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Vol. 26 No. 23 (2014)

Copyright (c) 2014 Pengmian Huang1, Wenjuan Tang3, Guishan Tan1, Wenbin Zeng1, Yuanjian Li1, Qinghua Zhang2, Bo Chen2

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Chemoselective Reduction of Carbonyl Compounds to Alcohols with Co-Doped Ammonia Borane

https://doi.org/10.14233/ajchem.2014.18504
Pengmian Huang1
1School of Pharmaceutical Sciences, Central South University, Changsha 410000, Hunan Province, P.R. China 2Fangsheng Pharmaceutical Co., Ltd. of Hunan, Changsha 410000, Hunan Province, P.R. China 3School of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410000, Hunan Province, P.R. China *Corresponding author: Fax: +86 731 85258733; Tel: +86 15973196958; E-mail: pengmianhuang@163.com
Wenjuan Tang3
1School of Pharmaceutical Sciences, Central South University, Changsha 410000, Hunan Province, P.R. China 2Fangsheng Pharmaceutical Co., Ltd. of Hunan, Changsha 410000, Hunan Province, P.R. China 3School of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410000, Hunan Province, P.R. China *Corresponding author: Fax: +86 731 85258733; Tel: +86 15973196958; E-mail: pengmianhuang@163.com
Guishan Tan1
1School of Pharmaceutical Sciences, Central South University, Changsha 410000, Hunan Province, P.R. China 2Fangsheng Pharmaceutical Co., Ltd. of Hunan, Changsha 410000, Hunan Province, P.R. China 3School of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410000, Hunan Province, P.R. China *Corresponding author: Fax: +86 731 85258733; Tel: +86 15973196958; E-mail: pengmianhuang@163.com
Wenbin Zeng1
1School of Pharmaceutical Sciences, Central South University, Changsha 410000, Hunan Province, P.R. China 2Fangsheng Pharmaceutical Co., Ltd. of Hunan, Changsha 410000, Hunan Province, P.R. China 3School of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410000, Hunan Province, P.R. China *Corresponding author: Fax: +86 731 85258733; Tel: +86 15973196958; E-mail: pengmianhuang@163.com
Yuanjian Li1
1School of Pharmaceutical Sciences, Central South University, Changsha 410000, Hunan Province, P.R. China 2Fangsheng Pharmaceutical Co., Ltd. of Hunan, Changsha 410000, Hunan Province, P.R. China 3School of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410000, Hunan Province, P.R. China *Corresponding author: Fax: +86 731 85258733; Tel: +86 15973196958; E-mail: pengmianhuang@163.com
Qinghua Zhang2
1School of Pharmaceutical Sciences, Central South University, Changsha 410000, Hunan Province, P.R. China 2Fangsheng Pharmaceutical Co., Ltd. of Hunan, Changsha 410000, Hunan Province, P.R. China 3School of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410000, Hunan Province, P.R. China *Corresponding author: Fax: +86 731 85258733; Tel: +86 15973196958; E-mail: pengmianhuang@163.com
Bo Chen2
1School of Pharmaceutical Sciences, Central South University, Changsha 410000, Hunan Province, P.R. China 2Fangsheng Pharmaceutical Co., Ltd. of Hunan, Changsha 410000, Hunan Province, P.R. China 3School of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410000, Hunan Province, P.R. China *Corresponding author: Fax: +86 731 85258733; Tel: +86 15973196958; E-mail: pengmianhuang@163.com

Corresponding Author(s) : Pengmian Huang1

Asian Journal of Chemistry, Vol. 26 No. 23 (2014)

Abstract

Chemoselective reduction of various carbonyl compounds to alcohols with Co-doped ammonia borane was investigated in the present work. It was observed that Co-doped ammonia borane exhibited much better performance than ammonia borane. The Co-based catalysts could be reused up to four times with a slight decrease in activity. Thus, a mild and efficient method for chemoselective reduction of carbonyl compounds with Co-doped ammonia borane was established. The Co-doped ammonia borane sample was characterized by electron paramagnetic resonance. Electron paramagnetic resonance characterization revealed that Co element in a partially reduced state.

Keywords

Co-doped ammonia boarne Chemoselective reduction Carbonyl compounds.
Huang1, P., Tang3, W., Tan1, G., Zeng1, W., Li1, Y., Zhang2, Q., & Chen2, B. (2014). Chemoselective Reduction of Carbonyl Compounds to Alcohols with Co-Doped Ammonia Borane. Asian Journal of Chemistry, 26(23), 8248–8250. https://doi.org/10.14233/ajchem.2014.18504
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