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Vol. 26 No. 23 (2014)

Copyright (c) 2014 Chanwoo Lee1, Kyunghun Song2

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Tulipalin-Based Polymers

https://doi.org/10.14233/ajchem.2014.17098
Chanwoo Lee1
1Department of Innovative Industrial Technology, Hoseo University, Asan, Chungnam 336-851, Republic of Korea 2Department of Clothing & Textiles, Paichai University, Seo-gu, Daejeon 302-735, Republic of Korea *Corresponding author: Fax: +82 42 5205576; Tel: +82 42 5205413; E-mail: khsong@pcu.ac.kr
Kyunghun Song2
1Department of Innovative Industrial Technology, Hoseo University, Asan, Chungnam 336-851, Republic of Korea 2Department of Clothing & Textiles, Paichai University, Seo-gu, Daejeon 302-735, Republic of Korea *Corresponding author: Fax: +82 42 5205576; Tel: +82 42 5205413; E-mail: khsong@pcu.ac.kr

Corresponding Author(s) : Chanwoo Lee1

Asian Journal of Chemistry, Vol. 26 No. 23 (2014)

Abstract

2-Hydroxyethyl methacrylate (HEMA) terminated poly(DL-lactide) macromonomers (HEMA-PDLLA) were synthesized and copolymerized with a-methylene-g-butyrolactone (MBL) to produce their graft copolymers of poly(tulipalin A) (PT) and poly(DL-lactide) (PDLLA) (PT-g-PDLLA). HEMA-PDLLA were synthesized by ring opening polymerization (ROP) of DL-lactide in the presence of 2-hydroxyethyl methacrylate. The thermal stabilities of PT-g-PDLLA copolymers were investigated by Thermogravimetry analysis. There were two stages in weight loss of each copolymer by recorded at 270-300 ºC are attributed to the decomposition of poly(DL-lactide). Two isolated Tg were shown in each case, corresponding to the poly(DL-lactide)-rich domain and PT-rich domain were also investigated by differential scanning calorimetry.

Keywords

Poly(tulipalin A) Ring opening polymerization Copolymer Decomposition.
Lee1, C., & Song2, K. (2014). Synthesis and Characterization of Tulipalin-Based Polymers. Asian Journal of Chemistry, 26(23), 8057–8061. https://doi.org/10.14233/ajchem.2014.17098
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