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Copyright (c) 2014 Yongfu Li
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A New Mn(II) Coordination Polymer Based on Dicarboxylate and Imidazole-Containing Ligand
Corresponding Author(s) : Yongfu Li
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
A new coordination polymer with the composition [Mn(ada)(bib)]n·2H2O (1) [H2ada = 1,3-Adamantane dicarboxylic acid and bib = 4,4'-bis(imidazolyl)-biphenyl], has been prepared by hydrothermal synthesis. Complex [Mn(ada)(bib)]n·2H2O (1), is Orthorhombic, space group Pnma with a = 14.352 (5) Å, b = 26.869 (5)Å, c = 11.576 (5) Å, V = 4464 (3)Å3, Z = 4, Mr = 904.89, Dc =1.346 g/cm3, F(000) = 1896 and μ = 0.357 mm-1. The final refinement gave R = 0.0583 and wR = 0.0712 for 2819 reflections with I > 2s(I). X-ray diffraction analysis reveals that complex 1 shows a two-dimensional (2D) layer structure.
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- G.M. Sheldrick, SHELXTL NT, version 5.1; Program for Solution and Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany (1997).
References
J.Q. Liu, Y.Y. Wang, P. Liu, Z. Dong, Q.Z. Shi and S.R. Batten, CrystEngComm, 11, 1207 (2009).
Y.F. Zhou, B.Y. Lou, D.Q. Yuan, Y.Q. Xu, F.L. Jiang and M.C. Hong, Inorg. Chim. Acta, 358, 3057 (2005).
X.Q. Lv, M. Pan, J.R. He, Y.P. Cai, B.S. Kang and C.Y. Su, CrystEngComm, 8, 827 (2006).
J. Wang, Z. Lin, Y.C. Ou, N.L. Yang, Y.H. Zhang and M.L. Tong, Inorg. Chem., 47, 190 (2008).
O.R. Evans and W. Lin, Chem. Mater., 13, 2705 (2001).
X.L. Wang, C. Qin, E.B. Wang, Y.G. Li and Z.M. Su, Chem. Commun., 5450 (2005).
SAINT Software Reference Manual; Bruker AXS: Madison, WI (1998).
G.M. Sheldrick, SHELXTL NT, version 5.1; Program for Solution and Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany (1997).