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Copyright (c) 2014 Yujing Wang
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Cobalt(II) Coordination Polymer Based on Dicarboxylate and Nitrogen-Containing Ligands
Corresponding Author(s) : Yujing Wang
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
A new coordination polymers [Co(5-NO2-ip)(bimb)]n (1) [5-NO2-ip = 5-nitro isophthalic acid, bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene], has been prepared by hydrothermal synthesis. Complex [Co(5-NO2-ip)( bimb)]n (1), is monoclinic, space group P21/c with a = 10.228 (5) Å, b = 16.804 (5) Å, c = 12.488 (5) Å, b = 91.771 (5)° V = 2145.3 (15) Å3, Z = 4, Mr = 506.34, Dc = 1.568 g/cm3, F (000) = 1036 and μ = 0.85 mm-1. The final refinement gave R = 0.0321 and wR = 0.0809 for 4072 reflections with I > 2s(I). X-ray diffraction analysis reveals that complex 1 shows a two-dimensional (2D) layer structure and features a three-dimensional supramolecular structure.
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References
P.J. Hagrman, D. Hagrman and J. Zubieta, Angew. Chem. Int. Ed., 38, 2638 (1999).
S. Kitagawa, R. Kitaura and S.-i. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004).
M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O'Keefe and O.M. Yaghi, Science, 295, 469 (2002).
B. Zhao, H.-L. Gao, X.-Y. Chen, P. Cheng, W. Shi, D.-Z. Liao, S.-P. Yan and Z.-H. Jiang, Chem. Eur. J., 12, 149 (2005).
L.J. Charbonniere, R. Ziessel, M. Montalti, L. Prodi, N. Zaccheroni, C. Boehme and G. Wipff, J. Am. Chem. Soc., 124, 7779 (2002).
T. Gunnlaugsson, J.P. Leonard, K. Senechal and A.J. Harte, J. Am. Chem. Soc., 125, 12062 (2003).
J.-P. Zhang and X.-M. Chen, Chem. Commun., 1689 (2006).
Y.-F. Zhou, M.-C. Hong and X.-T. Wu, Chem. Commun., 135 (2006).
A.X.S. Bruker, SAINT Software Reference Manual, Madison, WI, (1998).
G.M. Sheldrick, SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).