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Copyright (c) 2014 Mahtab Baghban1, Saeid Mansour Baghahi1, Fatemeh Damercheli2, Ali Akbar Miran Beigi3
This work is licensed under a Creative Commons Attribution 4.0 International License.
Identification and Quantification of Polycyclic Aromatic Hydrocarbons in Tehran Drinking Water by Gas Chromatography-Mass Spectrometry
Corresponding Author(s) : Mahtab Baghban1
Asian Journal of Chemistry,
Vol. 26 No. 23 (2014)
Abstract
Polycyclic aromatic hydrocarbons are a main group of organic compounds that their monitoring in water recourses is very important because of their side effects such as carcinogenic, genetic and systematic effects on human health. Sources of water pollution with polycyclic aromatic hydrocarbons are oil industries, oil leakage from storage tanks and oil transferring pipe lines, using of fossil fuels, industrial wastewater's disposal, burning and ash of wastes, etc. Due to ecological and environmental importance and also vast spreading of the pollutant resources in many districts of Iran including, monitoring of pollutants is necessary especially in Tehran province in order to ensure the health of water resources. In this study, 16 compounds of polycyclic aromatic hydrocarbons which are listed as potentially-carcinogen agents for human by the United States Environmental Protection Agency (EPA) were determined by gas chromatography-mass spectrometry. The instrument was calibrated in a selected ion monitoring mode (SIM mode) and it was equipped to a 30 m capillary column. In this research five water effluents including Jalalieh, Kan, Tehranpars 1, Tehranpars 2 and Sohanak water treatment plants with several water storage tanks (related to Tehran province water distribution) were studied. The samples were extracted from liquid phase and analyzed by injection to a GC-MS system (Agilent 6890N). The mass spectra indicate that the concentrations of these 16 polycyclic aromatic hydrocarbons compounds are lower than permitted limits of Iranian National Standard (standard number 1053 for drinking water), World Health Organization (WHO) and US.EPA recommendations.
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- M. Zander, Physical and Chemical Properties of Polycyclic Aromatic Hydrocarbons, In Handbook of Polycyclic Aromatic Hydrocarbons. New York, pp. 1-25 (1983).
- R.P. Wayne, Chemistry of the Atmospheres, Oxford University Press, Oxford, edn 3, pp. 1-50 (2000).
- World Health Organization, Guidelines for Drinking-Water Quality, Recommendations, Geneva, Switzerland, edn 3, Vol. 1 (2004).
- E. Manoli and C. Samara, Trends Analyt. Chem., 18, 417 (1999).
- United States Environmental Protection Agency (USEPA), Toxics Criteria for those States Not Complying with the Clean Water; Act section 303(c)(2)(B), 40 CFR 131.36, pp. 531-538 (1995).
- Council of European Communities, Directives 75/440/EEC, 79/869/EEC and 80/778/EEC (1998).
- Council of the European Communities, Council Directive 98/83/EC of 3 November 1998 on the Quality of Water Intended for Human Consumption, Off. J. Eur. Commun., L330, pp. 32-54 (1998).
- R.G. Harvey, Polycyclic Aromatic Hydrocarbons, Wiley-VCH, New York, pp. 8-11 (1997).
- B. Janoszka, I. Warzecha, U. Blaszczyk and D. Bodzek, Acta Chromatogr., 14, 115 (2004).
- M. Norin and A.-M. Strömvaix, Environ. Technol., 25, 323 (2004).
- L. Becker, G. Matuschek, D. Lenoir and A. Kettrup, Chemosphere, 42, 301 (2001).
- T. Vo-Dinh, Talanta, 47, 943 (1998).
- L. Pozzoli, S. Gilardoni, M.G. Perrone, G. De Gennaro, M. De Rienzo and D. Vione, Ann. Chim., 94, 17 (2004).
- D. MacKay, W.Y. Shiu and K.C. Ma, Chemicals, Illustrated Handbook of Physical-Chemical. Properties and Environmental Fate for Organic, Vol. II, Lewis, Boca Raton, pp. 246-252 (1992).
- L.E. Sverdrup, T. Nielsen and P.H. Krogh, Environ. Sci. Technol., 36, 2429 (2002).
- L.A. Gundel, V.C. Lee, K.R.R. Mahanama, R.K. Stevens and J.M. Daisey, Atmos. Environ., 29, 1719 (1995).
- United States Environmental Protection Agency (USEPA), Ground Water and Drinking Water, National Primary Drinking Water Regulations; http://www.epa.gov/safewater/contaminants/dw_contamfs/benzopyr. html (2006).
- U.S. Wisconsin, Department of Health and Human Services; Public Health Service; Agency for Toxic Substances and Disease Registry. Division of Health Assessment and Consultation. Atlanta, Georgia 30333; http://www.atsdr.cdc.gov (2004).
- Iranian Standard and Industrial Research Institute (ISIRI). Available from http://www.isiri.org, (2012).
References
M. Zander, Physical and Chemical Properties of Polycyclic Aromatic Hydrocarbons, In Handbook of Polycyclic Aromatic Hydrocarbons. New York, pp. 1-25 (1983).
R.P. Wayne, Chemistry of the Atmospheres, Oxford University Press, Oxford, edn 3, pp. 1-50 (2000).
World Health Organization, Guidelines for Drinking-Water Quality, Recommendations, Geneva, Switzerland, edn 3, Vol. 1 (2004).
E. Manoli and C. Samara, Trends Analyt. Chem., 18, 417 (1999).
United States Environmental Protection Agency (USEPA), Toxics Criteria for those States Not Complying with the Clean Water; Act section 303(c)(2)(B), 40 CFR 131.36, pp. 531-538 (1995).
Council of European Communities, Directives 75/440/EEC, 79/869/EEC and 80/778/EEC (1998).
Council of the European Communities, Council Directive 98/83/EC of 3 November 1998 on the Quality of Water Intended for Human Consumption, Off. J. Eur. Commun., L330, pp. 32-54 (1998).
R.G. Harvey, Polycyclic Aromatic Hydrocarbons, Wiley-VCH, New York, pp. 8-11 (1997).
B. Janoszka, I. Warzecha, U. Blaszczyk and D. Bodzek, Acta Chromatogr., 14, 115 (2004).
M. Norin and A.-M. Strömvaix, Environ. Technol., 25, 323 (2004).
L. Becker, G. Matuschek, D. Lenoir and A. Kettrup, Chemosphere, 42, 301 (2001).
T. Vo-Dinh, Talanta, 47, 943 (1998).
L. Pozzoli, S. Gilardoni, M.G. Perrone, G. De Gennaro, M. De Rienzo and D. Vione, Ann. Chim., 94, 17 (2004).
D. MacKay, W.Y. Shiu and K.C. Ma, Chemicals, Illustrated Handbook of Physical-Chemical. Properties and Environmental Fate for Organic, Vol. II, Lewis, Boca Raton, pp. 246-252 (1992).
L.E. Sverdrup, T. Nielsen and P.H. Krogh, Environ. Sci. Technol., 36, 2429 (2002).
L.A. Gundel, V.C. Lee, K.R.R. Mahanama, R.K. Stevens and J.M. Daisey, Atmos. Environ., 29, 1719 (1995).
United States Environmental Protection Agency (USEPA), Ground Water and Drinking Water, National Primary Drinking Water Regulations; http://www.epa.gov/safewater/contaminants/dw_contamfs/benzopyr. html (2006).
U.S. Wisconsin, Department of Health and Human Services; Public Health Service; Agency for Toxic Substances and Disease Registry. Division of Health Assessment and Consultation. Atlanta, Georgia 30333; http://www.atsdr.cdc.gov (2004).
Iranian Standard and Industrial Research Institute (ISIRI). Available from http://www.isiri.org, (2012).