Issue

Vol. 26 No. 20 (2014)

Copyright (c) 2014 Jinpeng Wu

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Hydrothermal Synthesis and Crystal Structure of Ni(II) Coordination Polymer of 4,4'-Benzophenonedicarboxylic Acid and bis(4-pyridyl)amine

https://doi.org/10.14233/ajchem.2014.17631
Jinpeng Wu
College of Chemical engineering and environment, Weifang University of Science and Technology, Weifang 262700, Shandong, P.R. China Corresponding author: E-mail: dzlihongliang@163.com

Corresponding Author(s) : Jinpeng Wu

Asian Journal of Chemistry, Vol. 26 No. 20 (2014)

Abstract

A new coordination polymer of nickel(II) with the formula {[Ni (bda)(bpa)]·(H2O)n} (1) (H2bda = 4,4'-benzophenonedicarboxylic acid and bpa = bis(4-pyridyl)amine), has been prepared by hydrothermal synthesis. Complex {[Ni (bda)(bpa)]·(H2O)n} (1), monoclinic, space group C2/c with a = 23.735 (5)Å, b = 12.146 (5) Å, c = 16.789 (5) Å, b = 106.731 (5)° V = 4635 (3) Å3, Z = 8, Mr = 516.14, Dc = 1.479 g/cm3, F(000) = 2128 and μ = 0.88 mm-1. The final refinement gave R = 0.0402 and wR = 0.1242 for 4735 reflections with I > 2s(I). X-ray diffraction analysis reveals that complex 1 shows a two-dimensional structure with 1D helical chains.

Keywords

Nickel(II) Coordination polymer 4 4'-Benzophenonedicarboxylic acid Bis(4-pyridyl)amine).
Wu, J. (2014). Hydrothermal Synthesis and Crystal Structure of Ni(II) Coordination Polymer of 4,4’-Benzophenonedicarboxylic Acid and bis(4-pyridyl)amine. Asian Journal of Chemistry, 26(20), 7079–7080. https://doi.org/10.14233/ajchem.2014.17631
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. C.-S. Liu, J.-J. Wang, Z. Chang, L.-F. Yan and X.-H. Bu, CrystEngComm, 12, 1833 (2010).
  2. L. Zhang, Y. Ling, D.J. Li, J. Li and M. Du, Inorg. Chim. Acta, 363, 2010 (2010).
  3. F. Guo, B.Y. Zhu, G.L. Xu, M.M. Zhang, X.L. Zhang and J. Zhang, J. Solid State Chem., 199, 42 (2013).
  4. D.S. Liu, Y. Sui, C.C. Huang, T.H. Pan, X.H. Huang, J.Z. Chen and X.Z. You, Inorg. Chem. Commun., 13, 762 (2010).
  5. J.Q. Liu, Z.B. Jia and Y.Y. Wang, J. Mol. Struct., 987, 126 (2011).
  6. Z.L. Xie, M.L. Feng, J.R. Li and X.Y. Huang, Inorg. Chem. Commun., 11, 1143 (2008).
  7. R. Prajapati, L. Mishra, K. Kimura and P. Raghavaiah, Polyhedron, 28, 600 (2009).
  8. A. Thirumurugan and C.N.R. Rao, J. Mater. Chem., 15, 3852 (2005).
  9. AXS Bruker, SAINT Software Reference Manual, Madison, WI (1998).
  10. G.M. Sheldrick, SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).
Read More
Author biographies is not available.
Download
Statistic
Read Counter : 0