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Copyright (c) 2014 Weiping Li1, Peijiang Han1, Yiran Shi1, Fang He2, Haojie Duan1, Peifeng Yang1
This work is licensed under a Creative Commons Attribution 4.0 International License.
Treatment Process for Phenolic Wastewater
Corresponding Author(s) : Weiping Li1
Asian Journal of Chemistry,
Vol. 26 No. 23 (2014)
Abstract
Hydrogen production from waste using supercritical water gasification (SCWG) is a promising approach towards cleaner fuel production and a solution for hard to treat wastes. In this paper, the catalytic gasification of phenolic wastewater was investigated in a batch reactor at 26-34 MPa, 510-550 °C, residence time of 2-5 min. The results showed that the main gas products were H2, CO, CO2 and CH4. When residence time was 5 min, temperature is 550 °C, hydrogen gasification ratio reached up to 135 %. Supercritical water gasification was proved to be an efficient technology for phenolic wastewater treatment.
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References
S.J. Wang and K.C. Loh, Enzyme Microb. Technol., 25, 177 (1999).
S.H. Lin and C.S. Wang, J. Hazard. Mater., B90, 205 (2002).
B. Veriansyah, J. Kim, J.D. Kim and Y.W. Lee, Int. J. Green Energy, 5, 322 (2008).
Y. Matsumura, T. Minowa, B. Potic, S.R.A. Kersten, W. Prins, W.P.M. van Swaaij, B. van de Beld, D.C. Elliott, G.G. Neuenschwander, A. Kruse and M.J. Antal Jr., Biomass Bioenergy, 29, 269 (2005).
A. Kruse, Biofuel Bioproducts Biorefining, 2, 415 (2008).
C.Q. Cao, L.J. Guo, H. Jin, S.M. Guo, Y.J. Lu and X.M. Zhang, Int. J. Hydrogen Energy, 38, 13293 (2013).
A.A. Peterson, F. Vogel, R.P. Lachance, M. Froling, J.M.J. Antal and J.W. Tester, Environ. Sci., 1, 32 (2008).
S.M. Guo, L.J. Guo, J.R. Yin and H. Jin, J. Supercrit. Fluids, 78, 95 (2013).
Q.Q. Guan, C.H. Wei, P. Ning, S.L. Tian and J.J. Gu, Environ. Sci., 18, 844 (2013).
N. Ding, R. Azargohar, A.K. Dalai and J.A. Kozinski, Fuel, 118, 416 (2014).
O. Sawai, T. Nunoura and K. Yamamoto, J. Supercrit. Fluids, 79, 274 (2013).
L.Y. Peng, M.D. Bao, Q.F. Wang, F.C. Wang and H.J. Su, Bioresour. Technol., 151, 236 (2014).
R. Muangrat, J.A. Onwudili and P.T. Williams, Appl. Catal. B, 100, 440 (2010).
J.B. Gadhe and R.B. Gupta, Ind. Eng. Chem. Res., 44, 4577 (2005).
A. Kruse, D. Meier, P. Rimbrecht and M. Schacht, Ind. Eng. Chem. Res., 39, 4842 (2000).
N. Boukis, V. Diem, W. Habicht and E. Dinjus, Ind. Eng. Chem. Res., 42, 728 (2003).
M.J. Antal Jr., S.G. Allen, D. Schulman and X. Xu, Ind. Eng. Chem. Res., 39, 4040 (2000).
T. Minowa and T. Ogi, Catal. Today, 45, 411 (1998).
T. Minowa and S. Inoue, Renew. Energy, 16, 1114 (1999).