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Vol. 26 No. 20 (2014)

Copyright (c) 2014 Xiaoxia Yang, Jianbin Zhang*, Yan Chang, Qiang Li

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Novel Oxidation of Hydrogen Sulfide by Dimethyl Sulfoxide in Presence of b-Cyclodextrin

https://doi.org/10.14233/ajchem.2014.17827
Xiaoxia Yang
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China *Corresponding author: Tel/Fax: +86 471 6575722; E-mail: tadzhang@pku.edu.cn
Jianbin Zhang*
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China *Corresponding author: Tel/Fax: +86 471 6575722; E-mail: tadzhang@pku.edu.cn
Yan Chang
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China *Corresponding author: Tel/Fax: +86 471 6575722; E-mail: tadzhang@pku.edu.cn
Qiang Li
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China *Corresponding author: Tel/Fax: +86 471 6575722; E-mail: tadzhang@pku.edu.cn

Corresponding Author(s) : Xiaoxia Yang

Asian Journal of Chemistry, Vol. 26 No. 20 (2014)

Abstract

Dimethyl sulfoxide is used as an oxidizing agent to oxidize hydrogen sulfide to solid sulfur at room temperatures and normal pressures, in which, b-cyclodextrin plays an important role in this reaction. In this work, when GC-MS, SEM and FTIR spectroscopic techniques were used for inspection of spectral changes of b-cyclodextrin, dimethyl sulfoxide solution with increasing H2S concentration, the results suggest that H2S was oxidated by dimethyl sulfoxide in the presence of b-cyclodextrin and dimethyl sulfide, water, and sulfur can be identified. The results of this work can be used to provide important reaction mechanism of H2S with dimethyl sulfoxide in the presence of b-cyclodextrin with potential industrial application of b-cyclodextrin-dimethyl sulfoxide solution.

Keywords

Dimethyl sulfoxide Hydrogen sulfide b-Cyclodextrin Dimethyl sulfide.
Yang, X., Zhang*, J., Chang, Y., & Li, Q. (2014). Novel Oxidation of Hydrogen Sulfide by Dimethyl Sulfoxide in Presence of b-Cyclodextrin. Asian Journal of Chemistry, 26(20), 7040–7042. https://doi.org/10.14233/ajchem.2014.17827
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References
  1. W.W. Epstein and F.W. Sweat, Chem. Rev., 67, 247 (1967).
  2. I. Barnes, J. Hjorth and N. Mihalopoulos, Chem. Rev., 106, 940 (2006).
  3. S. Searles Jr. and J.H. Hays, J. Org. Chem., 23, 2028 (1958).
  4. N. Kornblum, J.W. Powers, G.J. Anderson, W.J. Jones, H.O. Larson, O. Levand and W.M. Weaver, J. Am. Chem. Soc., 79, 6562 (1957).
  5. O.G. Lowe, J. Org. Chem., 42, 2524 (1977).
  6. D. Martin, A. Weise and H.J. Niclas, Angew. Chem. Int. Ed. Engl., 6, 318 (1967).
  7. T.J. Wallace, J. Am. Chem. Soc., 86, 2018 (1964).
  8. T.J. Wallace and J.J. Mahon, J. Am. Chem. Soc., 86, 4099 (1964).
  9. X. Esteve, A. Conesa and A. Coronas, J. Chem. Eng. Data, 48, 392 (2003).
  10. H.C. Ku and C.H. Tu, J. Chem. Eng. Data, 45, 391 (2000).
  11. A. Valtz, C. Coquelet and D. Richon, Fluid Phase Equilib., 220, 75 (2004).
  12. D. Nagel, R. De Kermadec, H.G. Lintz, C. Roizard and F. Lapicque, Chem. Eng. Sci., 57, 4883 (2002).
  13. R. De Kermadec, F. Lapicque, D. Roizard and C. Roizard, Ind. Eng. Chem. Res., 41, 153 (2002).
  14. X.X. Li, Y.X. Liu and X.H. Wei, Chin. J. Chem. Eng., 13, 234 (2005).
  15. J. Zhang, P. Zhang, G. Chen, F. Han and X. Wei, J. Chem. Eng. Data, 53, 1479 (2008).
  16. J. Zhang, P. Zhang, F. Han, G. Chen, L. Zhang and X. Wei, Ind. Eng. Chem. Res., 48, 1287 (2009).
  17. J.B. Zhang, F. Han, X.H. Wei, L. Shui, H. Gong and P. Zhang, Ind. Eng. Chem. Res., 49, 2025 (2010).
  18. A. Lasagabaster, M.J. Abad, L. Barral and A. Ares, Eur. Polym. J., 42, 3121 (2006).
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