of Chemistry, 26(24), 8604–8606. https://doi.org/10.14233/ajchem.2014.18477
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