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Copyright (c) 2014 Teja Dwi Sutanto1, Bambang Setiaji3, Karna Wijaya3, Totok Eka Suharto2
This work is licensed under a Creative Commons Attribution 4.0 International License.
Effect of KOH as Stabilizer on Mechanical and Chemical Properties of Liquid Rubber Compound
Corresponding Author(s) : Teja Dwi Sutanto1
Asian Journal of Chemistry,
Vol. 26 No. 24 (2014)
Abstract
The effect of KOH stabilizer on mechanical and chemical properties of liquid rubber compound has been examined. Liquid rubber made by mixing stearic acid and zinc oxide as activator, 3,5-di-tert-butyl-4-hydroxy toluene and liquid smoke as antioxidant, CaCO3 as filler, dibenzothiazole disulfide and tetramethyl thiuram disulfide as accelerator, KOH as stabilizer and sulphur as vulcanizing agent with concentrated latex at room temperature, then maturated for 72 h. In this research the use of KOH stabilizer was varied as 3, 4, 5, 6 and 7 phr. Before being examined, rubber film made from liquid rubber compound by dyeing process then vulcanization done at 100 °C with water vapor. The rubber film which produced from liquid rubber compound then was characterized their mechanical and chemical properties such as resistance to heating, resistance to acid and alkaline resistance. The result showed that KOH content changed the mechanical and chemical properties of liquid rubber compound.
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- H. Xu, J. Han, L. Fang, F. Shen and C. Wu, Polym. Bull., 58, 951 (2007).
- J. White and S.K. De Naskar, Rubber Technologi's Handbook Volume 2, Smithers Rapra Technology Ltd., Shawbury, pp. 281-287 (2009).
- T.H. Khang and Z.M. Ariff, J. Therm. Anal. Calorim., 109, 1545 (2012).
- K.F. El-Nemr, Mater. Des., 32, 3361 (2011).
- C. Kumnuantip and N. Sombatsompop, Mater. Lett., 57, 3167 (2003).
- C.K. Radhakrishnan, P. Kumari, A. Sujith and G. Unnikrishnan, J. Polym. Res., 15, 161 (2008).
- P. Danwanichakul, P. Lertsurasakda and R. Wiwattanasit, Songklanakarin J. Sci. Technol., 34, 551 (2012).
- K.C. Manoj, P. Kumari and G. Unnikrishnan, J. Appl. Polym. Sci., 120, 2654 (2011).
- C.C. Roberts and L.F. Francis, J. Coat. Technol. Res., 10, 441 (2013).
- R.P. Brown and T. Butler, Natural Ageing of Rubber, Rapra Technology Ltd., Shawbury, p. 2, 9, 19-34 (2000).
- F.H.A. Rodrigues, J.P.A. Feitosa, N.M.P.S. Ricardo, F.C.F. França and J.O.B. Carioca, J. Braz. Chem. Soc., 17, 265 (2006).
- H.T. Chiu and P.A. Tsai, J. Mater. Eng. Perform., 15, 88 (2006).
- P.B. Sulekha and R. Joseph, J. Elastomers Plastics, 35, 85 (2003).
- D.X. Huo, X.Y. Yuan, D.Z. Liu, L. Zhang and F. Wang, Chinese J. Polym. Sci., 26, 39 (2008).
- C.S. Kan, J. Coatings Technol., 71, 89 (1999).
- Y. Lu, J. Zhang, P. Chang, Y. Quan and Q. Chen, J. Appl. Polym. Sci., 120, 2001 (2011).
- S.S. Ochigbo, A.S. Luyt and W.W. Focke, J. Mater. Sci., 44, 3248 (2009).
References
H. Xu, J. Han, L. Fang, F. Shen and C. Wu, Polym. Bull., 58, 951 (2007).
J. White and S.K. De Naskar, Rubber Technologi's Handbook Volume 2, Smithers Rapra Technology Ltd., Shawbury, pp. 281-287 (2009).
T.H. Khang and Z.M. Ariff, J. Therm. Anal. Calorim., 109, 1545 (2012).
K.F. El-Nemr, Mater. Des., 32, 3361 (2011).
C. Kumnuantip and N. Sombatsompop, Mater. Lett., 57, 3167 (2003).
C.K. Radhakrishnan, P. Kumari, A. Sujith and G. Unnikrishnan, J. Polym. Res., 15, 161 (2008).
P. Danwanichakul, P. Lertsurasakda and R. Wiwattanasit, Songklanakarin J. Sci. Technol., 34, 551 (2012).
K.C. Manoj, P. Kumari and G. Unnikrishnan, J. Appl. Polym. Sci., 120, 2654 (2011).
C.C. Roberts and L.F. Francis, J. Coat. Technol. Res., 10, 441 (2013).
R.P. Brown and T. Butler, Natural Ageing of Rubber, Rapra Technology Ltd., Shawbury, p. 2, 9, 19-34 (2000).
F.H.A. Rodrigues, J.P.A. Feitosa, N.M.P.S. Ricardo, F.C.F. França and J.O.B. Carioca, J. Braz. Chem. Soc., 17, 265 (2006).
H.T. Chiu and P.A. Tsai, J. Mater. Eng. Perform., 15, 88 (2006).
P.B. Sulekha and R. Joseph, J. Elastomers Plastics, 35, 85 (2003).
D.X. Huo, X.Y. Yuan, D.Z. Liu, L. Zhang and F. Wang, Chinese J. Polym. Sci., 26, 39 (2008).
C.S. Kan, J. Coatings Technol., 71, 89 (1999).
Y. Lu, J. Zhang, P. Chang, Y. Quan and Q. Chen, J. Appl. Polym. Sci., 120, 2001 (2011).
S.S. Ochigbo, A.S. Luyt and W.W. Focke, J. Mater. Sci., 44, 3248 (2009).