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Vol. 26 No. 24 (2014)

Copyright (c) 2014 Yongfen Wang1, Chuanzhou Bian2

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Crystal Structure of [a-(2,4-Difluorophenyl)-a-(1H-1,2,4-triazole-1-ylmethyl)-1H-1,2,4-triazole-1-ethanol]Cu(II) Complex

https://doi.org/10.14233/ajchem.2014.18408
Yongfen Wang1
1College of Life Science, ShanXi Normal University, Xi'an 710062, P.R. China 2Academy of Bioengineering, Henan University of Animal Husbandry and Economy, Zhengzhou 450011, P.R. China *Corresponding author: E-mail: jyzhang2004@126.com
Chuanzhou Bian2
1College of Life Science, ShanXi Normal University, Xi'an 710062, P.R. China 2Academy of Bioengineering, Henan University of Animal Husbandry and Economy, Zhengzhou 450011, P.R. China *Corresponding author: E-mail: jyzhang2004@126.com

Corresponding Author(s) : Yongfen Wang1

Asian Journal of Chemistry, Vol. 26 No. 24 (2014)

Abstract

A novel complex of copper(II) was prepared by reaction of CuCl2 and fluconazole at reflux in water and tetrahydrofuran. Its structure was determined by single crystal X-ray diffraction analysis. The crystals are monoclinic space group C2/c with a = 23.490(2), b = 9.4719(9), c = 19.8459(18) Å, a = 90.00, b = 123.639(2), g = 90.00°, V = 3676.2(6) Å3, Z = 4, F(000) = 1676, Dc = 1.480 g/cm3, μ = 0.815 mm-1, the final R = 0.0526 and wR = 0.1688. A total of 8828 reflections were collected, of which 3244 were independent (Rint = 0.0344).

Keywords

Fluconazole Copper complex Synthesis Crystal structure.
Wang1, Y., & Bian2, C. (2014). Synthesis and Crystal Structure of [a-(2,4-Difluorophenyl)-a-(1H-1,2,4-triazole-1-ylmethyl)-1H-1,2,4-triazole-1-ethanol]Cu(II) Complex. Asian Journal of Chemistry, 26(24), 8593–8595. https://doi.org/10.14233/ajchem.2014.18408
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