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Copyright (c) 2014 Liang Guo1, Yong Zhang1, Ruo-Xi Zhang2
This work is licensed under a Creative Commons Attribution 4.0 International License.
A Simple and Practical Synthetic Method of Carbon Quantum Dots
Corresponding Author(s) : Liang Guo1
Asian Journal of Chemistry,
Vol. 26 No. 24 (2014)
Abstract
Compared with the traditional quantum dots, carbon quantum dots have excellent optical properties, low cell toxicity, good biocompatibility, easy functionalization and low cost, etc. Recently the synthesis of water-soluble carbon quantum dots have attracted more and more attention of researchers. This experiment used nitric acid and hydrogen peroxide as mixed oxidants to activate commercial carbon to synthesize water-soluble fluorescent carbon dots. We investigated the effect of different factors on the fluorescence intensity of carbon dots. Under the optimal conditions, the particle size of carbon dots is about 5 nm, the fluorescence intensity is high and soluble in water, the fluorescence of carbon dots of surface modification is stronger and more stable. We also found that hydrogen peroxide contributed the synthesis of carbon dots. The synthesis method is very simple, low cost, without expensive and large equipment and owns high practicability.
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- Y.-P. Sun, B. Zhou, Y. Lin, W. Wang, K.A.S. Fernando, P. Pathak, M.J. Meziani, B.A. Harruff, X. Wang, H. Wang, P.G. Luo, H. Yang, M.E. Kose, B. Chen, L.M. Veca and S.-Y. Xie, J. Am. Chem. Soc., 128, 7756 (2006).
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- L.Q. Liu, Y.F. Li, L. Zhan, Y. Liu and C.Z. Huang, Sci. China Chem., 58, 1342 (2011).
- F. Du, F. Zeng, Y. Ming and S. Wu, Microchim. Acta, 180, 453 (2013).
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- S.-L. Hu, K.-Y. Niu, J. Sun, J. Yang, N.-Q. Zhao and X.-W. Du, J. Mater. Chem., 19, 484 (2009).
- Y.-P. Sun, X. Wang, F. Lu, L. Cao, M.J. Meziani, P.G. Luo, L. Gu and L.M. Veca, J. Phys. Chem. C, 112, 18295 (2008).
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References
Y.-P. Sun, B. Zhou, Y. Lin, W. Wang, K.A.S. Fernando, P. Pathak, M.J. Meziani, B.A. Harruff, X. Wang, H. Wang, P.G. Luo, H. Yang, M.E. Kose, B. Chen, L.M. Veca and S.-Y. Xie, J. Am. Chem. Soc., 128, 7756 (2006).
J. Zha, X. Liu, K.-W. Wang and Z.-B. Chen, Chinese J. Spectros. Lab., 30, 2089 (2013).
H. Wu, W. Lu, J.-J. Shao, C. Zhang, M.-B. Wu, B.-H. Li and Q.-H. Yang, New Carbon Mater., 28, 307 (2013).
L. Cao, S.-T. Yang, X. Wang, P.G. Luo, J.-H. Liu, S. Sahu, Y. Liu and Y.-P. Sun, Theranostics., 2, 295 (2012).
X.Y. Xu, R. Ray, Y.L. Gu, H.J. Ploehn, L. Gearheart, K. Raker and W.A. Scrivens, J. Am. Chem. Soc., 126, 12736 (2004).
S.L. Hu, K.Y. Niu, J. Sun, J. Yang, N.-Q. Zhao and X.-W. Du, J. Chem. Mater., 19, 484 (2009).
Z. Xu, J. Yu and G. Liu, Sens. Actuators, 181, 209 (2013).
L.Q. Liu, Y.F. Li, L. Zhan, Y. Liu and C.Z. Huang, Sci. China Chem., 58, 1342 (2011).
F. Du, F. Zeng, Y. Ming and S. Wu, Microchim. Acta, 180, 453 (2013).
C.-X. Li, C. Yu, C.F. Wang and S. Chen, J. Mater. Sci., 48, 6307 (2013).
S.-L. Hu, K.-Y. Niu, J. Sun, J. Yang, N.-Q. Zhao and X.-W. Du, J. Mater. Chem., 19, 484 (2009).
Y.-P. Sun, X. Wang, F. Lu, L. Cao, M.J. Meziani, P.G. Luo, L. Gu and L.M. Veca, J. Phys. Chem. C, 112, 18295 (2008).
L. Tian, D. Ghosh, W. Chen, S. Pradhan, X. Chang and S. Chen, J. Chem. Mater., 21, 2803 (2009).
C.Z. Bing, J. Zha, S. Qian, et al., Chinese J. Inorg. Anal. Chem., 2, 10 (2012).
W.-J. Liu, F.-X. Zeng, H. Jiang and X.-S. Zhang, Chem. Eng. J., 170, 21 (2011).
D.P. Wu,Y. Zhang, R.P. Feng, et al., J. Anal. Chem., 27, 638(2008).