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Copyright (c) 2014 Lingfeng Zhu1, Jinzhou Fan2, Zhao Ye1, Binbin Wang1, Guoting Li1
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorption Performance of Tetracycline on Yellow River Sediment
Corresponding Author(s) : Lingfeng Zhu1
Asian Journal of Chemistry,
Vol. 26 No. 23 (2014)
Abstract
Pharmaceuticals and personal care products have aroused increasing concern throughout the world due to their wide occurrence in natural waters and direct threat to human beings. In this study, tetracycline , one of the pharmaceuticals and personal care products was selected as a target pollutant to check its adsorption behavior on Yellow river sediment. This will help understanding about its transportation in Yellow river and potential risk for human beings. Adsorption kinetics and isotherm tests were conducted for the sediments collected from Huayuankou (Zhengzhou city, China), the middle reach of Yellow river. Effect of solution pH and natural organic matters were also investigated. It was observed that solution pH had a dramatic influence on tetracycline adsorption while the maximal uptake of tetracycline achieved 40.8 mg/g at equilibrium pH 5. Elovich kinetic model could describe the adsorption kinetics better than pseudo-first-order and pseudo-second-order models. The isotherm data were well fitted by Langmuir, Freundlich, Toth and Redlich-Peterson models. The coexisting natural organic matter (humic acid) significantly inhibited the uptake of tetracycline onto Yellow river sediment.
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- X. Yang, R.C. Flowers, H.S. Weinberg and P.C. Singer, Water Res., 45, 5218 (2011).
- P.H. Chang, Z.H. Li, J.S. Jean, W.T. Jiang, C.J. Wang and K.H. Lin, Appl. Clay Sci., 67-68, 158 (2012).
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- P. Kulshrestha, R.F. Giese and D.S. Aga, Environ. Sci. Technol., 38, 4097 (2004).
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- P.H. Chang, J.H. Jean, W.T. Jiang and Z.H. Li, Colloid Surf. A, 339, 94 (2009).
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- M. Kithome, J.W. Paul, L.M. Lavkulich and A.A. Bomke, Soil Sci. Soc. Am. J., 62, 622 (1998).
- I. Langmuir, J. Am. Chem. Soc., 38, 2221 (1916).
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- O. Redlich and D.L. Peterson, J. Phys. Chem., 63, 1024 (1959).
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References
X. Yang, R.C. Flowers, H.S. Weinberg and P.C. Singer, Water Res., 45, 5218 (2011).
P.H. Chang, Z.H. Li, J.S. Jean, W.T. Jiang, C.J. Wang and K.H. Lin, Appl. Clay Sci., 67-68, 158 (2012).
S. Kim, P. Eichhorn, J.N. Jensen, A.S. Weber and D.S. Aga, Environ. Sci. Technol., 39, 5816 (2005).
P. Kay, P.A. Blackwell and A.B.A. Boxall, Environ. Toxicol. Chem., 23, 1136 (2004).
T. Polubesova, D. Zadaka, L. Groisman and S. Nir, Water Res., 40, 2369 (2006).
P. Kulshrestha, R.F. Giese and D.S. Aga, Environ. Sci. Technol., 38, 4097 (2004).
P.H. Chang, Z.H. Li, T.L. Yu, S. Munkhbayer, T.H. Kuo, Y.C. Hung, J.S. Jean and K.H. Lin, J. Hazard. Mater., 165, 148 (2009).
P.H. Chang, Z.H. Li, W.T. Jiang and J.S. Jean, Appl. Clay Sci., 46, 27 (2009).
R.A. Figueroa, A. Leonard and A.A. MacKay, Environ. Sci. Technol., 38, 476 (2004).
P.H. Chang, J.H. Jean, W.T. Jiang and Z.H. Li, Colloid Surf. A, 339, 94 (2009).
H.J. Liu, Y. Yang, J. Kang, M.H. Fan and J.H. Qu, J. Environ. Sci. (China), 24, 242 (2012).
S. Lagergren, Handlingar, 24, 1 (1898).
Y.S. Ho and G. McKay, Process Biochem., 34, 451 (1999).
M. Kithome, J.W. Paul, L.M. Lavkulich and A.A. Bomke, Soil Sci. Soc. Am. J., 62, 622 (1998).
I. Langmuir, J. Am. Chem. Soc., 38, 2221 (1916).
H.M.F. Freundlich, J. Phys. Chem., 57, 385 (1906).
V.C. Srivastava, M.M. Swamy, I.D. Mall, B. Prasad and I.M. Mishra, Colloids Surf. A, 272, 89 (2006).
O. Redlich and D.L. Peterson, J. Phys. Chem., 63, 1024 (1959).
A.B.M. Giasuddin, S.R. Kanel and H. Choi, Environ. Sci. Technol., 41, 2022 (2007).
A.W.P. Vermeer, W.H. van Riemsdijk and L.K. Koopal, Langmuir, 14, 2810 (1998).
T. Saito, L.K. Koopal, W.H. van Riemsdijk, S. Nagasaki and S. Tanaka, Langmuir, 20, 689 (2004).